LC determination of propylene glycol in human plasma after pre-column derivatization with benzoyl chloride

A simple high-performance liquid chromatographic method, using photodiode array detection was developed for the determination of propylene glycol in human plasma and in the fluid retreived after continuous veno-venous hemofiltration. The method entailed alkaline derivatization with benzoyl chloride and ethylene glycol as internal standard. The separation of the compounds, after extraction with pentane, was carried out on a Pursuit C8 column with UV-detection at 230 nm. Validation samples were analyzed with an accuracy between 95 and 105%, and intra- and inter-day coefficients of variation of less than 8%. The calibration curve was linear over a concentration range of 5-100 mg

Measurements of atmospheric electricity aloft

Measurements of the electrical characteristics of the atmosphere above the surface have been made for over 200 years, from a variety of different platforms, including kites, balloons, rockets and aircraft. From these measurements, a great deal of information about the electrical characteristics of the atmosphere has been gained, assisting our understanding of the global atmospheric electric circuit, thunderstorm electrification and lightning generation mechanisms, discovery of transient luminous events above thunderstorms, and many other electrical phenomena. This paper surveys the history of atmospheric electrical measurements aloft, from the earliest manned balloon ascents to current day observations with free balloons and aircraft. Measurements of atmospheric electrical parameters in a range of meteorological conditions are described, including clear air conditions, polluted conditions, non-thunderstorm clouds, and thunderstorm clouds, spanning a range of atmospheric conditions, from fair weather, to the most electrically active

Modelling rainfall and canopy controls on net-precipitation beneath selectively-logged tropical forest.

Understanding spatio-temporal patterns in rainfall received beneath tropical forest is required for eco- hydrological modelling of soil-water status, river behaviour, soil erosion, nutrient loss and wet-canopy evaporation. As selective-logging of tropical forest leaves a very complex mosaic of canopy types, it is likely to add to the spatio-temporal complexity of this sub-canopy or net precipitation. As a precursor to addressing this problem, the analysis presented here will examine the two dominant biophysical controls on sub-canopy precipitation. These controls are: (a) the spatial and temporal patterns in above-canopy or gross rainfall, and (b) the rate of wet-canopy evaporation associated with each type of canopy structure created by selective-forestry. For this study, over 400 raingauges were installed within a 10 km2 area of lowland dipterocarp forest affected by selective-forestry some 9-years prior to this work. Gauges were located beneath various canopy types and within large openings. The spatial distribution of gross rainfall (monitored within the openings) was modelled using variography, while the effects of different canopy types on sub-canopy preciptation was analysed by comparing 6-month totals. The temporal distribution of gross rainfall over an 11-year record collected at the same site (Danum Valley Field Centre) was modelled with Data-Based-Mechanistic (DBM) approaches. These DBM approaches were also applied to the rainfall time-series of the two adjacent meteorological stations; all three gauges being contained within a 5000 km2 region of Eastern Sabah in Malaysian Borneo. Strong diurnal modulation was apparent within gross rainfall for the inland rainforest site, with a distribution consistent with a dominance of local convective rain cells. A similarly strong cycle coincident with the periodicity of the El Niño-Southern Oscillation (ENSO) was present within all of the region's rainfall records, though marked differences in annual and intra-annual seasonality were apparent. The preliminary variogram modelling indicated that a deterministic drift was present within the local-scale gross rainfall data, probably related to local topographic effects. Notwithstanding the need to remove this drift, the work indicated that spatial models of gross rainfall could be identified and used to interpret similar models of net-precipitation. During the ENSO drought-period monitored, the lowland dipterocarp forest allowed 91% of the gross rainfall to reach the ground as throughfall. These rates were, however, reduced to between 80%–86% beneath representative plots of moderately impacted to creeper-covered, highly damaged patches of forest