Diurnal variation of midlatitudinal NO3 column abundance over table mountain facility, California

The column abundance of NO3 was measured over Table Mountain Facility, CA (34.4° 117.7° W) from May 2003 through September 2004, using lunar occultation near full moon with a grating spectrometer. The NO 3 column retrieval was performed with the differential optical absorption spectroscopy (DOAS) technique using both the 623 and 662 nm NO 3 absorption bands. Other spectral features such as Fraunhofer lines and absorption from water vapor and oxygen were removed using solar spectra obtained at different airmass factors. We observed a seasonal variation, with nocturnally averaged NO3 columns between 5-7 × 1013 molec cm-2 during October through March, and 5-22 × 10 13 molec cm-2 during April through September. A subset of the data, with diurnal variability vastly different from the temporal profile obtained from one-dimensional stratospheric model calculations, clearly has boundary layer contributions; this was confirmed by simultaneous long-path DOAS measurements. However, even the NO3 columns that did follow the modeled time evolution were often much larger than modeled stratospheric partial columns constrained by realistic temperatures and ozone concentrations. This discrepancy is attributed to substantial tropospheric NO3 in the free troposphere, which may have the same time dependence as stratospheric NO 3

High spectral resolution Fabry-Perot interferometer measurements of comet Halley at H-alpha and 6300 A

A 40.6 cm Newtonian telescope has been interfaced to the Fabry-Perot interferometer at the Arecibo Observatory to make high spectral resolution measurements of Comet Halley emissions at 6562.72 A (H-alpha) and 6300.3 A (OI). In March 1986 the H-alpha surface brightness for a 5'.9 field of view centered on the comet nucleus decreased from 39+/-7.8 rayleighs on 12 March to 16+/-3.8 rayleighs on 23 March. The atomic hydrogen production rate on 12 March 1986 was 1.62+/-0.5 x 1030 s-1, and on 23 March 1986 it was 6.76+/-2.3 x 1029 s-1. Using spectral resolution of 0.196 A, we found the atomic hydrogen outflow velocity to be approximately 7.9+/-1.0 km s-1. In general, the H-alpha spectra are highly structured, and indicative of a multiple component atomic hydrogen velocity distribution. An isotropic outflow of atomic hydrogen at various velocities is not adequate to explain the spectra measured at H-alpha. The 6300.3 A emission of O(1D) had a surface brightness of 81+/-16 rayleighs on 15 March 1986, and 95+/-11 rayleighs on 17 March 1986. After adjustment for atmospheric extinction, the implied O(1D) production rate on 15 March is 6.44+/-3.0 x 1028 s-1, and the production rate on 17 March is 5.66+/-2.7 x 1028 s-1. These spectra included a feature at 6300.8 A that we attribute to NH2. The brightness of this emission feature was 37+/-11 rayleighs on 15 March.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/25881/1/0000444.pd

First lidar observations of mesospheric hydroxyl

Ground-based lidars have been used to detect and identify ground-state (v" =0) hydroxyl radicals (OH) in the mesosphere between about 75 and 85 km altitude. These lidars operate near 308 nm and OH is observed through laser-induced-fluorescence on the A 2∑ + -X 2II(0, 0) band. The results expose a valuable global set of nighttime OH observations, since existing long-term lidar data at several NDSC sites contain the (serendipitous) OH information. Results of lidar observations are presented from two mid-latitude sites, one in each hemisphere: Table Mountain (34°N), California, and Lauder (45°S), New Zealand. They show observations of a geometrically thin (∼3 km) nocturnal layer of OH near 80 km. For the Table Mountain observations, the derived values for the OH density at 80 km typically are 2 - 4 × 10 5 cm -3 which is in accordance with model predictions [Dodd et al., 1994]. The temporal behavior of the mesospheric OH signal, following sunset, that was found, supports previous model predictions [Allen et al., 1984] in a qualitative fashion