52 research outputs found
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Coherent coupling in ferroelectric superlattices
The phase transition and dielectric behavior of ferroelectric multilayers have been discussed. The coherent interaction between ultra-thin layers can be significantly strong, resulting in a broad diffuse phase transition. The thicknesses of layers and their spatial distributions hold the keys of enhancing dielectric properties in a broad temperature range
Electronic structure and ferroelectricity in SrBi2Ta2O9
The electronic structure of SrBi2Ta2O9 is investigated from first-principles,
within the local density approximation, using the full-potential linearized
augmented plane wave (LAPW) method. The results show that, besides the large
Ta(5d)-O(2p) hybridization which is a common feature of the ferroelectric
perovskites, there is an important hybridization between bismuth and oxygen
states. The underlying static potential for the ferroelectric distortion and
the primary source for ferroelectricity is investigated by a lattice-dynamics
study using the Frozen Phonon approach.Comment: 17 pages, 7 figures. Phys. Rev. B, in pres
Porous ferroelectrics for energy harvesting applications
This paper provides an overview of energy harvesting using ferroelectric materials, with a particular focus on the energy harvesting capabilities of porous ferroelectric ceramics for both piezo- and pyroelectric harvesting. The benefits of introducing porosity into ferro- electrics such as lead zirconate titanate (PZT) has been known for over 30 years, but the potential advantages for energy harvesting from both ambient vibrations and temperature fluctuations have not been studied in depth. The article briefly discusses piezoelectric and pyro- electric energy harvesting, before evaluating the potential benefits of porous materials for increasing energy harvesting figures of merits and electromechanical/electrothermal coupling factors. Established processing routes are evaluated in terms of the final porous structure and the resulting effects on the electrical, thermal and mechanical properties
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