527 research outputs found
Revisiting the valence-band and core-level photoemission spectra of NiO
We have re-examined the valence-band (VB) and core-level electronic structure
of NiO by means of hard and soft x-ray photoemission spectroscopy (PES). The
spectral weight of the lowest energy state found to be enhanced in the bulk
sensitive Ni 2p core-level PES. A configuration-interaction model including the
bound state screening has shown significant agreement with the core-level
spectra, and the off and on-resonance VB spectra. These results identify the
lowest energy state in core-level and VB-PES as the Zhang-Rice doublet bound
state, consistent with the spin-fermion model and recent ab initio calculation
with dynamical mean-field theory (LDA + DMFT).Comment: 4 pages, 3 figure
Expression of GABAergic Receptors in Mouse Taste Receptor Cells
) while it is terminated by the re-uptake of GABA through transporters (GATs).- immunoreactivity were detected in the peripheral taste receptor cells. We also used transgenic mice that express green fluorescent protein (GFP) in either the Type II taste cells, which can respond to bitter, sweet or umami taste stimuli, or in the Type III GAD67 expressing taste cells. Thus, we were able to identify that GABAergic receptors are expressed in some Type II and Type III taste cells. Mouse GAT4 labeling was concentrated in the cells surrounding the taste buds with a few positively labeled TRCs at the margins of the taste buds.The presence of GABAergic receptors localized on Type II and Type III taste cells suggests that GABA is likely modulating evoked taste responses in the mouse taste bud
Strong valence fluctuation in the quantum critical heavy fermion superconductor beta-YbAlB4: A hard x-ray photoemission study
Electronic structures of the quantum critical superconductor beta-YbAlB4 and
its polymorph alpha-YbAlB4 are investigated by using bulk-sensitive hard x-ray
photoemission spectroscopy. From the Yb 3d core level spectra, the values of
the Yb valence are estimated to be ~2.73 and ~2.75 for alpha- and beta-YbAlB4,
respectively, thus providing clear evidence for valence fluctuations. The
valence band spectra of these compounds also show Yb2+ peaks at the Fermi
level. These observations establish an unambiguous case of a strong mixed
valence at quantum criticality for the first time among heavy fermion systems,
calling for a novel scheme for a quantum critical model beyond the conventional
Doniach picture in beta-YbAlB4.Comment: 4 pages, 3 figures, revised version accepted for publication in PR
Inelastic neutron scattering studies of Crystal Field Levels in PrOsAs
We use neutron scattering to study the Pr crystalline electric field
(CEF) excitations in the filled skutterudite PrOsAs. By comparing
the observed levels and their strengths under neutron excitation with the
theoretical spectrum and neutron excitation intensities, we identify the
Pr CEF levels, and show that the ground state is a magnetic
triplet, and the excited states ,
and are at 0.4, 13 and 23 meV, respectively. A comparison of the
observed CEF levels in PrOsAs with the heavy fermion superconductor
PrOsSb reveals the microscopic origin of the differences in the
ground states of these two filled skutterudites.Comment: 7 pages, 7 figure
Temperature dependent Eu 3d-4f X-ray Absorption and Resonant Photoemission Study of the Valence Transition in
We study the mixed valence transition ( 80 K) in
EuNi(SiGe) using Eu 3 X-ray absorption
spectroscopy (XAS) and resonant photoemission spectroscopy (RESPES). The
Eu and Eu main peaks show a giant resonance and the spectral
features match very well with atomic multiplet calculations. The spectra show
dramatic temperature ()-dependent changes over large energies (10 eV)
in RESPES and XAS. The observed non-integral mean valencies of 2.35
0.03 ( = 120 K) and 2.70 0.03 ( = 40 K) indicate homogeneous
mixed valence above and below . The redistribution between
Eu+ and Eu+ states is attributed to
a hybridization change coupled to a Kondo-like volume collapse.Comment: 4 pages, 3 figure
Temperature-Dependence of Magnetically-Active Charge Excitations in Magnetite across the Verwey Transition
We have studied the electronic structure of bulk single crystals and
epitaxial films of magnetite FeO. Fe core-level spectra show clear
differences between hard x-ray (HAX-) and soft x-ray (SX-) photoemission
spectroscopy (PES), indicative of surface effects. The bulk-sensitive spectra
exhibit temperature ()-dependent charge excitations across the Verwey
transition at =122 K, which is missing in the surface-sensitive spectra.
An extended impurity Anderson model full-multiplet analysis reveals roles of
the three distinct Fe-species (A-Fe, B-Fe, B-Fe) below
for the Fe spectra, and its dependent evolution. The Fe
HAXPES spectra show a clear magnetic circular dichroism (MCD) in the metallic
phase of magnetized 100-nm-thick films. The model calculations also reproduce
the MCD and identify the magnetically distinct sites associated with the charge
excitations. Valence band HAXPES shows finite density of states at for
the polaronic metal with remnant order above , and a clear gap formation
below . The results indicate that the Verwey transition is driven by
changes in the strongly correlated and magnetically active B-Fe and
B-Fe electronic states, consistent with resistivity and bulk-sensitive
optical spectra.Comment: 5 pages, 4 figures Accepted in Physical Review Letter
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