Collisional broadening and spectral line shape of an entire rotational band

The impact approximation is applied to the classical binary collision operator making it possible to derive an expression for the dipole correlation function for real systems in a form which is computationally tractable and contains no adjustable parameters. Trajectory calculations are performed (in order to evaluate the microscopic expression for the relaxation parameter in the correlation function) for the system CO in dense Ar gas. Comparison is made with experimental data and excellent agreement is found for certain densities when a quantum correction is included. At higher densities (i.e., ρ^(−1/3)< "the range of the potential") one approximation is not valid and comparison with experiment illustrates this point

Semiclassical collision theory. Multidimensional Bessel uniform approximation

A multidimensional Bessel uniform approximation for the semiclassical S matrix is derived for the case of four real stationary phase points. A formula is also developed for the particular case when four stationary phase points may be considered to be well separated in pairs. The latter equation is then used in the treatment of two real and two complex stationary phase points

Semiclassical collision theory. Application of multidimensional uniform approximations to the atom-rigid-rotor system

The multidimensional Bessel and Airy uniform approximations developed earlier in this series for the semiclassical S matrix are applied to the atom rigid−rotor system. The need is shown for (a) using a geoemetrical criterion for determining whether a stationary phase point (s.p.pt) is a maximum, minimum, or saddle point; (b) choosing a proper quadrilateral configuration of the s.p.pts. with the phases as nearly equal as possible; and (c) choosing a unit cell to favor near−separation of variables. (a) and (b) apply both to the Airy and to the Bessel uniform approximations, and (c) to the Bessel. The use of a contour plot both to understand and to facilitate the search in new cases is noted. The case of real and complex−valued stationary phase points is also considered, and the Bessel uniform−in−pairs approximation is applied. Comparison is made with exact quantum results. As in the one−dimensional case, the Bessel is an improvement over the Airy for ’’k = 0’’ transitions, while for other transitions they give similar results. Comparison in accuracy with the results of the integral method is also given. As a whole, the agreement can be considered to be reasonable. The improvement of the present over various more approximate results is shown

Cross-correlation trajectory study of V-V energy transfer in HF-HF and DF-DF

Results of a fully three‐dimensional classical trajectory calculation of vibrational energy transfer are presented for the collision of HF(v=1) with HF(v=1) and its deuterium analog. A cross‐correlation method, together with quasiclassical trajectories, is introduced to relate the changes in vibrational states of the two molecules to probabilities and rate constants. Multiple collisions are found to make an important contribution to the vibrational energy transfer cross‐sections for the present potential surface. Vibrational anharmonicity is shown to decrease the energy transfer rate constant by a factor of ten, by causing the process to be further from exact resonance. Excellent agreement with experiment is obtained for the HF–HF and DF–DF systems

Ground state spin and Coulomb blockade peak motion in chaotic quantum dots

We investigate experimentally and theoretically the behavior of Coulomb blockade (CB) peaks in a magnetic field that couples principally to the ground-state spin (rather than the orbital moment) of a chaotic quantum dot. In the first part, we discuss numerically observed features in the magnetic field dependence of CB peak and spacings that unambiguously identify changes in spin S of each ground state for successive numbers of electrons on the dot, N. We next evaluate the probability that the ground state of the dot has a particular spin S, as a function of the exchange strength, J, and external magnetic field, B. In the second part, we describe recent experiments on gate-defined GaAs quantum dots in which Coulomb peak motion and spacing are measured as a function of in-plane magnetic field, allowing changes in spin between N and N+1 electron ground states to be inferred.Comment: To appear in Proceedings of the Nobel Symposium 2000 (Physica Scripta

Energy Level Quasi-Crossings: Accidental Degeneracies or Signature of Quantum Chaos?

In the field of quantum chaos, the study of energy levels plays an important role. The aim of this review paper is to critically discuss some of the main contributions regarding the connection between classical dynamics, semi-classical quantization and spectral statistics of energy levels. In particular, we analyze in detail degeneracies and quasi-crossings in the eigenvalues of quantum Hamiltonians which are classically non-integrable. Summary: 1. Introduction; 2. Quasi-Crossing and Chaos; 3. Molecular Spectroscopy; 4. Nuclear Models; 4.1 Zirnbauer-Verbaashot-Weidenmuller Model; 4.2 Lipkin-Meshow-Glick Model; 5. Particle Physics and Field Theory; 6. Conclusions.Comment: 26 pages, Latex, 9 figures, to be published in International Journal of Modern Physics

Liquid encapsulated float zone process and apparatus

The process and apparatus for growing crystals using float zone techniques are described. A rod of crystalline materials is disposed in a cylindrical container, leaving a space between the rod and container walls. This space is filled with an encapsulant, selected to have a slightly lower melting point than the crystalline material. The rod is secured to a container end cap at one end and to a shaft at its other end. A piston slides over the rod and provides pressure to prevent loss of volatile components upon melting of the rod. Prior to melting the rod the container is first heated to melt the encapsulant, with any off-gas from this step being vented to a cavity behind the piston. The piston moves slightly forward owing to volume change upon melting of the encapsulant, and the vent passageway is closed. The container is then moved longitudinally through a heated zone to progressively melt sections of the rod as in conventional float zone processes. The float zone technique may be used in the microgravity environment of space