37,838 research outputs found
Quenching of fluorescence of aromatic molecules by graphene due to electron transfer
Investigations on the fluorescence quenching of graphene have been carried
out with two organic donor molecules, pyrene butanaoic acid succinimidyl ester
(PyBS, I) and oligo(p-phenylenevinylene) methyl ester (OPV-ester, II).
Absorption and photoluminescence spectra of I and II recorded in mixture with
increasing the concentrations of graphene showed no change in the former, but
remarkable quenching of fluorescence. The property of graphene to quench
fluorescence of these aromatic molecules is shown to be associated with
photo-induced electron transfer, on the basis of fluorescence decay and
time-resolved transient absorption spectroscopic measurements.Comment: 18 pages, 6 figure
Novel magnetic properties of graphene: Presence of both ferromagnetic and antiferromagnetic features and other aspects
Investigations of the magnetic properties of graphenes prepared by different
methods reveal that dominant ferromagnetic interactions coexist along with
antiferromagnetic interactions in all the samples. Thus, all the graphene
samples exhibit room-temperature magnetic hysteresis. The magnetic properties
depend on the number of layers and the sample area, small values of both
favoring larger magnetization. Molecular charge-transfer affects the magnetic
properties of graphene, interaction with a donor molecule such as
tetrathiafulvalene having greater effect than an electron-withdrawing molecule
such as tetracyanoethyleneComment: 16 pges, 5 figure
Measuring thermodynamic length
Thermodynamic length is a metric distance between equilibrium thermodynamic
states. Among other interesting properties, this metric asymptotically bounds
the dissipation induced by a finite time transformation of a thermodynamic
system. It is also connected to the Jensen-Shannon divergence, Fisher
information and Rao's entropy differential metric. Therefore, thermodynamic
length is of central interest in understanding matter out-of-equilibrium. In
this paper, we will consider how to define thermodynamic length for a small
system described by equilibrium statistical mechanics and how to measure
thermodynamic length within a computer simulation. Surprisingly, Bennett's
classic acceptance ratio method for measuring free energy differences also
measures thermodynamic length.Comment: 4 pages; Typos correcte
Structures and Electromagnetic Properties of New Metal-Ordered Manganites; RBaMn_{2}O_{6} (R = Y and Rare Earth Elements)
New metal-ordered manganites RBaMn_{2}O_{6} have been synthesized and
investigated in the structures and electromagnetic properties. RBaMn_{2}O_{6}
can be classified into three groups from the structural and electromagnetic
properties. The first group (R = La, Pr and Nd) has a metallic ferromagnetic
transition, followed by an A-type antiferromagnetic transition in
PrBaMn_{2}O_{6}. The second group (R = Sm, Eu and Gd) exhibits a charge-order
transition, followed by an antiferromagnetic long range ordering. The third
group (R = Tb, Dy and Ho) shows successive three phase transitions, the
structural, charge/orbital-order and magnetic transitions, as observed in
YBaMn_{2}O_{6}. Comparing to the metal-disordered manganites
(R^{3+}_{0.5}A^{2+}_{0.5})MnO_{3}, two remarkable features can be recognized in
RBaMn_{2}O_{6}; (1) relatively high charge-order transition temperature and (2)
the presence of structural transition above the charge-order temperature in the
third group. We propose a possible orbital ordering at the structural
transition, that is a possible freezing of the orbital, charge and spin degrees
of freedom at the independent temperatures in the third group. These features
are closely related to the peculiar structure that the MnO_{2} square-lattice
is sandwiched by the rock-salt layers of two kinds, RO and BaO with extremely
different lattice-sizes.Comment: 5 pages, 4 figures, submitted to J. Phys. Soc. Jp
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