22,818 research outputs found
Infrared absorption and emission characteristics of interstellar PAHs
The mid-infrared interstellar emission spectrum with features at 3.28, 6.2, 7.7, 8.7 and 11.3 microns is discussed in terms of the Polycyclic Aromatic Hydrocarbon (PAH) hypothesis, which is based on the suggestive, but inconclusive comparison between the interstellar emission spectrum with the infrared absorption and Raman spectra of a few PAHs. The fundamental vibrations of PAHs and PAH-like species which determine the IR and Raman properties are discussed. Interstellar IR band emission is due to relaxation from highly vibrationally excited PAHs excited by ultraviolet photons. The excitation/emission process is described and the IR fluorescence from one PAH, chrysene, is traced. Generally, there is sufficient energy to populate several vibrational levels in each mode. Molecular vibrational potentials are anharmonic and emission from these higher levels will fall at lower frequencies and produce weak features to the red of the stronger fundamentals. This process is also described and can account for some spectroscopic details of the interstellar emission spectra previously unexplained. Analysis of the interstellar spectrum shows that PAHs contain between 20 and 30 carbon atoms are responsible for the emission
The hydrogen coverage of interstellar PAHs
The rate at which the CH bond in interstellar Polycyclic Aromatic Hydrocarbons (PAHs) rupture due to the absorption of a UV photon has been calculated. The results show that small PAHs (less than or equal to 25 carbon atoms) are expected to be partially dehydrogenated in regions with intense UV fields, while large PAHs (greater than or equal to 25 atoms) are expected to be completely hydrogenated in those regions. Because estimate of the carbon content of interstellar PAHs lie in the range of 20 to 25 carbon atoms, dehydrogenation is probably not very important. Because of the absence of other emission features besides the 11.3 micrometer feature in ground-based 8 to 13 micrometer spectra, it has been suggested that interstellar PAHs are partially dehydrogenated. However, IRAS 8 to 22 micrometer spectra of most sources that show strong 7.7 and 11.2 micrometer emission features also show a plateau of emission extending from about 11.3 to 14 micrometer. Like the 11.3 micrometer feature, this new feature is attributed to the CH out of plane bending mode in PAHs. This new feature shows that interstellar PAHs are not as dehydrogenated as estimated from ground-based 8 to 13 micrometer spectra. It also constrains the molecular structure of interstellar PAHs. In particular, it seems that very condensed PAHs, such as coronene and circumcoronene, dominate the interstellar PAH mixture as expected from stability arguments
Role of geometrical symmetry in thermally activated processes in clusters of interacting dipolar moments
Thermally activated magnetization decay is studied in ensembles of clusters
of interacting dipolar moments by applying the master-equation formalism, as a
model of thermal relaxation in systems of interacting single-domain
ferromagnetic particles. Solving the associated master-equation reveals a
breakdown of the energy barrier picture depending on the geometrical symmetry
of structures. Deviations are most pronounced for reduced symmetry and result
in a strong interaction dependence of relaxation rates on the memory of system
initialization. A simple two-state system description of an ensemble of
clusters is developed which accounts for the observed anomalies. These results
follow from a semi-analytical treatment, and are fully supported by kinetic
Monte-Carlo simulations.Comment: 9 pages, 6 figure
Laser anemometer measurements of trailing vortices in water
A series of measurements of trailing vortices behind lifting hydrofoils is described. These measurements were made in the Caltech Free-Surface Water Tunnel, using a laser-Doppler velocimeter to measure two components of velocity in the vortex wake. Two different model planforms were tested, and measurements were made at several free-stream velocities and angles of attack for each. Velocity profiles were measured at distances downstream of the model of from five to sixty chord lengths. These measurements are the first results of a continuing experimental programme.
In § 3 of this paper, the theory of trailing vortices is discussed. The effects of ‘vortex wandering’ upon the measurements are computed, and the corrected results are seen to be in reasonable agreement with the theory
New broad 8Be nuclear resonances
Energies, total and partial widths, and reduced width amplitudes of 8Be
resonances up to an excitation energy of 26 MeV are extracted from a coupled
channel analysis of experimental data. The presence of an extremely broad J^pi
= 2^+ ``intruder'' resonance is confirmed, while a new 1^+ and very broad 4^+
resonance are discovered. A previously known 22 MeV 2^+ resonance is likely
resolved into two resonances. The experimental J^pi T = 3^(+)? resonance at 22
MeV is determined to be 3^-0, and the experimental 1^-? (at 19 MeV) and 4^-?
resonances to be isospin 0.Comment: 16 pages, LaTe
Richness and Abundance of Carabidae and Staphylinidae (Coleoptera), in Northeastern Dairy Pastures Under Intensive Grazing
Dairy cattle has become popular to dairy farmers in the Northeast looking for management schemes to cut production costs. Carabidae (ground beetles) and Staphylinidae (rove beetles) are indicators of habitat disturbances, such as drainage of wetlands, or grassland for grazing animals, and their monitoring could provide one measure of ecosystem sustainability if intensive management systems expand or intensify in the future. Our objective was assess the abundance and species richness of these two beetle families under intensive grazing throughout Pennsylvania, southern New York and Vermont. We collected 4365 ground beetles (83 species) and 4,027 rove beetles (79 species) by pitfall traps in three years in Pennsylvania. Nine ground beetle species, Amara aenea, Poecilus chalcites, Pterostichus melanarius, Bembidion quadrimaculatum oppositum, Amara familiaris, Poecilus lucublandus, Agonum muelleri, Bembidion obtusum and Bembidion mimus represented 80% of the Carabidae collected.
Five other species were new to Pennsylvania. Four rove beetle species, Philonthus cognatus, Meronera venustula, Amischa analis, and Philonthus various = (carbonarius), comprised 74% of the total Staphylinidae collected. Yearly distributions of the dominant species did not change significantly in the three years with A. aenea and P. cognatus being most abundant every year. A parasitic rove beetle, Aleochara tristis, was recovered for the first time in Pennsylvania and Vermont since its release in the 1960\u27s to control face fly, Musca autumnalis.
Similar results were found in New York and Vermont. We collected 1,984 ground beetles (68 species). Pterostichus melanarius was most abundant. Pterostichus vernalis was detected for the first time in the United States (Vermont). It was previously reported from Montreal, Canada. We collected 843 rove beetles (45 species). Philonthus cognatus was the most abundant rove beetle. In addition, Tachinus corticinus, previously known only from Canada, was discovered for the first time in the United States in Vermont.
Pastures in Pennsylvania were diverse, containing 14 species of forage plants and 17 weed species. Botanical composition was similar in New York and Vermont. Sixteen species of grasses and legumes made up 90% of the plant composition and 36 species of weeds made up the remainder. This diÂverse plant ecosystem may explain the richness of ground and rove beetles in northeastern U.S. pastures because the heterogeneity in the plant population provided additional resources which can support a rich assemblage of beetles. Monitoring richness and abundance of Carabidae and Staphylinidae over three years in Pennsylvania suggests intensive grazing systems are ecoÂlogically sustainable
An Alternative Parameterization of R-matrix Theory
An alternative parameterization of R-matrix theory is presented which is
mathematically equivalent to the standard approach, but possesses features
which simplify the fitting of experimental data. In particular there are no
level shifts and no boundary-condition constants which allows the positions and
partial widths of an arbitrary number levels to be easily fixed in an analysis.
These alternative parameters can be converted to standard R-matrix parameters
by a straightforward matrix diagonalization procedure. In addition it is
possible to express the collision matrix directly in terms of the alternative
parameters.Comment: 8 pages; accepted for publication in Phys. Rev. C; expanded Sec. IV,
added Sec. VI, added Appendix, corrected typo
Studies of the superconducting properties of Sn1-xInxTe (x=0.38 to 0.45) using muon-spin spectroscopy
The superconducting properties of Sn1-xInxTe (x = 0.38 to 0.45) have been
studied using magnetization and muon-spin rotation or relaxation (muSR)
measurements. These measurements show that the superconducting critical
temperature Tc of Sn1-xInxTe increases with increasing x, reaching a maximum at
around 4.8 K for x = 0.45. Zero-field muSR results indicate that time-reversal
symmetry is preserved in this material. Transverse-field muon-spin rotation has
been used to study the temperature dependence of the magnetic penetration depth
lambda(T) in the mixed state. For all the compositions studied, lambda(T) can
be well described using a single-gap s-wave BCS model. The magnetic penetration
depth at zero temperature lambda(0) ranges from 500 to 580 nm. Both the
superconducting gap Delta(0) at 0 K and the gap ratio Delta(0)/kBTc indicate
that Sn1-xInxTe (x = 0.38 to 0.45) should be considered as a superconductor
with intermediate to strong coupling.Comment: 7 pages, 6 figures, 3 table
Superconducting and normal-state properties of the noncentrosymmetric superconductor Re6Zr
We systematically investigate the normal and superconducting properties of
non-centrosymmetric ReZr using magnetization, heat capacity, and
electrical resistivity measurements. Resistivity measurements indicate
ReZr has poor metallic behavior and is dominated by disorder. ReZr
undergoes a superconducting transition at K. Magnetization measurements give a lower critical
field, mT. The
Werthamer-Helfand-Hohenberg model is used to approximate the upper critical
field T which is close to
the Pauli limiting field of 12.35 T and which could indicate singlet-triplet
mixing. However, low-temperature specific-heat data suggest that ReZr is
an isotropic, fully gapped s-wave superconductor with enhanced electron-phonon
coupling. Unusual flux pinning resulting in a peak effect is observed in the
magnetization data, indicating an unconventional vortex state.Comment: 11 pages, 7 figures, 2 table
Validation of magnetophonon spectroscopy as a tool for analyzing hot-electron effects in devices
It is shown that very high precision hot-electron magnetophonon experiments made on n+n−n+-GaAs sandwich device structures which are customized for magnetoresistance measurements can be very accurately modeled by a new Monte Carlo technique. The latter takes account of the Landau quantization and device architecture as well as material parameters. It is proposed that this combination of experiment and modeling yields a quantitative tool for the direct analysis of spatially localized very nonequilibrium electron distributions in small devices and low dimensional structures
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