34 research outputs found

    Uranium–Nitrogen Multiple Bonding: The Case of a Four-Coordinate Uranium(VI) Nitridoborate Complex

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    While uranium imido complexes are well established in the literature, complexes featuring a uranium nitride functionality are rare. Data pertaining to terminal uranium nitrides are limited to the spectroscopic observation of the binary uranium nitrides UN and NUN and the ternary nitride NUF[subscript 3] under matrix conditions. We are interested in the uranium nitride functional group as it incorporates metal-ligand multiple bonding, valence f orbitals, and redox activity
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