216 research outputs found
Energy Landscape and Overlap Distribution of Binary Lennard-Jones Glasses
We study the distribution of overlaps of glassy minima, taking proper care of
residual symmetries of the system. Ensembles of locally stable, low lying
glassy states are efficiently generated by rapid cooling from the liquid phase
which has been equilibrated at a temperature . Varying , we
observe a transition from a regime where a broad range of states are sampled to
a regime where the system is almost always trapped in a metastable glassy
state. We do not observe any structure in the distribution of overlaps of
glassy minima, but find only very weak correlations, comparable in size to
those of two liquid configurations.Comment: 7 pages, 5 figures, uses europhys-style. Minor notational changes,
typos correcte
Elasticity of highly cross-linked random networks
Starting from a microscopic model of randomly cross-linked particles with
quenched disorder, we calculate the Laudau-Wilson free energy S for arbitrary
cross-link densities. Considering pure shear deformations, S takes the form of
the elastic energy of an isotropic amorphous solid state, from which the shear
modulus can be identified. It is found to be an universal quantity, not
depending on any microscopic length-scales of the model.Comment: 6 pages, 5 figure
Goldstone fluctuations in the amorphous solid state
Goldstone modes in the amorphous solid state, resulting from the spontaneous
breaking of translational symmetry due to random localisation of particles, are
discussed. Starting from a microscopic model with quenched disorder, the broken
symmetry is identified to be that of relative translations of the replicas.
Goldstone excitations, corresponding to pure shear deformations, are
constructed from long wavelength distortions of the order parameter. The
elastic free energy is computed, and it is shown that Goldstone fluctuations
destroy localisation in two spatial dimensions, yielding a two-dimensional
amorphous solid state characterised by power-law correlations.Comment: 7 pages, 2 figure
Glassy states and microphase separation in cross-linked homopolymer blends
The physical properties of blends of distinct homopolymers, cross-linked
beyond the gelation point, are addressed via a Landau approach involving a pair
of coupled order-parameter fields: one describing vulcanisation, the other
describing local phase separation. Thermal concentration fluctuations, present
at the time of cross-linking, are frozen in by cross-linking, and the structure
of the resulting glassy fluctuations is analysed at the Gaussian level in
various regimes, determined by the relative values of certain physical
length-scales. The enhancement, due to gelation, of the stability of the blend
with respect to demixing is also analysed. Beyond the corresponding stability
limit, gelation prevents complete demixing, replacing it by microphase
separation, which occurs up to a length-scale set by the rigidity of the
network, as a simple variational scheme reveals.Comment: 7 pages, 6 figure
Goldstone-type fluctuations and their implications for the amorphous solid state
In sufficiently high spatial dimensions, the formation of the amorphous (i.e.
random) solid state of matter, e.g., upon sufficent crosslinking of a
macromolecular fluid, involves particle localization and, concommitantly, the
spontaneous breakdown of the (global, continuous) symmetry of translations.
Correspondingly, the state supports Goldstone-type low energy, long wave-length
fluctuations, the structure and implications of which are identified and
explored from the perspective of an appropriate replica field theory. In terms
of this replica perspective, the lost symmetry is that of relative translations
of the replicas; common translations remain as intact symmetries, reflecting
the statistical homogeneity of the amorphous solid state. What emerges is a
picture of the Goldstone-type fluctuations of the amorphous solid state as
shear deformations of an elastic medium, along with a derivation of the shear
modulus and the elastic free energy of the state. The consequences of these
fluctuations -- which dominate deep inside the amorphous solid state -- for the
order parameter of the amorphous solid state are ascertained and interpreted in
terms of their impact on the statistical distribution of localization lengths,
a central diagnostic of the the state. The correlations of these order
parameter fluctuations are also determined, and are shown to contain
information concerning further diagnostics of the amorphous solid state, such
as spatial correlations in the statistics of the localization characteristics.
Special attention is paid to the properties of the amorphous solid state in two
spatial dimensions, for which it is shown that Goldstone-type fluctuations
destroy particle localization, the order parameter is driven to zero, and
power-law order-parameter correlations hold.Comment: 20 pages, 3 figure
Orientational order and glassy states in networks of semiflexible polymers
Motivated by the structure of networks of cross-linked cytoskeletal
biopolymers, we study the orientationally ordered phases in two-dimensional
networks of randomly cross-linked semiflexible polymers. We consider permanent
cross-links which prescribe a finite angle and treat them as quenched disorder
in a semi-microscopic replica field theory. Starting from a fluid of
un-cross-linked polymers and small polymer clusters (sol) and increasing the
cross-link density, a continuous gelation transition occurs. In the resulting
gel, the semiflexible chains either display long range orientational order or
are frozen in random directions depending on the value of the crossing angle,
the crosslink concentration and the stiffness of the polymers. A crossing angle
leads to long range -fold orientational order, e.g.,
"hexatic" or "tetratic" for or , respectively.
The transition is discontinuous and the critical cross-link density depends on
the bending stiffness of the polymers and the cross-link geometry: the higher
the stiffness and the lower , the lower the critical number of cross-links.
In between the sol and the long range ordered state, we always observe a gel
which is a statistically isotropic amorphous solid (SIAS) with random
positional and random orientational localization of the participating polymers.Comment: 20 pages, added references, minor changes, final version as published
in PR
Universality and its Origins at the Amorphous Solidification Transition
Systems undergoing an equilibrium phase transition from a liquid state to an
amorphous solid state exhibit certain universal characteristics. Chief among
these are the fraction of particles that are randomly localized and the scaling
functions that describe the order parameter and (equivalently) the statistical
distribution of localization lengths for these localized particles. The purpose
of this Paper is to discuss the origins and consequences of this universality,
and in doing so, three themes are explored. First, a replica-Landau-type
approach is formulated for the universality class of systems that are composed
of extended objects connected by permanent random constraints and undergo
amorphous solidification at a critical density of constraints. This formulation
generalizes the cases of randomly cross-linked and end-linked macromolecular
systems, discussed previously. The universal replica free energy is
constructed, in terms of the replica order parameter appropriate to amorphous
solidification, the value of the order parameter is obtained in the liquid and
amorphous solid states, and the chief universal characteristics are determined.
Second, the theory is reformulated in terms of the distribution of local static
density fluctuations rather than the replica order parameter. It is shown that
a suitable free energy can be constructed, depending on the distribution of
static density fluctuations, and that this formulation yields precisely the
same conclusions as the replica approach. Third, the universal predictions of
the theory are compared with the results of extensive numerical simulations of
randomly cross-linked macromolecular systems, due to Barsky and Plischke, and
excellent agreement is found.Comment: 10 pages, including 3 figures (REVTEX
Soft random solids and their heterogeneous elasticity
Spatial heterogeneity in the elastic properties of soft random solids is
examined via vulcanization theory. The spatial heterogeneity in the
\emph{structure} of soft random solids is a result of the fluctuations
locked-in at their synthesis, which also brings heterogeneity in their
\emph{elastic properties}. Vulcanization theory studies semi-microscopic models
of random-solid-forming systems, and applies replica field theory to deal with
their quenched disorder and thermal fluctuations. The elastic deformations of
soft random solids are argued to be described by the Goldstone sector of
fluctuations contained in vulcanization theory, associated with a subtle form
of spontaneous symmetry breaking that is associated with the
liquid-to-random-solid transition. The resulting free energy of this Goldstone
sector can be reinterpreted as arising from a phenomenological description of
an elastic medium with quenched disorder. Through this comparison, we arrive at
the statistics of the quenched disorder of the elasticity of soft random
solids, in terms of residual stress and Lam\'e-coefficient fields. In
particular, there are large residual stresses in the equilibrium reference
state, and the disorder correlators involving the residual stress are found to
be long-ranged and governed by a universal parameter that also gives the mean
shear modulus.Comment: 40 pages, 7 figure
The integrated density of states of the random graph Laplacian
We analyse the density of states of the random graph Laplacian in the
percolating regime. A symmetry argument and knowledge of the density of states
in the nonpercolating regime allows us to isolate the density of states of the
percolating cluster (DSPC) alone, thereby eliminating trivially localised
states due to finite subgraphs. We derive a nonlinear integral equation for the
integrated DSPC and solve it with a population dynamics algorithm. We discuss
the possible existence of a mobility edge and give strong evidence for the
existence of discrete eigenvalues in the whole range of the spectrum.Comment: 4 pages, 1 figure. Supplementary material available at
http://www.theorie.physik.uni-goettingen.de/~aspel/data/spectrum_supplement.pd
Variational bounds for the shear viscosity of gelling melts
We study shear stress relaxation for a gelling melt of randomly crosslinked,
interacting monomers. We derive a lower bound for the static shear viscosity
, which implies that it diverges algebraically with a critical exponent
. Here, and are the critical exponents of
percolation theory for the correlation length and the gel fraction. In
particular, the divergence is stronger than in the Rouse model, proving the
relevance of excluded-volume interactions for the dynamic critical behaviour at
the gel transition. Precisely at the critical point, our exact results imply a
Mark-Houwink relation for the shear viscosity of isolated clusters of fixed
size.Comment: 5 pages; CHANGES: typos corrected, some references added; version as
publishe
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