9,134 research outputs found
Microscopic Theory of Rashba Interaction in Magnetic Metal
Theory of Rashba spin-orbit coupling in magnetic metals is worked out from
microscopic Hamiltonian describing d-orbitals. When structural inversion
symmetry is broken, electron hopping between -orbitals generates chiral
ordering of orbital angular momentum, which combines with atomic spin-orbit
coupling to result in the Rashba interaction. Rashba parameter characterizing
the interaction is band-specific, even reversing its sign from band to band.
Large enhancement of the Rashba parameter found in recent experiments is
attributed to the orbital mixing of 3d magnetic atoms with non-magnetic heavy
elements as we demonstrate by first-principles and tight-binding calculations.Comment: 5 pages, 2 figure
Dynamic Failure Properties of the Porcine Medial Collateral Ligament-Bone Complex for Predicting Injury in Automotive Collisions
The goal of this study was to model the dynamic failure properties of ligaments and their attachment sites to facilitate the development of more realistic dynamic finite element models of the human lower extremities for use in automotive collision simulations. Porcine medial collateral ligaments were chosen as a test model due to their similarities in size and geometry with human ligaments. Each porcine medial collateral ligament-bone complex (n = 12) was held in a custom test fixture placed in a drop tower to apply an axial impulsive impact load, applying strain rates ranging from 0.005 s-1 to 145 s-1. The data from the impact tests were analyzed using nonlinear regression to construct model equations for predicting the failure load of ligament-bone complexes subjected to specific strain rates as calculated from finite element knee, thigh, and hip impact simulations. The majority of the ligaments tested failed by tibial avulsion (75%) while the remaining ligaments failed via mid-substance tearing. The failure load ranged from 384 N to 1184 N and was found to increase with the applied strain rate and the product of ligament length and cross-sectional area. The findings of this study indicate the force required to rupture the porcine MCL increases with the applied bone-to-bone strain rate in the range expected from high speed frontal automotive collisions
Core-Shell Interface-Oriented Synthesis of Bowl-Structured Hollow Silica Nanospheres Using Self-Assembled ABC Triblock Copolymeric Micelles
© 2018 American Chemical Society. Hollow porous silica nanospheres (HSNs) are emerging classes of cutting-edge nanostructured materials. They have elicited much interest as carriers of active molecule delivery due to their amorphous chemical structure, nontoxic nature, and biocompatibility. Structural development with hierarchical morphology is mostly required to obtain the desired performance. In this context, large through-holes or pore openings on shells are desired so that the postsynthesis loading of active-molecule onto HSNs via a simple immersion method can be facilitated. This study reports the synthesis of HSNs with large through-holes or pore openings on shells, which are subsequently termed bowl-structured hollow porous silica nanospheres (BHSNs). The synthesis of BHSNs was mediated by the core-shell interfaces of the core-shell corona-structured micelles obtained from a commercially available ABC triblock copolymer (polystyrene-b-poly(2-vinylpyridine)-b-poly(ethylene oxide) (PS-P2VP-PEO)). In this synthesis process, polymer@SiO2 composite structure was formed because of the deposition of silica (SiO2) on the micelles' core. The P2VP block played a significant role in the hydrolysis and condensation of the silica precursor, i.e., tetraethylorthosilicate (TEOS) and then maintaining the shell's growth. The PS core of the micelles built the void spaces. Transmission electron microscopy (TEM) images revealed a spherical hollow structure with an average particle size of 41.87 ± 3.28 nm. The average diameter of void spaces was 21.71 ± 1.22 nm, and the shell thickness was 10.17 ± 1.68 nm. According to the TEM image analysis, the average large pore was determined to be 15.95 nm. Scanning electron microscopy (SEM) images further confirmed the presence of large single pores or openings in shells. These were formed as a result of the accumulated ethanol on the PS core acting to prevent the growth of silica
Gauge coupling renormalization in orbifold field theories
We investigate the gauge coupling renormalization in orbifold field theories
preserving 4-dimensional N=1 supersymmetry in the framework of 4-dimensional
effective supergravity. As a concrete example, we consider the 5-dimensional
Super-Yang-Mills theory on a slice of AdS_5. In our approach, one-loop gauge
couplings can be determined by the loop-induced axion couplings and the tree
level properties of 4-dimensional effective supergravity which are much easier
to be computed.Comment: 18 pages, JHEP style; 1-loop corrections to gauge kinetic functions
are fully computed, references are adde
Dynamic Changes in LSM Nanoparticles on YSZ: A Model System for Non-Stationary SOFC Cathode Behavior
The interaction between nanoparticles of strontium-doped lanthanum manganite (LSM) and single-crystal yttria-stabilized zirconia (YSZ) was investigated using atomic force microscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM)/energy-dispersive X-ray spectroscopy (EDX). Nanoparticles of LSM were deposited directly onto single-crystal YSZ (100) substrates using an ultrasonic spray nozzle. As samples were annealed from 850 to 1250 degrees C, nanoparticles gradually decreased in height and eventually disappeared completely. Subsequent reduction in H-2/H2O at 700 degrees C resulted in the reappearance of nanoparticles. Studies were carried out on identical regions of the sample, allowing the same nanoparticles to be characterized at different temperatures. Morphological changes indicate the formation of a thin layer of LSM, and XPS results support the observation by indicating an increase in signal from the La and Sr and a decrease in signal from the Y and Zr with increasing temperature. SEM/EDX was used to verify that the nanoparticles in the reduced sample contained La. The changes in the LSM/YSZ morphology may be important in explaining the nonstationary behavior observed in operating solid-oxide fuel cells (SOFCs). The thin layer of LSM initially results in poor cathode performance; reducing conditions then lead to film disruptions, indicating nano/microporosity, that increase oxygen ion diffusion and performance
Efficiency of Energy Transduction in a Molecular Chemical Engine
A simple model of the two-state ratchet type is proposed for molecular
chemical engines that convert chemical free energy into mechanical work and
vice versa. The engine works by catalyzing a chemical reaction and turning a
rotor. Analytical expressions are obtained for the dependences of rotation and
reaction rates on the concentrations of reactant and product molecules, from
which the performance of the engine is analyzed. In particular, the efficiency
of energy transduction is discussed in some detail.Comment: 4 pages, 4 fugures; title modified, figures 2 and 3 modified, content
changed (pages 1 and 4, mainly), references adde
Gauge Threshold Corrections in Warped Geometry
We discuss the Kaluza-Klein threshold correction to low energy gauge
couplings in theories with warped extra-dimension, which might be crucial for
the gauge coupling unification when the warping is sizable. Explicit
expressions of one-loop thresholds are derived for generic 5D gauge theory on a
slice of AdS_5, where some of the bulk gauge symmetries are broken by orbifold
boundary conditions and/or by bulk Higgs vacuum values. Effects of the mass
mixing between the bulk fields with different orbifold parities are included as
such mixing is required in some class of realistic warped unification models.Comment: 33 pages, 1 figure, 6 tables, invited contribution to New Journal of
Physics Focus Issue on 'Extra Space Dimensions
One loop gauge couplings in AdS5
We calculate the full 1-loop corrections to the low energy coupling of bulk
gauge boson in a slice of AdS5 which are induced by generic 5-dimensional
scalar, Dirac fermion, and vector fields with arbitrary Z_2 times Z_2' orbifold
boundary conditions. In supersymmetric limit, our results correctly reproduce
the results obtained by an independent method based on 4-dimensional effective
supergravity. This provides a nontrivial check of our results and assures the
regularization scheme-independence of the results.Comment: RevTeX, 22 pages, 2 figures, some typos corrected and notations
change
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