Toxic level hypergolic vapor detection sensor development

Development of an electrochemical sensor technology capable of PPB level hypergolic vapor sensing is reported. A portable instrument capable of meeting the design goals is described

Evaluation of present thermal barrier coatings for potential service in electric utility gas turbines

The resistance of present-day thermal barrier coatings to combustion gases found in electric utility turbines was assessed. The plasma sprayed coatings, both duplex and graded types, were primarily zirconia-based, although a calcium silicate was also evaluated. Both atmospheric burner rig tests and high pressure tests (135 psig) showed that several present-day thermal barrier coatings have a high potential for service in gas turbines burning the relatively clean GT No. 2 fuel. However, coating improvements are needed for use in turbines burning lower grade fuel such as residual oil. The duplex ZrO2.8Y2O3/NiCrA1Y coating was ranked highest and selected for near-term field testing, with Ca2SiO4/NiCrA1Y ranked second. Graded coatings show potential for corrosive turbine operating conditions and warrant further development. The coating degradation mechanisms for each coating system subjected to the various environmental conditions are also described

Electron emission: From the Fowler–Nordheim relation to the Child–Langmuir law

Universal voltage‐current characteristics are presented for a planar diode, showing the general transition from the Fowler–Nordheim relation to the Child–Langmuir law. These curves are normalized to the intrinsic scales that are constructed from the Fowler–Nordheim coefficients A, B. They provide an immediate assessment of the importance of the space charge effects, once the gap voltage, gap spacing, and the Fowler–Nordheim coefficients are specified. An example in the parameter regime of vacuum microelectronics is presented.  Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69957/2/PHPAEN-1-6-2082-1.pd

Advanced ceramic coating development for industrial/utility gas turbine applications

The effects of ceramic coatings on the lifetimes of metal turbine components and on the performance of a utility turbine, as well as of the turbine operational cycle on the ceramic coatings were determined. When operating the turbine under conditions of constant cooling flow, the first row blades run 55K cooler, and as a result, have 10 times the creep rupture life, 10 times the low cycle fatigue life and twice the corrosion life with only slight decreases in both specific power and efficiency. When operating the turbine at constant metal temperature and reduced cooling flow, both specific power and efficiency increases, with no change in component lifetime. The most severe thermal transient of the turbine causes the coating bond stresses to approach 60% of the bond strengths. Ceramic coating failures was studied. Analytic models based on fracture mechanics theories, combined with measured properties quantitatively assessed both single and multiple thermal cycle failures which allowed the prediction of coating lifetime. Qualitative models for corrosion failures are also presented

Recent developments in monolithic integration of InGaAsP/InP optoelectronic devices

Monolithically integrated optoelectronic circuits combine optical devices such as light sources (injection lasers and light emitting diodes) and optical detectors with solid-state semiconductor devices such as field effect transistors, bipolar transistors, and others on a single semiconductor crystal. Here we review some of the integrated circuits that have been realized and discuss the laser structures suited for integration with emphasis on the InGaAsP/InP material system. Some results of high frequency modulation and performance of integrated devices are discussed

Multipactor discharge on metals and dielectrics: Historical review and recent theories

This paper reviews the history of multipactor discharge theory, focusing on recent models of multipactor accessibility and saturation. Two cases are treated in detail: That of a first-order, two-surface multipactor, and that of a single-surface multipactor on a dielectric. In both cases, susceptibility curves are constructed to indicate the regions of external parameter space where multipactor is likely to occur, taking into account the dependence on surface materials, and the effects of space charge and cavity loading. In the case of a dielectric, multipactor is found to deliver about 1% of the rf power to the surface. The two cases are contrasted in light of experimental observations. © 1998 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/71019/2/PHPAEN-5-5-2120-1.pd