89 research outputs found
Electronic Characteristics of Quasi-2D Metallochloronitrides: Na(x)HfNCL (T_c=25 K)
Local density functional results are presented for the electron-doped
metallochloronitrides A(x)ZrNCl and A(x)HfNCl, A = Li or Na, which superconduct
up to 25K. The alkali non-stoichiometry is treated in a virtual crystal
approximation. The electronic structure is strongly two dimensional, especially
in the conduction band region occupied by the carriers, because the states are
formed from the in-plane orbitals d_xy, d_{x^2-y^2} of the metal ion and the
p_x, p_y orbitals of the N ion. We predict a change of behavior at a doping
level of x=0.3.Comment: To appear in Proc. HTS99 Conf., Miami 1999. Four revtex pages, 5
embedded postscript figure
Magnetism in Atomic-Sized Palladium Contacts and Nanowires
We have investigated Pd nanowires theoretically, and found that, unlike
either metallic or free atomic Pd, they exhibit Hund's rule magnetism. In long,
monoatomic wires, we find a spin moment of 0.7 Bohr magnetons per atom, whereas
for short, monoatomic wires between bulk leads, the predicted moment is about
0.3 Bohr magnetons per wire atom. In contrast, a coaxial (6,1) wire was found
to be nonmagnetic. The origin of the wire magnetism is analyzed.Comment: 6 pages, including 4 figure
Mechanism for bipolar resistive switching in transition metal oxides
We introduce a model that accounts for the bipolar resistive switching
phenomenom observed in transition metal oxides. It qualitatively describes the
electric field-enhanced migration of oxygen vacancies at the nano-scale. The
numerical study of the model predicts that strong electric fields develop in
the highly resistive dielectric-electrode interfaces, leading to a spatially
inhomogeneous oxygen vacancies distribution and a concomitant resistive
switching effect. The theoretical results qualitatively reproduce non-trivial
resistance hysteresis experiments that we also report, providing key validation
to our model.Comment: Accepted for publication in Physical Review B, 6 twocolumn pages, 5
figure
First-Order Insulator-to-Metal Mott Transition in the Paramagnetic 3D System GaTa4Se8
The nature of the Mott transition in the absence of any symmetry braking
remains a matter of debate. We study the correlation-driven insulator-to-metal
transition in the prototypical 3D Mott system GaTa4Se8, as a function of
temperature and applied pressure. We report novel experiments on single
crystals, which demonstrate that the transition is of first order and follows
from the coexistence of two states, one insulating and one metallic, that we
toggle with a small bias current. We provide support for our findings by
contrasting the experimental data with calculations that combine local density
approximation with dynamical mean-field theory, which are in very good
agreement.Comment: 5 pages and 4 figures. Supplemental material: 2 pages, 2 figure
Interchain interactions and magnetic properties of Li2CuO2
An effective Hamiltonian is constructed for an insulating cuprate with
edge-sharing chains Li2CuO2.The Hamiltonian contains the nearest and
next-nearest neighboring intrachain and zigzag-type interchain interactions.The
values of the interactions are obtained from the analysis of the magnetic
susceptibility, and this system is found to be described as coupled frustrated
chains.We calculate the dynamical spin correlation function S(q,\omega) by
using the exact diagonalization method, and show that the spectra of
S(q,\omega) are characterized by the zigzag-type interchain interactions. The
results of the recent inelastic neutron scattering experiment are discussed in
the light of the calculated spectra.Comment: 4 pages, 3 figures, RevTe
Direct observation of the influence of the As-Fe-As angle on the Tc of superconducting SmFeAsOF
The electrical resistivity, crystalline structure and electronic properties
calculated from the experimentally measured atomic positions of the compound
SmFeAsOF have been studied up to pressures ~20GPa. The
correlation between the pressure dependence of the superconducting transition
temperature (Tc) and crystallographic parameters on the same sample shows
clearly that a regular FeAs tetrahedron maximizes Tc, through
optimization of carrier transfer to the FeAs planes as indicated by the
evolution of the electronic band structures.Comment: 15pages, 4 figure
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