42 research outputs found
The order parameter-entropy relation in some universal classes: experimental evidence
The asymptotic behaviour near phase transitions can be suitably characterized
by the scaling of with , where is
the excess entropy and is the order parameter. As is obtained by
integration of the experimental excess specific heat of the transition , it displays little experimental noise so that the curve versus is better constrained than, say,
versus . The behaviour of for different
universality classes is presented and compared. In all cases, it clearly
deviates from being a constant. The determination of this function can then be
an effective method to distinguish asymptotic critical behaviour. For
comparison, experimental data for three very different systems, Rb2CoF4,
Rb2ZnCl4 and SrTiO3, are analysed under this approach. In SrTiO3, the function
does not deviate within experimental resolution from a straight
line so that, although Q can be fitted with a non mean-field exponent, the data
can be explained by a classical Landau mean-field behaviour. In contrast, the
behaviour of for the antiferromagnetic transition in Rb2CoF4 and
the normal-incommensurate phase transition in Rb2ZCl4 is fully consistent with
the asymptotic critical behaviour of the universality class corresponding to
each case. This analysis supports, therefore, the claim that incommensurate
phase transitions in general, and the ABX compounds in particular, in
contrast with most structural phase transitions, have critical regions large
enough to be observable.Comment: 13 pp. 9 ff. 2 tab. RevTeX. Submitted to J. Phys.: Cond. Matte
Reaktionskinetik in Glasschmelzen Abschlussbericht
SIGLEAvailable from TIB Hannover: F00B1193+a / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekBundesministerium fuer Bildung, Wissenschaft, Forschung und Technologie, Bonn (Germany); DLR Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Bonn (Germany)DEGerman