884 research outputs found
The Effect of varying Ground-state Aromaticity on the First Molecular Electronic Hyperpolarizabilites of Organic Donor-Acceptor Molecules
A series of compounds of the form 4-dimethylaminophenyl–polyene–acceptor, where the polyene ranges from nothing to all-trans-1,3,5-hexatriene and the acceptor is 2-nitrovinyl, formyl, or 2,2-dicyanovinyl has been prepared and their β values measured by solution electric-field-induced second-harmonic generation; these molecules, which lose only one aromatic resonance upon charge-transfer excitation, show enhanced β compared to bi-aromatic molecules with the same substitution and total conjugation length, such as 4-dimethylamino-4′-nitrostilbene (DANS), a well-known benchmark for high β organic molecules
The First Molecular Electronic Hyperpolarizabilities of Highly Polarizable Organic Molecules: 2,6-Di-tert-butylindoanilines
The first molecular hyperpolarizabilities (β) of a series of 2,6-di-tert-butylindoanilines, measured by electric-field-induced second harmonic generation are somewhat more sensitive to donor strength than was found for analogously substituted nitrostilbenes, and dimethylindoaniline has a β roughly twice that of its 2,6 di-tert-butylated analogue, measured in chloroform; solvatochromic measurements on the former compound suggest that this decrease in hyperpolarizability is consistent with a bound-solvent effect
Synthesis and First Hyperpolarizabilities of Acceptor-substituted β-apo-8’-Carotenal Derived Compounds
The synthesis and second-order nonlinear optical properties of acceptor-substituted biologically derived β-apo-8′-carotenal compounds are reported; electric field-induced second harmonic generation (EFISH) measurements give values of β(0) which are 2–6 times greater than for 4-N,N-dimethylamino-4′-nitrostilbene (DANS)
Universality of weakly bound dimers and Efimov trimers close to Li-Cs Feshbach resonances
We study the interspecies scattering properties of ultracold Li-Cs mixtures
in their two energetically lowest spin channels in the magnetic field range
between 800 G and 1000 G. Close to two broad Feshbach resonances we create
weakly bound LiCs dimers by radio-frequency association and measure the
dependence of the binding energy on the external magnetic field strength. Based
on the binding energies and complementary atom loss spectroscopy of three other
Li-Cs s-wave Feshbach resonances we construct precise molecular singlet and
triplet electronic ground state potentials using a coupled-channels
calculation. We extract the Li-Cs interspecies scattering length as a function
of the external field and obtain almost a ten-fold improvement in the precision
of the values for the pole positions and widths of the s-wave Li-Cs Feshbach
resonances as compared to our previous work [Pires \textit{et al.}, Phys. Rev.
Lett. \textbf{112}, 250404 (2014)]. We discuss implications on the Efimov
scenario and the universal geometric scaling for LiCsCs trimers
The dependence of the molecular first hyperpolarizabilities of merocyanines on ground-state polarization and length
We report here the dipole moment (µ) and first hyperpolarizability (β) determined by electric field-induced second harmonic generation, for several merocyanine dyes containing an 1,3,3-trimethylindoline heterocycle as a ‘donor’ in which the ‘acceptor’ end of the molecule and the polyene bridge length was systematically varied; dyes with hexamethine bridges gave positive β, while that with a dimethine bridge gave a negative β value
Creation of a dipolar superfluid in optical lattices
We show that by loading a Bose-Einstein condensate (BEC) of two different
atomic species into an optical lattice, it is possible to achieve a
Mott-insulator phase with exactly one atom of each species per lattice site. A
subsequent photo-association leads to the formation of one heteronuclear
molecule with a large electric dipole moment, at each lattice site. The melting
of such dipolar Mott-insulator creates a dipolar superfluid, and eventually a
dipolar molecular BEC.Comment: 4 pages, 2 eps figure
Feshbach spectroscopy and scattering properties of ultracold Li+Na mixtures
We have observed 26 interspecies Feshbach resonances at fields up to 2050 G
in ultracold Li+Na mixtures for different spin-state combinations.
Applying the asymptotic bound-state model to assign the resonances, we have
found that most resonances have d-wave character. This analysis serves as
guidance for a coupled-channel calculation, which uses modified interaction
potentials to describe the positions of the Feshbach resonances well within the
experimental uncertainty and to calculate their widths. The scattering length
derived from the improved interaction potentials is experimentally confirmed
and deviates from previously reported values in sign and magnitude. We give
prospects for Li+Na and predict broad Feshbach resonances suitable
for tuning.Comment: 8 pages, 4 figures, version as published in PR
Feshbach spectroscopy and analysis of the interaction potentials of ultracold sodium
We have studied magnetic Feshbach resonances in an ultracold sample of Na
prepared in the absolute hyperfine ground state. We report on the observation
of three s-, eight d-, and three g-wave Feshbach resonances, including a more
precise determination of two known s-wave resonances, and one s-wave resonance
at a magnetic field exceeding 200mT. Using a coupled-channels calculation we
have improved the sodium ground-state potentials by taking into account these
new experimental data, and derived values for the scattering lengths. In
addition, a description of the molecular states leading to the Feshbach
resonances in terms of the asymptotic-bound-state model is presented.Comment: 11 pages, 4 figure
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