Satellite Detection of Smoke Aerosols Over a Snow/Ice Surface by TOMS

The use of TOMS (Total Ozone Mapping Spectrometer) satellite data demonstrates the recently developed technique of using satellite UV radiance measurements to detect absorbing tropospheric aerosols is effective over snow/ice surfaces. Instead of the traditional single wavelength (visible or infrared) method of measuring tropospheric aerosols, this method takes advantage of the wavelength dependent reduction in the backscattered radiance due to the presence of absorbing aerosols over snow/ice surfaces. An example of the resulting aerosol distribution derived from TOMS data is shown for an August 1998 event in which smoke generated by Canadian forest fires drifts over and across Greenland. As the smoke plume moved over Greenland, the TOMS observed 380 nm reflectivity over the snow/ice surface dropped drastically from 90-100% down to 30-40%. To study the effects of this smoke plume in both the UV and visible regions of the spectrum, we compared a smoke-laden spectrum taken over Greenland by the high spectral resolution (300 to 800 nm) GOME instrument with one that is aerosol-free. We also discuss the results of modeling the darkening effects of various types of absorbing aerosols over snow/ice surfaces using a radiative transfer code. Finally, we investigated the history of such events by looking at the nearly twenty year record of TOMS aerosol index measurements and found that there is a large interannual variability in the amount of smoke aerosols observed over Greenland. This information will be available for studies of radiation and transport properties in the Arctic

Profile shape dependence in backscattered ultraviolet satellite retrievals of total ozone

Total ozone operational algorithms use climatological mean ozone profiles. When the actual ozone profiles have significantly different shapes versus the climatology and the solar zenith angles are large, retrieved total ozone will have an error. Recalibrated SBUV profiles are used to estimate this error. Preliminary results suggest that, on the average, the change and variation in significant profiles shapes can to a large degree be estimated by the SBUV derived profiles. Preliminary results suggest the average error in the report algorithm ozone trend (trend in reported ozone) from profile shape is relatively small during the north hemisphere winter (less than 2 percent) for solar zenith angles less than 82 degrees (for 60 degrees North Latitude)

Enhanced Deep Blue Aerosol Retrieval Algorithm: The Second Generation

The aerosol products retrieved using the MODIS collection 5.1 Deep Blue algorithm have provided useful information about aerosol properties over bright-reflecting land surfaces, such as desert, semi-arid, and urban regions. However, many components of the C5.1 retrieval algorithm needed to be improved; for example, the use of a static surface database to estimate surface reflectances. This is particularly important over regions of mixed vegetated and non- vegetated surfaces, which may undergo strong seasonal changes in land cover. In order to address this issue, we develop a hybrid approach, which takes advantage of the combination of pre-calculated surface reflectance database and normalized difference vegetation index in determining the surface reflectance for aerosol retrievals. As a result, the spatial coverage of aerosol data generated by the enhanced Deep Blue algorithm has been extended from the arid and semi-arid regions to the entire land areas

Detection of volcanic ash clouds from Nimbus 7/total ozone mapping spectrometer

Measured radiances from the Version 7 reprocessing of the Nimbus 7/total ozone mapping spectrometer (TOMS) 340- and 380-nm channels are used to detect absorbing particulates injected into the atmosphere after the El Chichon eruption on April 4, 1982. It is shown that while the single-channel reflectivity determined from the 380-nm channel is able to detect clouds and haze composed of nonabsorbing aerosols, the spectral contrast between the 340- and 380-nm channels is sensitive to absorbing particulates such as volcanic ash, desert dust, or smoke from biomass burning. In this paper the spectral contrast between these two channels is used to detect the volcanic ash injection into the atmosphere and to track its evolution for several days. The movement of the ash clouds is shown to be consistent with the motions expected from the National Centers for Environmental Prediction (NCEP)-derived balanced wind fields in the troposphere and lower stratosphere. The movement of the volcanic SO2 cloud detected from TOMS data was also in agreement with the NCEP wind at higher altitudes of up to 100–10 mbar. The vertical wind shear in the neighborhood of the eruption site resulted in a clear separation of the ash and SO2 clouds. The location and movement of the ash cloud are consistent with information obtained by the advanced very high resolution radiometer (AVHRR) instrument on board the NOAA 7 satellite and to ground reports of ash fall

Nimbus-7 TOMS Version 7 Calibration

This report describes an improved instrument characterization used for the Version 7 processing of the Nimbus-7 Total Ozone Mapping Spectrometer (TOMS) data record. An improved internal calibration technique referred to as spectral discrimination is used to provide long-term calibration precision of +/- 1%/decade in total column ozone amount. A revised wavelength scale results in a day one calibration that agrees with other satellite and ground-based measurements of total ozone, while a wavelength independent adjustment of the initial radiometric calibration constants provides good agreement with surface reflectivity measured by other satellite-borne ultraviolet measurements. The impact of other aspects of the Nimbus-7 TOMS instrument performance are also discussed. The Version 7 data should be used in all future studies involving the Nimbus-7 TOMS measurements of ozone. The data are available through the NASA Goddard Space Flight Center's Distributive Active Archive Center (DAAC)

Earth Probe Total Ozone Mapping Spectrometer (TOMS) Data Product User's Guide

Two data products from the Earth Probe Total Ozone Mapping Spectrometer (EP/TOMS) have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The EP/ TOMS began taking measurements on July 15, 1996. The instrument measures backscattered Earth radiance and incoming solar irradiance; their ratio is used in ozone retrievals. Changes in the reflectivity of the solar diffuser used for the irradiance measurement are monitored using a carousel of three diffusers, each exposed to the degrading effects of solar irradiation at different rates. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and the drift is less than 0.5 percent over the first year of data. The Level-2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level-3 product contains daily total ozone and reflectivity in a 1-degree latitude by 1.25 degrees longitude grid. Level-3 files containing estimates of LTVB at the Earth surface and tropospheric aerosol information are also available, Detailed descriptions of both HDF data-files and the CD-ROM product are provided

ADEOS Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

Two data products from the Total Ozone Mapping Spectrometer (ADEOS/TOMS) have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The ADEOS/ TOMS began taking measurements on September 11, 1996, and ended on June 29, 1997. The instrument measured backscattered Earth radiance and incoming solar irradiance; their ratio was used in ozone retrievals. Changes in the reflectivity of the solar diffuser used for the irradiance measurement were monitored using a carousel of three diffusers, each exposed to the degrading effects of solar irradiation at different rates. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values, solar zenith angles, and optical paths. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and the drift is less than 0.5 percent over the 9-month data record. The Level 2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level 3 product contains daily total ozone and reflectivity in a 1-degree latitude by 1.25 degrees longitude grid. The Level 3 files containing estimates of UVB at the Earth surface and tropospheric aerosol information will also be available. Detailed descriptions of both HDF data files and the CDROM product are provided

Trends in Global Tropospheric Ozone Inferred from a Composite Record of TOMS/OMI/MLS/OMPS Satellite Measurements and the MERRA-2 GMI Simulation

Past studies have suggested that ozone in the troposphere has increased globally throughout much of the 20th century due to increases in anthropogenic emissions and transport. We show, by combining satellite measurements with a chemical transport model, that during the last four decades tropospheric ozone does indeed indicate increases that are global in nature, yet still highly regional. Satellite ozone measurements from Nimbus-7 and Earth Probe Total Ozone Mapping Spectrometer (TOMS) are merged with ozone measurements from the Aura Ozone Monitoring Instrument/Microwave Limb Sounder (OMI/MLS) to determine trends in tropospheric ozone for 19792016. Both TOMS (19792005) and OMI/MLS (20052016) depict large increases in tropospheric ozone from the Near East to India and East Asia and further eastward over the Pacific Ocean. The 38-year merged satellite record shows total net change over this region of about +6 to +7 Dobson units (DU) (i.e., 15 %20 % of average background ozone), with the largest increase (4 DU) occurring during the 20052016 Aura period. The Global Modeling Initiative (GMI) chemical transport model with time-varying emissions is used to aid in the interpretation of tropospheric ozone trends for 19802016. The GMI simulation for the combined record also depicts the greatest increases of +6 to +7 DU over India and East Asia, very similar to the satellite measurements. In regions of significant increases in tropospheric column ozone (TCO) the trends are a factor of 22.5 larger for the Aura record when compared to the earlier TOMS record; for India and East Asia the trends in TCO for both GMI and satellite measurements are +3 DU decade(exp 1) or greater during 20052016 compared to about +1.2 to +1.4 DU decade(exp 1) for 19792005. The GMI simulation and satellite data also reveal a tropospheric ozone increases in +4 to +5 DU for the 38-year record over central Africa and the tropical Atlantic Ocean. Both the GMI simulation and satellite-measured tropospheric ozone during the latter Aura time period show increases of +3 DU decade1 over the N Atlantic and NE Pacific

Evaluation of Version 3 Total and Tropospheric Ozone Columns From Earth Polychromatic Imaging Camera on Deep Space Climate Observatory for Studying Regional Scale Ozone Variations

Discrete wavelength radiance measurements from the Deep Space Climate Observatory (DSCOVR) Earth Polychromatic Imaging Camera (EPIC) allows derivation of global synoptic maps of total and tropospheric ozone columns every hour during Northern Hemisphere (NH) Summer or 2 hours during Northern Hemisphere winter. In this study, we present version 3 retrieval of Earth Polychromatic Imaging Camera ozone that covers the period from June 2015 to the present with improved geolocation, calibration, and algorithmic updates. The accuracy of total and tropospheric ozone measurements from EPIC have been evaluated using correlative satellite and ground-based total and tropospheric ozone measurements at time scales from daily averages to monthly means. The comparisons show good agreement with increased differences at high latitudes. The agreement improves if we only accept retrievals derived from the EPIC 317 nm triplet and limit solar zenith and satellite looking angles to 70°. With such filtering in place, the comparisons of EPIC total column ozone retrievals with correlative satellite and ground-based data show mean differences within ±5-7 Dobson Units (or 1.5–2.5%). The biases with other satellite instruments tend to be mostly negative in the Southern Hemisphere while there are no clear latitudinal patterns in ground-based comparisons. Evaluation of the EPIC ozone time series at different ground-based stations with the correlative ground-based and satellite instruments and ozonesondes demonstrated good consistency in capturing ozone variations at daily, weekly and monthly scales with a persistently high correlation (r2 > 0.9) for total and tropospheric columns. We examined EPIC tropospheric ozone columns by comparing with ozonesondes at 12 stations and found that differences in tropospheric column ozone are within ±2.5 DU (or ∼±10%) after removing a constant 3 DU offset at all stations between EPIC and sondes. The analysis of the time series of zonally averaged EPIC tropospheric ozone revealed a statistically significant drop of ∼2–4 DU (∼5–10%) over the entire NH in spring and summer of 2020. This drop in tropospheric ozone is partially related to the unprecedented Arctic stratospheric ozone losses in winter-spring 2019/2020 and reductions in ozone precursor pollutants due to the COVID-19 pandemic

Global retrieval of stratospheric and tropospheric BrO columns from the Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) on board the Suomi-NPP satellite

Quantifying the global bromine monoxide (BrO) budget is essential to understand ozone chemistry better. In particular, the tropospheric BrO budget has not been well characterized. Here, we retrieve nearly a decade (February 2012–July 2021) of stratospheric and tropospheric BrO vertical columns from the Ozone Mapping and Profiling Suite Nadir Mapper (OMPS-NM) on board the Suomi National Polar-orbiting Partnership (Suomi-NPP) satellite. In quantifying tropospheric BrO enhancements from total slant columns, the key aspects involve segregating them from stratospheric enhancements and applying appropriate air mass factors. To address this concern and improve upon the existing methods, our study proposes an approach that applies distinct BrO vertical profiles based on the presence or absence of tropospheric BrO enhancement at each pixel, identifying it dynamically using a satellite-derived stratospheric-ozone–BrO relationship. We demonstrate good agreement for both stratosphere (r = 0.81–0.83) and troposphere (r = 0.50–0.70) by comparing monthly mean BrO vertical columns from OMPS-NM with ground-based observations from three stations (Lauder, Utqiaġvik, and Harestua). Although algorithm performance is primarily assessed at high latitudes, the OMPS-NM BrO retrievals successfully capture tropospheric enhancements not only in polar regions but also in extrapolar areas, such as the Rann of Kutch and the Great Salt Lake. We also estimate random uncertainties in the retrievals pixel by pixel, which can assist in quantitative applications of the OMPS-NM BrO dataset. Our BrO retrieval algorithm is designed for cross-sensor applications and can be adapted to other space-borne ultraviolet spectrometers, contributing to the creation of continuous long-term satellite BrO observation records.</p