Synthesis and characteristics of polyarylene ether sulfones

A method utilizing potassium carbonate/dimethyl acetamide, as base and solvent respectively, was used for the synthesis of several homopolymers and copolymers derived from various bisphenols. It is demonstrated that this method deviates from simple second order kinetics; this deviation being due to the heterogeneous nature of the reaction. Also, it is shown that a liquid induced crystallization process can improve the solvent resistance of these polymers. Finally, a Monte Carlo simulation of the triad distribution of monomers in nonequilibrium copolycondensation is discussed

Portraits of people with dementia : three case studies of creating portraits

Peer reviewedPreprin

Development and evaluation of a prototype global volcano surveillance system utilizing the ERTS-1 satellite data collection system

There are no author-identified significant results in this report

Galactic Cosmic Ray Origins and OB Associations: Evidence from SuperTIGER Observations of Elements 26_{26}Fe through 40_{40}Zr

We report abundances of elements from $_{26}$Fe to $_{40}$Zr in the cosmic radiation measured by the SuperTIGER (Trans-Iron Galactic Element Recorder) instrument during 55 days of exposure on a long-duration balloon flight over Antarctica. These observations resolve elemental abundances in this charge range with single-element resolution and good statistics. These results support a model of cosmic-ray origin in which the source material consists of a mixture of 19$^{+11}_{-6}$\% material from massive stars and $\sim$81\% normal interstellar medium (ISM) material with solar system abundances. The results also show a preferential acceleration of refractory elements (found in interstellar dust grains) by a factor of $\sim$4 over volatile elements (found in interstellar gas) ordered by atomic mass (A). Both the refractory and volatile elements show a mass-dependent enhancement with similar slopes.Comment: 9 pages, 12 figures, 2 tables, accepted by Ap

Impurity and quaternions in nonrelativistic scattering from a quantum memory

Models of quantum computing rely on transformations of the states of a quantum memory. We study mathematical aspects of a model proposed by Wu in which the memory state is changed via the scattering of incoming particles. This operation causes the memory content to deviate from a pure state, i.e. induces impurity. For nonrelativistic particles scattered from a two-state memory and sufficiently general interaction potentials in 1+1 dimensions, we express impurity in terms of quaternionic commutators. In this context, pure memory states correspond to null hyperbolic quaternions. In the case with point interactions, the scattering process amounts to appropriate rotations of quaternions in the frequency domain. Our work complements a previous analysis by Margetis and Myers (2006 J. Phys. A 39 11567--11581).Comment: 16 pages, no figure

Dark cloud cores and gravitational decoupling from turbulent flows

We test the hypothesis that the starless cores may be gravitationally bound clouds supported largely by thermal pressure by comparing observed molecular line spectra to theoretical spectra produced by a simulation that includes hydrodynamics, radiative cooling, variable molecular abundance, and radiative transfer in a simple one-dimensional model. The results suggest that the starless cores can be divided into two categories: stable starless cores that are in approximate equilibrium and will not evolve to form protostars, and unstable pre-stellar cores that are proceeding toward gravitational collapse and the formation of protostars. The starless cores might be formed from the interstellar medium as objects at the lower end of the inertial cascade of interstellar turbulence. Additionally, we identify a thermal instability in the starless cores. Under par ticular conditions of density and mass, a core may be unstable to expansion if the density is just above the critical density for the collisional coupling of the gas and dust so that as the core expands the gas-dust coupling that cools the gas is reduced and the gas warms, further driving the expansion.Comment: Submitted to Ap

Lack of evidence for MHC-unrestricted (atypical) recognition of mucin by mucinous pancreatic tumour-reactive T-cells

Cytotoxic T-cells generated against heterologous, mucinous pancreatic tumour cells were shown to recognize mucin in a major histocombatibility complex (MHC)-unrestricted fashion. In contrast, the present study demonstrates a typical allogeneic response of heterologous cytotoxic T-cells established against mucin-expressing pancreatic tumour cells. Heterologous cytotoxic T cells lysed targets that were used as stimulators and other targets that shared human leucocyte antigen (HLA) with the stimulator. These cytotoxic T-cells lysed mucin-expressing stimulator cells but not autologous tumour cells in spite of expressing mucin on their surface. Likewise, tumour-infiltrating CD4+T-cells proliferated against its own tumour cell target, while such T-cells did not respond to heterologous, mucin-expressing pancreatic tumour cells. Culturing heterologous tumour-specific cytotoxic T-cells with purified pancreatic tumour cell-mucin rendered them unresponsive to their target cells. Furthermore, purified mucin did not produce a mucin-specific response in mucinous pancreatic tumour patients' primary T-cells even in the presence of antigen-presenting cells. Our study finds no evidence for MHC-unrestricted recognition of mucin by pancreatic cancer patients' T-cells. © 2000 Cancer Research Campaig

Development of control systems for space shuttle vehicles, volume 1

Control of winged two-stage space shuttle vehicles was investigated. Control requirements were determined and systems capable of meeting these requirements were synthesized. Control requirements unique to shuttles were identified. It is shown that these requirements can be satisfied by conventional control logics. Linear gain schedule controllers predominate. Actuator saturations require nonlinear compensation in some of the control systems

Massive Elementary Particles and Black Holes

An outstanding problem posed by Einstein's general theory of relativity to the quantum theory of point particle fields is the fate of a massive point particle; for, in the classical solutions of Einstein's theory, such a system should be a black hole. We use exact results in a new approach to quantum gravity to show that this conclusion is obviated by quantum loop effects. Phenomenological implications are discussedComment: 11 pages; 1 figure; improved text relating to asymptotic safet