307 research outputs found
Localization-delocalization transition of a reaction-diffusion front near a semipermeable wall
The A+B --> C reaction-diffusion process is studied in a system where the
reagents are separated by a semipermeable wall. We use reaction-diffusion
equations to describe the process and to derive a scaling description for the
long-time behavior of the reaction front. Furthermore, we show that a critical
localization-delocalization transition takes place as a control parameter which
depends on the initial densities and on the diffusion constants is varied. The
transition is between a reaction front of finite width that is localized at the
wall and a front which is detached and moves away from the wall. At the
critical point, the reaction front remains at the wall but its width diverges
with time [as t^(1/6) in mean-field approximation].Comment: 7 pages, PS fil
Reaction-diffusion fronts with inhomogeneous initial conditions
Properties of reaction zones resulting from A+B -> C type reaction-diffusion
processes are investigated by analytical and numerical methods. The reagents A
and B are separated initially and, in addition, there is an initial macroscopic
inhomogeneity in the distribution of the B species. For simple two-dimensional
geometries, exact analytical results are presented for the time-evolution of
the geometric shape of the front. We also show using cellular automata
simulations that the fluctuations can be neglected both in the shape and in the
width of the front.Comment: 11 pages, 3 figures, submitted to J. Phys.
Critical behavior and Griffiths effects in the disordered contact process
We study the nonequilibrium phase transition in the one-dimensional contact
process with quenched spatial disorder by means of large-scale Monte-Carlo
simulations for times up to and system sizes up to sites. In
agreement with recent predictions of an infinite-randomness fixed point, our
simulations demonstrate activated (exponential) dynamical scaling at the
critical point. The critical behavior turns out to be universal, even for weak
disorder. However, the approach to this asymptotic behavior is extremely slow,
with crossover times of the order of or larger. In the Griffiths region
between the clean and the dirty critical points, we find power-law dynamical
behavior with continuously varying exponents. We discuss the generality of our
findings and relate them to a broader theory of rare region effects at phase
transitions with quenched disorder.Comment: 10 pages, 8 eps figures, final version as publishe
Formation of Liesegang patterns: A spinodal decomposition scenario
Spinodal decomposition in the presence of a moving particle source is
proposed as a mechanism for the formation of Liesegang bands. This mechanism
yields a sequence of band positions x_n that obeys the spacing law
x_n~Q(1+p)^n. The dependence of the parameters p and Q on the initial
concentration of the reagents is determined and we find that the functional
form of p is in agreement with the experimentally observed Matalon-Packter law.Comment: RevTex, 4 pages, 4 eps figure
Liesegang patterns: Effect of dissociation of the invading electrolyte
The effect of dissociation of the invading electrolyte on the formation of
Liesegang bands is investigated. We find, using organic compounds with known
dissociation constants, that the spacing coefficient, 1+p, that characterizes
the position of the n-th band as x_n ~ (1+p)^n, decreases with increasing
dissociation constant, K_d. Theoretical arguments are developed to explain
these experimental findings and to calculate explicitly the K_d dependence of
1+p.Comment: RevTex, 8 pages, 3 eps figure
Impact of immigrants on a multi-agent economical system
© 2018 Kaufmann et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. We consider a multi-agent model of a simple economical system and study the impacts of a wave of immigrants on the stability of the system. Our model couples a labor market with a goods market. We first create a stable economy with N agents and study the impact of adding n new workers in the system. The time to reach a new equilibrium market is found to obey a power law in n. The new wages and market prices are observed to decrease as 1/n, whereas the wealth of agents remains unchanged
Collective traffic-like movement of ants on a trail: dynamical phases and phase transitions
The traffic-like collective movement of ants on a trail can be described by a
stochastic cellular automaton model. We have earlier investigated its unusual
flow-density relation by using various mean field approximations and computer
simulations. In this paper, we study the model following an alternative
approach based on the analogy with the zero range process, which is one of the
few known exactly solvable stochastic dynamical models. We show that our theory
can quantitatively account for the unusual non-monotonic dependence of the
average speed of the ants on their density for finite lattices with periodic
boundary conditions. Moreover, we argue that the model exhibits a continuous
phase transition at the critial density only in a limiting case. Furthermore,
we investigate the phase diagram of the model by replacing the periodic
boundary conditions by open boundary conditions.Comment: 8 pages, 6 figure
Kinetics and scaling in ballistic annihilation
We study the simplest irreversible ballistically-controlled reaction, whereby
particles having an initial continuous velocity distribution annihilate upon
colliding. In the framework of the Boltzmann equation, expressions for the
exponents characterizing the density and typical velocity decay are explicitly
worked out in arbitrary dimension. These predictions are in excellent agreement
with the complementary results of extensive Monte Carlo and Molecular Dynamics
simulations. We finally discuss the definition of universality classes indexed
by a continuous parameter for this far from equilibrium dynamics with no
conservation laws
Band Formation during Gaseous Diffusion in Aerogels
We study experimentally how gaseous HCl and NH_3 diffuse from opposite sides
of and react in silica aerogel rods with porosity of 92 % and average pore size
of about 50 nm. The reaction leads to solid NH_4Cl, which is deposited in thin
sheet-like structures. We present a numerical study of the phenomenon. Due to
the difference in boundary conditions between this system and those usually
studied, we find the sheet-like structures in the aerogel to differ
significantly from older studies. The influence of random nucleation centers
and inhomogeneities in the aerogel is studied numerically.Comment: 7 pages RevTex and 8 figures. Figs. 4-8 in Postscript, Figs. 1-3 on
request from author
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