53 research outputs found
The dimpling in the CuO_2 planes of YBa_2Cu_3O_x (x=6.806-6.984, T=20-300 K) measured by yttrium EXAFS
The dimpling of the CuO_2 planes (spacing between the O2,3 and Cu2 layers) in
YBa_2Cu_3O_x has been measured as a function of oxygen concentration and
temperature by yttrium x-ray extended-fine-structure spectroscopy (EXAFS). The
relative variations of the dimpling with doping (x=6.806-6.984) and temperature
(20-300 K) are weak (within 0.05 AA), and arise mainly from displacements of
the Cu2 atoms off the O2,3 plane towards Ba. The dimpling appears to be
connected with the transition from the underdoped to the overdoped regimes at
x=6.95, and with a characteristic temperature in the normal state, T*=150 K.Comment: 6 pages, 2 ps figs, LaTEX, Elsevier Elsart styl
Metal-insulator crossover in the Boson-Fermion model in infinite dimensions
The Boson-Fermion model, describing a mixture of tightly bound electron pairs
and quasi-free electrons hybridized with each other via a charge exchange term,
is studied in the limit of infinite dimensions, using the Non-Crossing
Approximation within the Dynamical Mean Field Theory. It is shown that a
metal-insulator crossover, driven by strong pair fluctuations, takes place as
the temperature is lowered. It manifests itself in the opening of a pseudogap
in the electron density of states, accompanied by a corresponding effect in the
optical and dc conductivity.Comment: 4 pages, 3 figures, to be published in Phys. Rev. Let
Inelastic X-ray Scattering by Electronic Excitations in Solids at High Pressure
Investigating electronic structure and excitations under extreme conditions
gives access to a rich variety of phenomena. High pressure typically induces
behavior such as magnetic collapse and the insulator-metal transition in 3d
transition metals compounds, valence fluctuations or Kondo-like characteristics
in -electron systems, and coordination and bonding changes in molecular
solids and glasses. This article reviews research concerning electronic
excitations in materials under extreme conditions using inelastic x-ray
scattering (IXS). IXS is a spectroscopic probe of choice for this study because
of its chemical and orbital selectivity and the richness of information it
provides. Being an all-photon technique, IXS has a penetration depth compatible
with high pressure requirements. Electronic transitions under pressure in 3d
transition metals compounds and -electron systems, most of them strongly
correlated, are reviewed. Implications for geophysics are mentioned. Since the
incident X-ray energy can easily be tuned to absorption edges, resonant IXS,
often employed, is discussed at length. Finally studies involving local
structure changes and electronic transitions under pressure in materials
containing light elements are briefly reviewed.Comment: submitted to Rev. Mod. Phy
From ferromagnetism to spin-density wave: Magnetism in the two channel periodic Anderson model
The magnetic properties of the two-channel periodic Anderson model for
uranium ions, comprised of a quadrupolar and a magnetic doublet are
investigated through the crossover from the mixed-valent to the stable moment
regime using dynamical mean field theory. In the mixed-valent regime
ferromagnetism is found for low carrier concentration on a hyper-cubic lattice.
The Kondo regime is governed by band magnetism with small effective moments and
an ordering vector \q close to the perfect nesting vector. In the stable
moment regime nearest neighbour anti-ferromagnetism dominates for less than
half band filling and a spin density wave transition for larger than half
filling. is governed by the renormalized RKKY energy scale \mu_{eff}^2
^2 J^2\rho_0(\mu).Comment: 4 pages, RevTeX, 3 eps figure
Pressure induced high-spin to low-spin transition in FeS evidenced by x-ray emission spectroscopy
We report the observation of the pressure-induced high-spin to low-spin
transition in FeS using new high-pressure synchrotron x-ray emission
spectroscopy techniques. The transition is evidenced by the disappearance of
the low-energy satellite in the Fe K emission spectrum of FeS. Moreover,
the phase transition is reversible and closely related to the structural phase
transition from a manganese phosphide-like phase to a monoclinic phase. The
study opens new opportunities for investigating the electronic properties of
materials under pressure.Comment: ReVTeX, 4 pages, 3 figures inserted with epsfig. minor modifications
before submission to PR
Slow crossover in YbXCu4 intermediate valence compounds
We compare the results of measurements of the magnetic susceptibility Chi(T),
the linear coefficient of specific heat Gamma(T)=C(T)/T and 4f occupation
number nf(T) for the intermediate valence compounds YbXCu4 (X = Ag, Cd, In, Mg,
Tl, Zn) to the predictions of the Anderson impurity model, calculated in the
non-crossing approximation (NCA). The crossover from the low temperature Fermi
liquid state to the high temperature local moment state is substantially slower
in the compounds than predicted by the NCA; this corresponds to the
''protracted screening'' recently predicted for the Anderson Lattice. We
present results for the dynamic susceptibility, measured through neutron
scattering experiments, to show that the deviations between theory and
experiment are not due to crystal field effects, and we present
x-ray-absorption fine-structure (XAFS) results that show the local crystal
structure around the X atoms is well ordered, so that the deviations probably
do not arise from Kondo Disorder. The deviations may correlate with the
background conduction electron density, as predicted for protracted screening.Comment: Submitted to Physical Review B on June 7, 2000, accepted for
publication November 2, 2000. Changes to the original manuscript include: 1)
a discussion of the relation of the slow crossover to the conduction electron
density; 2) a discussion of the relation of the reported results to earlier
photoemission results; and, 3) minor editorial change
Possible charge inhomogeneities in the CuO2 planes of YBa2Cu3O6+x (x=0.25, 0.45, 0.65, 0.94) from pulsed neutron diffraction
The atomic pair distribution functions (PDF) of four powder samples of
YBa2Cu3O6+x (x=0.25, 0.45, 0.65, 0.94) at 15 K have been measured by means of
pulsed neutron diffraction. The PDF is modelled using a full-profile fitting
approach to yield structural parameters. In contrast to earlier XAFS work we
find no evidence of a split apical oxygen site. However, a slightly improved
fit over the average crystallographic model results when the planar Cu(2) site
is split along the z-direction. This is interpreted in terms of charge
inhomogeneities in the CuO2 planes.Comment: 8 pages, 3 figure
Superconductivity in Ce- and U-based "122" heavy-fermion compounds
This review discusses the heavy-fermion superconductivity in Ce- and U-based
compounds crystallizing in the body-centered tetragonal ThCr2Si2 structure.
Special attention will be paid to the theoretical background of these systems
which are located close to a magnetic instability.Comment: 12 pages, 9 figures. Invited topical review (special issue on "Recent
Developments in Superconductivity") Metadata and references update
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