2 research outputs found
Rapid Conversion from Carbohydrates to Large-Scale Carbon Quantum Dots for All-Weather Solar Cells
A great challenge for state-of-the-art
solar cells is to generate electricity in all weather. We present
here the rapid conversion of carbon quantum dots (CQDs) from carbohydrates
(including glucose, maltol, sucrose) for an all-weather solar cell,
which comprises a CQD-sensitized mesoscopic titanium dioxide/long-persistence
phosphor (<i>m</i>-TiO<sub>2</sub>/LPP) photoanode, a I<sup>–</sup>/I<sub>3</sub><sup>–</sup> redox electrolyte,
and a platinum counter electrode. In virtue of the light storing and
luminescent behaviors of LPP phosphors, the generated all-weather
solar cells can not only convert sunlight into electricity on sunny
days but persistently realize electricity output in all dark–light
conditions. The maximized photoelectric conversion efficiency is as
high as 15.1% for so-called all-weather CQD solar cells in dark conditions
A Universal Grain “Cage” to Suppress Halide Segregation of Mixed-Halide Inorganic Perovskite Solar Cells
Bandgap-tunable mixed-halide perovskites offer exciting
opportunities
to construct efficient multijunction tandem solar cells. However,
the ion migration always causes halide segregation, which inevitably
creates detrimental defects and deteriorates the photovoltaic performances.
Here, we report a universal caging strategy to suppress halide segregation
by in situ formation of conjugated covalent organic frameworks (COFs)
catalyzed by PbX2 (X = Br and I) during the formation of
mixed-halide perovskite. Through theoretical calculation and systematic
investigation, the strong electron-donating feature of COFs is shown
to effectively solidify the soft lattice and impede the iodide ion
transport from bulk to grain boundary, decelerating the light-induced
halide-demixing process. Finally, the nonradiative recombination is
significantly reduced, boosting efficiency up to 11.50% for an inorganic
CsPbIBr2 perovskite solar cell and 14.35% for a CsPbI2Br cell with a prolonged shelf life and an improved photostability