The Influence of Strain Aging at Different Temperatures on the Mechanical Properties of Cold-Drawn 10B21 Steel Combined with an Electron Microscope Study of the Structures

The effect of aging treatments at various temperatures on the mechanical properties and microstructure of 10B21 cold heading steel with a 20% reduction in area (ε = 0.1) was investigated. The mechanical properties were evaluated based on tensile tests and hardness tests, while the evolution of microstructure was observed by using an optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray diffraction (XRD). The results reveal that aging treatment enhance the strength and hardness of 10B21 cold heading steel after drawing, and the highest values of strength and hardness are attained at an aging temperature of 300 °C. Specifically, the yield and ultrahigh tensile strength after aging at 300 °C are measured at 620 MPa and 685 MPa, respectively, which are 30 MPa and 50 MPa higher than the cold-drawn sample. Moreover, the hardness after aging at 300 °C reaches 293 HV, which has an increase of 30 HV compared to the cold-drawn state. The improvement in mechanical properties may be related to the strain-aging mechanism and the increased density of dislocations. In addition, the analysis of the TEM results reveal that the presence of the second-phase Ti(C,N) contributes to pinning the dislocations, whereas the dislocations are pinned between the cementite (Fe3C) lamellar and stacked at the grain boundaries, leading to strain hardening of the material

Enrichment of High Arsenic Groundwater Controlled by Hydrogeochemical and Physical Processes in the Hetao Basin, China

Based on 447 samples collected from a shallow aquifer (depths from 0 to 150 m) in the Hetao Basin, Northern China, an integrated hydrogeochemical approach was used in this study to conceptualize the enrichment of high arsenic groundwater in the Hetao Basin. An unconventional method of distinguishing hydrogeochemical and physical processes from a dataset was tested by investigating the cumulative frequency distribution of ionic ratios expressed on a probability scale. By applying cumulative frequency distribution curves to characterize the distribution of ionic ratios throughout the Hetao Basin, hydrogeochemical indicators were obtained that distinguish the series of hydrogeochemical processes that govern groundwater composition. All hydrogeochemical processes can basically be classified as recharge intensity of groundwater, evaporation concentration intensity, and reductive degree controlling the spatial distribution of arsenic. By considering the three processes, we found that the concentration of arsenic was more than 10 μg/L when the (HCO3−+CO32−)/SO42− ratio was over 4.1 (strong reductive area). As the evaporation concentration intensity increased, the median value of arsenic increased from 10.74 to 382.7 μg/L in the median reductive area and rapidly increased from 89.11 to 461.45 μg/L in the strong reductive area. As the river recharge intensity increased (with the intensity index increasing from 0 to 5), the median value of arsenic dropped from 40.2 to 6.8 μg/L in the median reductive area and decreased more markedly from 219.85 to 23.73 μg/L in the strong reductive area. The results provide a new insight into the mechanism of As enrichment in groundwater

Spatial Distribution, Contamination Assessment and Origin of Soil Heavy Metals in the Danjiangkou Reservoir, China

Soil heavy metal contamination is crucial due to menacing food safety and mortal health. At present, with the fast advancement of urbanization and industrialization, heavy metals are increasingly released into the soil by anthropogenic activities, and the soil ecosystem contamination around the Danjiangkou Reservoir is directly associated with water quality security of the reservoir. In this paper, using 639 soil samples from the Danjiangkou Reservoir, Henan Province, China, we studied a variety of space distribution characteristics of heavy metals in soil. Geographic information system analysis (GIS), geo-accumulation index (Igeo), contamination factor (CF), principal component analysis (PCA) model, and positive matrix factorization (PMF) model were used together to recognize and quantify the distribution, contamination, and origin of heavy metals. We uncovered an exceptional variety of heavy metal concentrations among the tested soils: the mean arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), manganese (Mn), nickel (Ni), zinc (Zn), lead (Pb) and mercury (Hg) concentrations (14.54, 0.21, 18.69, 81.69, 898.42, 39.37, 79.50, 28.11, 0.04 mg/kg, respectively, in the topsoil (0–20 cm depth)), all exceed their background values. The mean Igeo value and CF values of these trace elements are both in descending order: Cd > Co > Mn > Ni > Pb > Zn > Cr > As > Hg. Cd was the highest contributor to the assessment of heavy metal pollution, with an average Igeo value over three, indicating that the study area is modestly contaminated by Cd. The PCA analysis and PMF model revealed three potential sources, including natural sources (PC1) for Cr, Co, Mn and Ni; agricultural sources (PC2) for Cd, Zn and Hg; and industrial emissions and transportation sources (PC3) for Pb. This study displays a map of heavy metal contamination in the eastern area topsoil of the Danjiangkou Reservoir, showing the most severe pollutant is Cd, which poses a threat to the water quality security of Danjiangkou Reservoir and provides a significant source identification for future contamination control

Loess Strata Distribution Characteristics and Paleoclimate Spatial Pattern during the Last Interglacial in the Luohe River Basin

Paleoclimate studies of loess in China have focused mostly on the time series of a single borehole or profile. However, research on loess strata and regional paleoenvironmental patterns could facilitate a deeper understanding of loess as a paleoenvironmental indicator and provide new insights into interpreting loess in sedimentary records of the paleoclimate. In this study, we determined the spatial pattern and regional characteristics of the paleoclimate during the Last Interglacial period in the Luohe River Basin, Shaanxi Province, China. We selected four representative boreholes in the study area (ZK04, ZK18, ZK13, and ZK19) from different landforms and zones, distributed from the northwest to the southeast, as well as three classic profiles (JB, JD, and LC). From north to south, comparative analyses were conducted of the loess strata, magnetic susceptibility, and grain size, and we analyzed the distribution characteristics of loess and paleosols in different geomorphological regions. The results showed that both the thickness and the sedimentation rate of loess in this river basin decreased from north to south. There were few paleosol horizons in the northern Liangmao area, but numerous such horizons in the southern plateau, and the degree of paleosol development increased from north to south. The magnetic susceptibility increased, whereas the particle composition tended to become thinner from north to south. The climate fluctuations of the Last Glacial recorded by the loess and paleosols in different regions were inconsistent

Distribution Characteristics and Formation Mechanisms of Highly Mineralized Groundwater in the Hetao Plain, Inner Mongolia

As the largest artesian irrigation area in northern China, the Hetao Plain is also one of the major grain-producing areas in China. Meanwhile, there is a large amount of highly mineralized groundwater resulting in the soil salinization and desertification in this region. In addition, this study also uses the traditional hydro-geochemical methods to investigate the spatial evolution characteristics and formation mechanisms of highly mineralized groundwater. The results indicate that there is a large amount of highly mineralized groundwater (salinity > 3 g/L) in the shallow aquifer over the Hetao Plain. As far as the spatial patterns are concerned, there are significant spatial differences. In accordance with the structural, paleogeographic, landform, and hydrogeological conditions, the highly mineralized groundwater in the Hetao Plain can be divided into five zones, namely, the front fan depression, the north bank of the Yellow River, Xishanzui, Hasuhai in the Hubao Plain, and Dalad banner on the south bank of the Yellow River. Among them, the highly mineralized groundwater of Xishanzui exhibits the largest value of the salinity > 10 g/L. The main cations are Mg2+ and Na+, while the main anions are Cl− and SO42−. Moreover, the groundwater in the highly mineralized area contains a large amount of I−. According to the analysis of Piper, Gibbs diagrams of groundwater, the proportion coefficients of various components and the indication of isotope, it can be seen that most of the chemical ions in groundwater in the highly mineralized zone come from evaporation-concentration, which are mainly affected by climate, sedimentary environment, hydrogeological conditions and hydrology. The source of high mineralization in Xishanzui are different from other high mineralization regions, and the highly mineralized groundwater in Xishanzui is formed by the infestation of deep underground salt brine. These results can provide scientific basis for the rational allocation of regional water resources and the promotion of water resources development and utilization

Climate change recorded by the grain size end member since MIS 3 in Jingbian area

As a typical multisource sediment, the grain size distribution of loess presents multi-peak distribution.End member analysis can be used to separate the end member components representing different sediment sources and sedimentary dynamics from the complex sediment size, which has been widely used in loess research.In this paper, Paterson parametric end member model was used to separate and explained the end member size of Sandaogou profile located in the southeastern margin of the Mu Us Desert.The analyzed results indicated that the Sandaogou loess in Jingbian was divided into four end members: EM1(8.93 μm) was the background dust; EM2(25.18 μm) was a component related to monsoon circulation.EM3(39.91 μm) and EM4(56.37 μm) were components related to winter wind.Among them, EM3 was the main component of loess in the loess plateau and EM4 was roughly the same grain size as modern sandstorms.Through the analysis of the curves of the end member components with age, the following conclusions were drawn: the profile recorded that the Jingbian area had experienced MIS 3(32.8-29.8 ka BP), LGM(29.8-22.8 ka BP), last deglacial(22.8-11.3 ka BP) and Holocene(8.7-1.7 ka BP) since MIS 3. Three climatic rapid change evented and cycles Dansgaard-Oeschger in deglaciation Heinrich 1(16.2-13.8 ka BP), Bølling-Allerød(13.8-12.8 ka BP) and Younger Dryas(12.8-11.3 ka BP) were recorded.The profile also recorded three major expansion-contraction cycles during last glacial period of the Mu Us Desert, and three dry sand events during the Holocene(8.7-8.2 ka, 6.0-5.0 ka, and 3.5-2.5 ka)