953 research outputs found
Structural and electronic properties of Al nanowires: an ab initio pseudopotential study
The stability and electronic structure of a single monatomic Al wire has been
studied using the ab initio pseudopotential method. The Al wire undergoes two
structural rearrangements under compression, i.e., zigzag configurations at
angles of and . The evolution of electronic structures of the Al
chain as a function of structural phase transition has been investigated. The
relationship between electronic structure and geometric stability is also
discussed. The 2p bands in the Al nanowire are shown to play a critical role in
its stability. The effects of density functionals (GGA and LDA) on cohesive
energy and bond length of Al nanostructures (dimmer, chains, and monolayers)
are also examined. The link between low dimensional 0D structure (dimmer) to
high dimensional 3D bulk Al is estimated. An example of optimized tip-suspended
finite atomic chain is presented to bridge the gap between hypothetical
infinite chains and experimental finite chains.Comment: 11 pages, 5 figure
Perdeuterated cyanobiphenyl liquid crystals for infrared applications
Perdeuterated 4'-pentyl-4-cyanobiphenyl (D5CB) was synthesized and its physical properties evaluated and compared to those of 5CB. D5CB retains physical properties similar to those of 5CB, such as phase transition temperatures, dielectric constants, and refractive indices. An outstanding feature of D5CB is that it exhibits a much cleaner and reduced infrared absorption. Perdeuteration, therefore, extends the usable range of liquid crystals to the mid infrared by significantly reducing the absorption in the near infrared, which is essential for telecom applications
Charged particles in a rotating magnetic field
We study the valence electron of an alkaline atom or a general charged
particle with arbitrary spin and with magnetic moment moving in a rotating
magnetic field. By using a time-dependent unitary transformation, the
Schr\"odinger equation with the time-dependent Hamiltonian can be reduced to a
Schr\"odinger-like equation with a time-independent effective Hamiltonian.
Eigenstates of the effective Hamiltonian correspond to cyclic solutions of the
original Schr\"odinger equation. The nonadiabatic geometric phase of a cyclic
solution can be expressed in terms of the expectation value of the component of
the total angular momentum along the rotating axis, regardless of whether the
solution is explicitly available. For the alkaline atomic electron and a strong
magnetic field, the eigenvalue problem of the effective Hamiltonian is
completely solved, and the geometric phase turns out to be a linear combination
of two solid angles. For a weak magnetic field, the same problem is solved
partly. For a general charged particle, the problem is solved approximately in
a slowly rotating magnetic field, and the geometric phases are also calculated.Comment: REVTeX, 13 pages, no figure. There are two minor errors in the
published version due to incorrect editing by the publisher. The "spin-1" in
Sec. I and the "spin 1" in Sec. II below Eq. (2c) should both be changed to
"spin" or "spin angular momentum". The preferred E-mail for correspondence is
[email protected] or [email protected]
Probing the interstellar medium and star formation of the Most Luminous Quasar at z=6.3
We report new IRAM/PdBI, JCMT/SCUBA-2, and VLA observations of the
ultraluminous quasar SDSSJ010013.02+280225.8 (hereafter, J0100+2802) at z=6.3,
which hosts the most massive supermassive black hole (SMBH) of 1.24x10^10 Msun
known at z>6. We detect the [C II] 158 m fine structure line and molecular
CO(6-5) line and continuum emission at 353 GHz, 260 GHz, and 3 GHz from this
quasar. The CO(2-1) line and the underlying continuum at 32 GHz are also
marginally detected. The [C II] and CO detections suggest active star formation
and highly excited molecular gas in the quasar host galaxy. The redshift
determined with the [C II] and CO lines shows a velocity offset of ~1000 km/s
from that measured with the quasar Mg II line. The CO (2-1) line luminosity
provides direct constraint on the molecular gas mass which is about
(1.0+/-0.3)x10^10 Msun. We estimate the FIR luminosity to be (3.5+/-0.7)x10^12
Lsun, and the UV-to-FIR spectral energy distribution of J0100+2802 is
consistent with the templates of the local optically luminous quasars. The
derived [C II]-to-FIR luminosity ratio of J0100+2802 is 0.0010+/-0.0002, which
is slightly higher than the values of the most FIR luminous quasars at z~6. We
investigate the constraint on the host galaxy dynamical mass of J0100+2802
based on the [C II] line spectrum. It is likely that this ultraluminous quasar
lies above the local SMBH-galaxy mass relationship, unless we are viewing the
system at a small inclination angle.Comment: 19 pages, 4 figures, published by the Astrophysical Journal, minimal
changes in acknowledgement to match the published versio
Surface Structure of √3x√3R 30 Cl/Ni(111) Determined Using Low-temperature Angle-Resolved-Photoemission Extended Fine Structure
A surface structural study of the √3 × √3 R30° Cl/Ni(111) adsorbate system was made using low-temperature angle-resolved photoemission extended fine structure. The experiments were performed along two emission directions, [111] and [110], and at two temperatures, 120 and 300 K. The multiple-scattering spherical-wave analysis determined that the Cl atom adsorbs in the fcc threefold hollow site, 1.837(8) Å above the first nickel layer, with a Cl-Ni bond length of 2.332(6) Å, and an approximate 5% contraction between the first and the second nickel layers (the errors in parentheses are statistical standard deviations only)
Differential transendothelial transport of adiponectin complexes
BACKGROUND: Adiponectin’s effects on systemic physiology and cell-specific responses are well-defined, but little is known about how this insulin-sensitizing and anti-inflammatory adipokine reaches its target cells. All molecules face active and passive transport limitations, but adiponectin is particularly noteworthy due to the diverse size range and high molecular weights of its oligomers. Additionally, its metabolic target organs possess a range of endothelial permeability. METHODS: Full-length recombinant murine adiponectin was produced and oligomer fractions isolated by gel filtration. Adiponectin complex sizes were measured by dynamic light scattering to determine Stokes radii. Transendothelial transport of purified oligomers was quantitatively assessed under a number of different conditions in vitro using murine endothelial cells and in vivo using several mouse models of altered endothelial function. RESULTS: Adiponectin oligomers exhibit large transport radii that limit transendothelial transport. Oligomerization is a significant determinant of flux across endothelial monolayers in vitro; low molecular weight adiponectin is preferentially transported. In vivo sampled sera from the heart, liver, and tail vein demonstrated significantly different complex distribution of lower molecular weight oligomers. Pharmacological interventions, such as PPARγ agonist treatment, differentially affect adiponectin plasma clearance and tissue uptake. Exercise induces enhanced adiponectin uptake to oxidative skeletal muscles, wherein adiponectin potently lowers ceramide levels. In total, endothelial barriers control adiponectin transport in a cell- and tissue-specific manner. CONCLUSIONS: Adiponectin oligomer efficacy in a given tissue may therefore be endothelial transport mediated. Targeting endothelial dysfunction in the metabolic syndrome through exercise and pharmaceuticals may afford an effective approach to increasing adiponectin’s beneficial effects
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Long-read sequencing reveals genomic structural variations that underlie creation of quality protein maize
Mutation of o2 doubles maize endosperm lysine content, but it causes an inferior kernel phenotype. Developing quality protein maize (QPM) by introgressing o2 modifiers (Mo2s) into the o2 mutant benefits millions of people in developing countries where maize is a primary protein source. Here, we report genome sequence and annotation of a South African QPM line K0326Y, which is assembled from single-molecule, real-time shotgun sequencing reads collinear with an optical map. We achieve a N50 contig length of 7.7 million bases (Mb) directly from long-read assembly, compared to those of 1.04 Mb for B73 and 1.48 Mb for Mo17. To characterize Mo2s, we map QTLs to chromosomes 1, 6, 7, and 9 using an F2 population derived from crossing K0326Y and W64Ao2. RNA-seq analysis of QPM and o2 endosperms reveals a group of differentially expressed genes that coincide with Mo2 QTLs, suggesting a potential role in vitreous endosperm formation.Open access journalThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]
Time evolution, cyclic solutions and geometric phases for general spin in an arbitrarily varying magnetic field
A neutral particle with general spin and magnetic moment moving in an
arbitrarily varying magnetic field is studied. The time evolution operator for
the Schr\"odinger equation can be obtained if one can find a unit vector that
satisfies the equation obeyed by the mean of the spin operator. There exist at
least cyclic solutions in any time interval. Some particular time
interval may exist in which all solutions are cyclic. The nonadiabatic
geometric phase for cyclic solutions generally contains extra terms in addition
to the familiar one that is proportional to the solid angle subtended by the
closed trace of the spin vector.Comment: revtex4, 8 pages, no figur
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Precipitation and Deposition of Aluminum-Containing Species in Tank Wastes
Aluminum-containing phases represent the most prevalent solids that can appear or disappear during the processing of radioactive tank wastes. Processes such as sludge washing and leaching are designed to dissolve Al-containing phases and thereby minimize the volume of high-level waste glass required to encapsulate radioactive sludges. Unfortunately, waste-processing steps that include evaporation can involve solutions that are supersaturated with respect to cementitious aluminosilicates that result in unwanted precipitation and scale formation. Of all the constituents of tank waste, limited solubility cementitious aluminosilicates have the greatest potential for clogging pipes and transfer lines, fouling highly radioactive components such as ion exchangers, and completely shutting down processing operations. For instance, deposit buildup and clogged drain lines experienced during the tank waste volume-reduction process at the Savannah River Site (SRS) required an evaporator to be shut down in October 1999. The Waste Processing Technology Section of Westinghouse Savannah River Company at SRS now is collaborating with team members from Pacific Northwest National Laboratory (PNNL) to verify the thermodynamic stability of aluminosilicate compounds under waste tank conditions in an attempt to solve the deposition and clogging problems. The primary objectives of this study are (1) to understand the major factors controlling precipitation, heterogeneous nucleation, and growth phenomena of relatively insoluble aluminosilicates; (2) to determine the role of organics for inhibiting aluminosilicate formation, and (3) to develop a predictive tool to control precipitation, scale formation, and cementation under tank waste processing conditions. The results of this work will provide crucial information for (1) avoiding problematical sludge processing steps and (2) identifying and developing effective technologies to process retrieved sludges and supernatants before ultimate vitrification of wastes
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