Inclusion agglomeration in electrified molten metal: thermodynamic consideration

The effect of electric current on inclusion agglomeration in molten metal has been investigated. It is found that the agglomeration is dependent on the electric current density, distance between inclusions and orientation of electric field. Electric current retards the agglomeration unless two inclusions are aligned along or closely to the current flow streamlines and the distance between inclusions is less than a critical value. The mechanism is also validated in the computation of cluster agglomeration. The numerical results provide a comprehensive indication for the current-induced inclusion removal and current-induced inclusion elongation. When the inclusions are in long-thin shape, the calculation predicts the current-induced microstructure alignment and current-induced microstructure refinement phenomena

A self-consistent Hartree-Fock approach for interacting bosons in optical lattices

A theoretical study of interacting bosons in a periodic optical lattice is presented. Instead of the commonly used tight-binding approach (applicable near the Mott insulating regime of the phase diagram), the present work starts from the exact single-particle states of bosons in a cubic optical lattice, satisfying the Mathieu equation, an approach that can be particularly useful at large boson fillings. The effects of short-range interactions are incorporated using a self-consistent Hartree-Fock approximation, and predictions for experimental observables such as the superfluid transition temperature, condensate fraction, and boson momentum distribution are presented.Comment: 12 pages, 15 figure file

Application of the z-transform to composite materials

Applications of the z-transform were made earlier to interfacial electron transfer involving semi-infinite solids, e.g., semiconductor/liquid and metal/liquid interfaces and scanning tunneling microscopy. It is shown how the method is readily adapted to treat composite materials, such as solid/solid interfaces or "molecular wire"/solid interfaces

Pressure effects on bimolecular recombination and unimolecular dissociation reactions

The treatment of pressure effects on bimolecular recombinations and unimolecular dissociations is discussed. The analysis of recombination and dissociation reactions is made by showing how the nonequilibrium energy (E) and angular momentum (J)-dependent steady-state population distribution functions for the two reactions are related to each other and to the equilibrium population distribution function at the given E and J. As a special case a strong collision model is then used for the collisional rotational angular momentum transfer, and a ladder model for the collisional energy transfer. An analytical result is obtained for states below the dissociation threshold. The extension to recombinations with two exit channels is described, for application to ozone formation and isotopic effects

On the theory of electron transfer reactions at semiconductor/liquid interfaces. II. A free electron model

Electron transfer reactions at semiconductor/liquid interfaces are studied using the Fermi Golden rule and a free electron model for the semiconductor and the redox molecule. Bardeen's method is adapted to calculate the coupling matrix element between the molecular and semiconductor electronic states where the effective electron mass in the semiconductor need not equal the actual electron mass. The calculated maximum electron transfer rate constants are compared with the experimental results as well as with the theoretical results obtained in Part I using tight-binding calculations. The results, which are analytic for an s-electron in the redox agent and reduced to a quadrature for pz- and dz2-electrons, add to the insight of the earlier calculations

An approximate theory of the ozone isotopic effects: Rate constant ratios and pressure dependence

The isotopic effects in ozone recombination reactions at low pressures are studied using an approximate theory which yields simple analytic expressions for the individual rate constant ratios, observed under “unscrambled” conditions. It is shown that the rate constant ratio between the two competing channels XYZ-->X+YZ and XYZ-->XY+Z is mainly determined by the difference of the zero-point energies of diatomic molecules YZ and XY and by the efficiency of the deactivation of the newly formed excited ozone molecules, whereas the mass-independent fractionation depends on a “nonstatistical” symmetry factor eta and the collisional deactivation efficiency. Formulas for the pressure effects on the enrichment and on the rate constant ratios are obtained, and the calculated results are compared with experiments and more exact calculations. In all cases, ratios of isotope rates and the pressure dependence of enrichments, the agreement is good. While the initial focus was on isotope effects in the formation of O3, predictions are made for isotope effects on ratios of rate constants in other reactions such as O+CO-->CO2, O+NO-->NO2, and O+SO-->SO2

Deviation of light curves of gamma-ray burst pulses from standard forms due to the curvature effect of spherical fireballs or uniform jets

As revealed previously, under the assumption that some pulses of gamma-ray bursts are produced by shocks in spherical fireballs or uniform jets of large opening angles, there exists a standard decay form of the profile of pulses arising from very narrow or suddenly dimming local (or intrinsic) pulses due to the relativistic curvature effect (the Doppler effect over the spherical shell surface). Profiles of pulses arising from other local pulses were previously found to possess a reverse S-feature deviation from the standard decay form. We show in this paper that, in addition to the standard decay form shown in Qin et al. (2004), there exists a marginal decay curve associated with a local $\delta$ function pulse with a mono-color radiation. We employ the sample of Kocevski et al. (2003) to check this prediction and find that the phenomenon of the reverse S-feature is common, when compared with both the standard decay form and the marginal decay curve. We accordingly propose to take the marginal decay curve (whose function is simple) as a criteria to check if an observed pulse could be taken as a candidate suffered from the curvature effect. We introduce two quantities $A_1$ and $A_2$ to describe the mentioned deviations within and beyond the $FWHM$ position of the decay phase, respectively. The values of $A_1$ and $A_2$ of pulses of the sample are calculated, and the result suggests that for most of these pulses their corresponding local pulses might contain a long decay time relative to the time scale of the curvature effect.Comment: 24 pages, 7 figures, 1 table accepted for publication in MNRA

Iterative Solutions for Low Lying Excited States of a Class of Schroedinger Equation

The convergent iterative procedure for solving the groundstate Schroedinger equation is extended to derive the excitation energy and the wave function of the low-lying excited states. The method is applied to the one-dimensional quartic potential problem. The results show that the iterative solution converges rapidly when the coupling $g$ is not too small.Comment: 14 pages, 4 figure

Groundstate with Zero Eigenvalue for Generalized Sombrero-shaped Potential in NN-dimensional Space

Based on an iterative method for solving the goundstate of Schroedinger equation, it is found that a kind of generalized Sombrero-shaped potentials in N-dimensional space has groundstates with zero eigenvalue. The restrictions on the parameters in the potential are discussed.Comment: 8 pages, 3 figure