Melt Pond Retrieval Based on the LinearPolar Algorithm Using Landsat Data

The formation and distribution of melt ponds have an important influence on the Arctic climate. Therefore, it is necessary to obtain more accurate information on melt ponds on Arctic sea ice by remote sensing. The present large-scale melt pond products, especially the melt pond fraction (MPF), still require verification, and using very high resolution optical satellite remote sensing data is a good way to verify the large-scale retrieval of MPF products. Unlike most MPF algorithms using very high resolution data, the LinearPolar algorithm using Sentinel-2 data considers the albedo of melt ponds unfixed. In this paper, by selecting the best band combination, we applied this algorithm to Landsat 8 (L8) data. Moreover, Sentinel-2 data, as well as support vector machine (SVM) and iterative self-organizing data analysis technique (ISODATA) algorithms, are used as the comparison and verification data. The results show that the recognition accuracy of the LinearPolar algorithm for melt ponds is higher than that of previous algorithms. The overall accuracy and kappa coefficient results achieved by using the LinearPolar algorithm with L8 and Sentinel-2A (S2), the SVM algorithm, and the ISODATA algorithm are 95.38% and 0.88, 94.73% and 0.86, and 92.40%and 0.80, respectively, which are much higher than those of principal component analysis (PCA) and Markus algorithms. The mean MPF (10.0%) obtained from 80 cases from L8 data based on the LinearPolar algorithm is much closer to Sentinel-2 (10.9%) than the Markus (5.0%) and PCA algorithms (4.2%), with a mean MPF difference of only 0.9%, and the correlation coefficients of the two MPFs are as high as 0.95. The overall relative error of the LinearPolar algorithm is 53.5% and 46.4% lower than that of the Markus and PCA algorithms, respectively, and the root mean square error (RMSE) is 30.9% and 27.4% lower than that of the Markus and PCA algorithms, respectively

A detection of the layered structure of nearby open clusters

We applied the newly developed rose diagram overlay method to detect the layered structure of 88 nearby open clusters ($\leq$500~pc) on the three projections after the distance correction of their member stars, based on the catalog in literature. The results show that with the rose diagram overlay method, a total of 74 clusters in our sample have a layered structure, while the remaining clusters are without a clear layered structure. We for the first time defined the layered structure parameters for the sample clusters. Meanwhile, we found that the layered circle core area ($s$) has a strong positive correlation with the number of cluster members, while the kernel instability index ($\eta$) has a strong negative correlation with the number of cluster members. Our study provides a novel perspective for the detection of the layered structure of open clusters.Comment: 11 pages, 9 figures, 6 tables, accepted for publication in A&

Searching for Variable Stars in the Open Cluster NGC 2355 and Its Surrounding Region

We have investigated the variable stars in the field surrounding NGC 2355 based on the time-series photometric observation data. More than 3000 CCD frames were obtained in the V band spread over 13 nights with the Nanshan One-meter Wide-field Telescope. We have detected 88 variable stars, containing 72 new variable stars and 16 known variable stars. By analyzing these light curves, we classified the variable stars as follows: 26 eclipsing binaries, 52 pulsating stars, 4 rotating variables, and 6 unclear type variable stars for which their periods are much longer than the time baseline chosen. Employing Gaia DR2 parallax, kinematics, and photometry, the cluster membership of these variable stars were also analyzed for NGC 2355. In addition to the 11 variable members reported by Cantat-Gaudin et al. (2018), we identify 4 more variable member candidates located at the outer region of NGC 2355 and showed homogeneity in space positions and kinematic properties with the cluster members. The main physical parameters of NGC 2355 estimated from the two-color and color-magnitude diagrams are log(age/yr) = 8.9, E(B - V) = 0.24 mag, and [Fe/H] = - 0.07 dex.Comment: 15 pages, 11 figures. 6 tables,Accepted for publication in A

Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(II)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions

A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions.Original publication is available at http://dx.doi.org/10.1039/C5DT03256

Effect of Berberine on PPAR α

Rhizoma coptidis, the root of Coptis chinensis Franch, has been used in China as a folk medicine in the treatment of diabetes for thousands of years. Berberine, one of the active ingredients of Rhizoma coptidis, has been reported to improve symptoms of diabetes and to treat experimental cardiac hypertrophy, respectively. The objective of this study was to evaluate the potential effect of berberine on cardiomyocyte hypertrophy in diabetes and its possible influence on peroxisome proliferator-activated receptor-α (PPARα)/nitric oxide (NO) signaling pathway. The cardiomyocyte hypertrophy induced by high glucose (25.5 mmol/L) and insulin (0.1 μmol/L) (HGI) was characterized in rat primary cardiomyocyte by measuring the cell surface area, protein content, and atrial natriuretic factor mRNA expression level. Protein and mRNA expression were measured by western blot and real-time RT-PCR, respectively. The enzymatic activity of NO synthase (NOS) was measured using a spectrophotometric assay, and NO concentration was measured using the Griess assay. HGI significantly induced cardiomyocyte hypertrophy and decreased the expression of PPARα and endothelial NOS at the mRNA and protein levels, which occurred in parallel with declining NOS activity and NO concentration. The effect of HGI was inhibited by berberine (0.1 to 100 μmol/L), fenofibrate (0.3 μmol/L), or L-arginine (100 μmol/L). MK886 (0.3 μmol/L), a selective PPARα antagonist, could abolish the effects of berberine and fenofibrate. NG-nitro-L-arginine-methyl ester (100 μmol/L), a NOS inhibitor, could block the effects of L-arginine, but only partially blocked the effects of berberine. These results suggest that berberine can blunt HGI-induced cardiomyocyte hypertrophy in vitro, through the activation of the PPARα/NO signaling pathway

Modulation of the optical properties of chiral porphyrin dimers by introducing bridged chiral amide-bonds

The d/l-enantiomers of a series of three Zn(II)tetraarylporphyrin dimers were synthesized and isolated by incorporating a bridging amide-bonded xanthene moiety at the para-position of one of the meso-aryl rings. The electronic structures and optical properties were modulated by incorporating chiral amino acid moieties into the amide-bonding moieties of the xanthene bridge that contain methyl, tolyl and 2-methylindole substituents. A cofacial dimer was formed in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) resulting in a significant red shift of the B band, due to a relative destabilization of the HOMO, which has large MO coefficients on the pyrrole nitrogens. The sign sequences observed in the B band region of the CD spectra due to the presence of the chiral amino acid moieties were modified due to this change in geometry. Significant CD intensity is also observed in the B band region of the CD spectra of anion radical species during in situ spectroelectrochemical measurements

Porphyrin dimers with a bridging chiral amide-bonded benzo-moiety

The facile synthesis and characterization of four porphyrin dimers which introduced stereomeric centers with chiral amide-bonded para- and meta-disubstituted benzo-moiety is reported. Trends in the electronic structures and optical and redox properties are analyzed through a comparison with theoretical calculations to explore the effect of positional isomerism of the bridging benzene rings

Abietane Diterpenoids Isolated from Clerodendrum bracteatum and Their Antioxidant and Cytotoxic Activities

Two new abietane diterpenoids (1,2), along with five known diterpenoids (3–7), were first isolated and purified from the stems of Clerodendrum bracteatum. The structures of the new compounds were established by extensive analysis of mass spectrometric and 1-D, 2-D NMR spectroscopic data. Their antioxidant activities were determined on DPPH radical scavenging and ABTS. The in vitro cytotoxic activities of the compounds were evaluated against the HL-60 and A549 cell lines by the MTT method

A detection of the layered structure of nearby open clusters

We applied the newly developed rose diagram overlay method to detect the layered structure of 88 nearby open clusters ($\leq$500~pc) on the three projections after the distance correction of their member stars, based on the catalog in literature. The results show that with the rose diagram overlay method, a total of 74 clusters in our sample have a layered structure, while the remaining clusters are without a clear layered structure. We for the first time defined the layered structure parameters for the sample clusters. Meanwhile, we found that the layered circle core area ($s$) has a strong positive correlation with the number of cluster members, while the kernel instability index ($\eta$) has a strong negative correlation with the number of cluster members. Our study provides a novel perspective for the detection of the layered structure of open clusters.Comment: 11 pages, 9 figures, 6 tables, accepted for publication in A&

Bioactive Diterpenoids from Clerodendrum kiangsiense

A new abeo-abietane diterpenoid, 12-methoxy-6,11,14,16-tetrahydroxy-17(15→16)-abeo-5,8,11,13-abietatetraen-3,7-dione (8), was isolated from the hydroalcoholic extract of the herb of Clerodendrum kiangsiense along with seven known diterpenoids (1–7). Their structures were identified on the basis of spectroscopic analyses including two-dimensional NMR and comparison with literature data. All of these compounds were evaluated for their cytotoxic activities against the growth of human cancer cells lines HL-60, SMMC-7721, A-549 and MCF-7 by the MTT assay. The results showed that cryptojaponol (4), fortunin E (6) and 8 exhibited significant cytotoxicity against four human cancer cell lines