Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives

In this work, we develop a sequential self-assembly approach to fabricate interpenetrated binary supramolecular nanofibers consisting of carbazole oligomer <b>1</b>–cobalt­(II) (<b>1</b>-Co²⁺) coordination nanofibers and oligomer <b>2</b> nanofibers for the sensitive detection of six classes of explosives. When exposed to peroxide explosives (e.g., H₂O₂), Co²⁺ in <b>1</b>-Co²⁺ coordination nanofibers can be reduced to Co⁺ that can transfer an electron to the excited <b>2</b> nanofibers and thereby quench their fluorescence. On the other hand, when exposed to the other five classes of explosives, the excited <b>2</b> nanofibers can transfer an electron to explosives to quench their fluorescence. On the basis of the distinct fluorescence quenching mechanisms, six classes of explosives can be sensitively detected. Herein, we provide a new strategy to design broad-band fluorescence sensors for a rich identification of threats

Discrimination of Five Classes of Explosives by a Fluorescence Array Sensor Composed of Two Tricarbazole-Nanostructures

In this work, we report a two-member fluorescence array sensor for the effective discrimination of five classes of explosives. This smallest array sensor is composed of tricarbazole-based nanofibers (sensor member <b>1</b>) and nanoribbons (sensor member <b>2</b>) deposited as two film bands in a quartz tube. On the basis of a simple comparison of the resulting fluorescence quenching ratios between two sensor members and the response reversibility upon exposure to vaporized explosives, five classes of explosives can be sensitively detected and easily discriminated. This array sensor that has only two sensor members and no complex data analysis represents a new design way for discrimination of a broad class of explosives