Removal of Arsenic (III) from groundwater applying a reusable Mg-Fe-Cl layered double hydroxide

BACKGROUND: Layered double hydroxide compounds (LDHs) have been applied for the removal of oxyanions including arsenate (As(V)). However, the aim of this present research is to develop a LDH to treat arsenite (As(III)). Both batch and column sorption studies were conducted to assess the effect of LDH dosage, contact time, solution pH and initial As(III) concentrations on the As(III) removal performance. The potential re-use of this sorbent was also investigated.<p></p> RESULTS: For 2 g L−1 of Mg-Fe-Cl LDH, As(III) in test solution can be reduced from 400 µg L−1 to <10 µg L−1 after a contact time of 2 h. High As(III) concentration in Bangladesh groundwater can be reduced to meet the national drinking water standards (<50 µg L−1). The maximum adsorption capacity of As(III) by Mg-Fe-Cl LDH is 14.6 mg g−1-LDH. Further, reusability of this sorbent was at least 20 cycles of regeneration with effective As(III) removal between 93.0 and 98.5%. Moreover, As(III) removal was unaffected by the solution pH but affected by the co-existing competing anions and concentration of As(III). Finally, the main mechanism of As(III) removal by Mg-Fe-Cl LDH was suggested to be chemical sorption together with anion and ligand exchange with interlayer Cl− and OH− ions.<p></p> CONCLUSION: High efficiency of sorption of As(III) by the developed Mg-Fe-Cl LDH was demonstrated in this study which is generally not the case for most other sorbent materials. Pilot-scale trials are needed to explore the suitability of full application of the developed Mg-Fe-Cl LDH for the removal of As(III).<p></p&gt

Comprehensive review of statistical methods for analysing patient-reported outcomes (PROs) used as primary outcomes in randomised controlled trials (RCTs) published by the UK’s Health Technology Assessment (HTA) journal (1997–2020)

Objectives: To identify how frequently patient-reported outcomes (PROs) are used as primary and/or secondary outcomes in randomised controlled trials (RCTs) and to summarise what statistical methods are used for the analysis of PROs. Design: Comprehensive review. Setting: RCTs funded and published by the United Kingdom’s (UK) National Institute for Health Research (NIHR) Health Technology Assessment (HTA) Programme. Data sources and eligibility: HTA reports of RCTs published between January 1997 and December 2020 were reviewed. Data extraction: Information relating to PRO use and analysis methods was extracted. Primary and secondary outcome measures: The frequency of using PROs as primary and/or secondary outcomes; statistical methods that were used for the analysis of PROs as primary outcomes. Results: In this review, 37.6% (114/303) of trials used PROs as primary outcomes, and 82.8% (251/303) of trials used PROs as secondary outcomes from 303 NIHR HTA reports of RCTs. In the 114 RCTs where the PRO was the primary outcome, the most used PRO was the Short-Form 36 (8/114); the most popular methods for multivariable analysis were linear mixed model (45/114), linear regression (29/114) and analysis of covariance (13/114); logistic regression was applied for binary and ordinal outcomes in 14/114 trials; and the repeated measures analysis was used in 39/114 trials. Conclusion: The majority of trials used PROs as primary and/or secondary outcomes. Conventional methods such as linear regression are widely used, despite the potential violation of their assumptions. In recent years, there is an increasing trend of using complex models (eg, with mixed effects). Statistical methods developed to address these violations when analysing PROs, such as beta-binomial regression, are not routinely used in practice. Future research will focus on evaluating available statistical methods for the analysis of PROs

Asymmetry of Strange Sea in Nucleons

Based on the finite-temperature field theory, we evaluate the medium effects in nucleon which can induce an asymmetry between quarks and antiquarks of the strange sea. The short-distance effects determined by the weak interaction can give rise to $\delta m\equiv \Delta m_s-\Delta m_{\bar s}$ where $\Delta m_{s(\bar s)}$ is the medium-induced mass of strange quark by a few KeV at most, but the long-distance effects by strong interaction are sizable. Our numerical results show that there exists an obvious mass difference between strange and anti-strange quarks, as large as 10-100 MeV.Comment: 15 latex pages, 3 figures, to appear in PR

Exact Solutions for Matter-Enhanced Neutrino Oscillations

The analogy between supersymmetric quantum mechanics and matter-enhanced neutrino oscillations is exploited to obtain exact solutions for a class of electron density profiles. This integrability condition is analogous to the shape-invariance in supersymmetric quantum mechanics. This method seems to be the most direct way to obtain the exact survival probabilities for a number of density profiles of interest, such as linear and exponential density profiles. The resulting neutrino amplitudes can also be utilized as comparison amplitudes for the uniform semiclassical treatment of neutrino propagation in arbitrary electron density profiles.Comment: Submitted to Physical Review D. Latex file, 8 pages. This paper is also available at http://nucth.physics.wisc.edu/preprints

Heavy quarkonium 2S states in light-front quark model

We study the charmonium 2S states $\psi'$ and $\eta_c'$, and the bottomonium 2S states $\Upsilon'$ and $\eta_b'$, using the light-front quark model and the 2S state wave function of harmonic oscillator as the approximation of the 2S quarkonium wave function. The decay constants, transition form factors and masses of these mesons are calculated and compared with experimental data. Predictions of quantities such as Br$(\psi' \to \gamma \eta_c')$ are made. The 2S wave function may help us learn more about the structure of these heavy quarkonia.Comment: 5 latex pages, final version for journal publicatio

Tri-meson-mixing of π\pi-η\eta-η′\eta' and ρ\rho-ω\omega-ϕ\phi in the light-cone quark model

The radiative transition form factors of the pseudoscalar mesons {$\pi$, $\eta$, $\eta'$} and the vector mesons {$\rho$, $\omega$, $\phi$} are restudied with $\pi$-$\eta$-$\eta'$ and $\rho$-$\omega$-$\phi$ in tri-meson-mixing pattern, which is described by tri-mixing matrices in the light-cone constituent quark model. The experimental transition decay widths are better reproduced with tri-meson-mixing than previous results in a two-mixing-angle scenario of only two-meson $\eta$-$\eta'$ mixing and $\omega$-$\phi$ mixing.Comment: 8 pages, 6 figures, final version to appear in EPJ

Three-dimensional parton distribution functions g1Tg_{1T} and h1L⊥h_{1L}^\perp in the polarized proton-antiproton Drell-Yan process

We present predictions of the unweighted and weighted double spin asymmetries related to the transversal helicity distribution $g_{1T}$ and the longitudinal transversity distribution $h_{1L}^\perp$, two of eight leading-twist transverse momentum dependent parton distributions (TMDs) or three-dimensional parton distribution functions (3dPDFs), in the polarized proton-antiproton Drell-Yan process at typical kinematics on the Facility for Antiproton and Ion Research (FAIR). We conclude that FAIR is ideal to access the new 3dPDFs towards a detailed picture of the nucleon structure.Comment: 6 latex pages, 5 figures, version for publication in EPJ

Constraints on the Variations of the Fundamental Couplings

We reconsider several current bounds on the variation of the fine-structure constant in models where all gauge and Yukawa couplings vary in an interdependent manner, as would be expected in unified theories. In particular, we re-examine the bounds established by the Oklo reactor from the resonant neutron capture cross-section of 149Sm. By imposing variations in \Lambda_{QCD} and the quark masses, as dictated by unified theories, the corresponding bound on the variation of the fine-structure constant can be improved by about 2 orders of magnitude in such theories. In addition, we consider possible bounds on variations due to their effect on long lived \alpha- and \beta-decay isotopes, particularly 147Sm and 187Re. We obtain a strong constraint on \Delta \alpha / \alpha, comparable to that of Oklo but extending to a higher redshift corresponding to the age of the solar system, from the radioactive life-time of 187Re derived from meteoritic studies. We also analyze the astrophysical consequences of perturbing the decay Q values on bound state \beta-decays operating in the s-process.Comment: 25 pages, latex, 5 eps figure

Properties of odd nuclei and the impact of time-odd mean fields: A systematic Skyrme-Hartree-Fock analysis

We present a systematic analysis of the description of odd nuclei by the Skyrme-Hartree-Fock approach augmented with pairing in BCS approximation and blocking of the odd nucleon. Current and spin densities in the Skyrme functional produce time-odd mean fields (TOMF) for odd nuclei. Their effect on basic properties (binding energies, odd-even staggering, separation energies and spectra) is investigated for the three Skyrme parameterizations SkI3, SLy6, and SV-bas. About 1300 spherical and axially-deformed odd nuclei with 16 < Z < 92 are considered. The calculations demonstrate that the TOMF effect is generally small, although not fully negligible. The influence of the Skyrme parameterization and the consistency of the calculations are much more important. With a proper choice of the parameterization, a good description of binding energies and their differences is obtained, comparable to that for even nuclei. The description of low-energy excitation spectra of odd nuclei is of varying quality depending on the nucleus

Extreme Ultra-Violet Spectroscopy of the Lower Solar Atmosphere During Solar Flares

The extreme ultraviolet portion of the solar spectrum contains a wealth of diagnostic tools for probing the lower solar atmosphere in response to an injection of energy, particularly during the impulsive phase of solar flares. These include temperature and density sensitive line ratios, Doppler shifted emission lines and nonthermal broadening, abundance measurements, differential emission measure profiles, and continuum temperatures and energetics, among others. In this paper I shall review some of the advances made in recent years using these techniques, focusing primarily on studies that have utilized data from Hinode/EIS and SDO/EVE, while also providing some historical background and a summary of future spectroscopic instrumentation.Comment: 34 pages, 8 figures. Submitted to Solar Physics as part of the Topical Issue on Solar and Stellar Flare