4,873 research outputs found
DC field induced enhancement and inhibition of spontaneous emission in a cavity
We demonstrate how spontaneous emission in a cavity can be controlled by the
application of a dc field. The method is specially suitable for Rydberg atoms.
We present a simple argument for the control of emission.Comment: 3-pages, 2figure. accepted in Phys. Rev.
Evaluation of different internal standards for precious metals quantification
The current study involved the evaluation of five different internal standards (Sc, Co, Y, In and La) as well as normal external or direct calibration methods in the simultaneous quantification of all six platinum group metals (PGMs) and gold (precious metals). The use of Sc as internal standard in the quantitative determination of precious metals in a liquid reference material (RM) and the geological Pyroxenite CRM was shown to yield excellent recoveries (> 99%) compared to the other metals used as internal standard in this study and the direct calibration method (> 91 %).Os recovered only 89% of the expected metal content. The evaluation of different proposed models (wavelength combinations, ionization and/or excitation energy) did not succeed in identifying or discriminating between the unsuccessful and successful internal standards. The robustness of the Sc internal standard addition method was evaluated with the variation in solution matrix (addition of HCl and NaCl). The analytical method (total metal recovery) proved to be very sensitive to elevated unmatched HCl matrix levels (above 1.0 mL of HCl (32% v/v) added) and Na+ addition larger than 4 ppm sodium using ICP-OES. KEY WORDS: Internal standard, Scandium, Precious metals, Spectrometric techniques, ICP-OES Bull. Chem. Soc. Ethiop. 2016, 30(1), 55-70.DOI: http://dx.doi.org/10.4314/bcse.v30i1.
Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ2 O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate
The title compound, [Rh(C10H7N2O2)(C18H15P)(CO)]·(CH3)2CO, is the second structural report of a metal complex formed with the O,O′-C10H7N2O2 (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenylphosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO2P coordination set which is best illustrated by the small O—Rh—O bite angle of 77.74 (10)°. There are no classical hydrogen-bond interactions observed for this complex
Magnetic field induced lattice anomaly inside the superconducting state of CeCoIn: evidence of the proposed Fulde-Ferrell-Larkin-Ovchinnikov state
We report high magnetic field linear magnetostriction experiments on
CeCoIn single crystals. Two features are remarkable: (i) a sharp
discontinuity in all the crystallographic axes associated with the upper
superconducting critical field that becomes less pronounced as the
temperature increases; (ii) a distinctive second order-like feature observed
only along the c-axis in the high field (10 T ) low
temperature ( 0.35 K) region. This second order transition is
observed only when the magnetic field lies within 20 of the ab-planes and
there is no signature of it above , which raises questions regarding
its interpretation as a field induced magnetically ordered phase. Good
agreement with previous results suggests that this anomaly is related to the
transition to the Fulde-Ferrel-Larkin-Ovchinnikov superconducting state.Comment: 3 figures, 5 page
Diffuse Galactic Soft Gamma-Ray Emission
The Galactic diffuse soft gamma-ray (30-800 keV) emission has been measured
from the Galactic Center by the HIREGS balloon-borne germanium spectrometer to
determine the spectral characteristics and origin of the emission. The
resulting Galactic diffuse continuum is found to agree well with a single
power-law (plus positronium) over the entire energy range, consistent with RXTE
and COMPTEL/CGRO observations at lower and higher energies, respectively. We
find no evidence of spectral steepening below 200 keV, as has been reported in
previous observations. The spatial distribution along the Galactic ridge is
found to be nearly flat, with upper limits set on the longitudinal gradient,
and with no evidence of an edge in the observed region. The soft gamma-ray
diffuse spectrum is well modeled by inverse Compton scattering of interstellar
radiation off of cosmic-ray electrons, minimizing the need to invoke
inefficient nonthermal bremsstrahlung emission. The resulting power requirement
is well within that provided by Galactic supernovae. We speculate that the
measured spectrum provides the first direct constraints on the cosmic-ray
electron spectrum below 300 MeV.Comment: 26 pages, 7 figure, submitted to Ap
Some Remarks on the Question of Charge Densities in Stationary-Current-Carrying Conductors
Recently, some discussions arose as to the definition of charge and the value
of the density of charge in stationary-current-carrying conductors. We stress
that the problem of charge definition comes from a misunderstanding of the
usual definition. We provide some theoretical elements which suggest that
positive and negative charge densities are equal in the frame of the positive
ions.Comment: 14 pages, TeX, macro newsym.tex include
Pressure Evolution of a Field Induced Fermi Surface Reconstruction and of the Neel Critical Field in CeIn3
We report high-pressure skin depth measurements on the heavy fermion material
CeIn3 in magnetic fields up to 64 T using a self-resonant tank circuit based on
a tunnel diode oscillator. At ambient pressure, an anomaly in the skin depth is
seen at 45 T. The field where this anomaly occurs decreases with applied
pressure until approximately 1.0 GPa, where it begins to increase before
merging with the antiferromagnetic phase boundary. Possible origins for this
transport anomaly are explored in terms of a Fermi surface reconstruction. The
critical magnetic field at which the Neel ordered phase is suppressed is also
mapped as a function of pressure and extrapolates to the previous ambient
pressure measurements at high magnetic fields and high pressure measurements at
zero magnetic field.Comment: 15 pages, 5 figure
Interrelations Between the Neutron's Magnetic Interactions and the Magnetic Aharonov-Bohm Effect
It is proved that the phase shift of a polarized neutron interacting with a
spatially uniform time-dependent magnetic field, demonstrates the same physical
principles as the magnetic Aharonov-Bohm effect. The crucial role of inert
objects is explained, thereby proving the quantum mechanical nature of the
effect. It is also proved that the nonsimply connectedness of the field-free
region is not a profound property of the system and that it cannot be regarded
as a sufficient condition for a nonzero phase shift.Comment: 18 pages, 1 postscript figure, Late
Predator-Induced Vertical Behavior of a Ctenophore
Although many studies have focused on Mnemiopsis leidyi predation, little is known about the role of this ctenophore as prey when abundant in native and invaded pelagic systems. We examined the response of the ctenophore M. leidyi to the predatory ctenophore Beroe ovata in an experiment in which the two species could potentially sense each other while being physically separated. On average, M. leidyi responded to the predator’s presence by increasing variability in swimming speeds and by lowering their vertical distribution. Such behavior may help explain field records of vertical migration, as well as stratified and near-bottom distributions of M. leidyi
Resonance between Noise and Delay
We propose here a stochastic binary element whose transition rate depends on
its state at a fixed interval in the past. With this delayed stochastic
transition this is one of the simplest dynamical models under the influence of
``noise'' and ``delay''. We demonstrate numerically and analytically that we
can observe resonant phenomena between the oscillatory behavior due to noise
and that due to delay.Comment: 4 pages, 5 figures, submitted to Phys.Rev.Lett Expanded and Added
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