Summer paleohydrology during the Late Glacial and Early Holocene based on δ2H and δ18O from Bichlersee, Bavaria.

Isotope-based records provide valuable information on past climate changes. However, it is not always trivial to disentangle past changes in the isotopic composition of precipitation from possible changes in evaporative enrichment, and seasonality may need to be considered. Here, we analyzed δ2H on n-alkanes and δ18O on hemicellulose sugars in sediments from Bichlersee, Bavaria, covering the Late Glacial and Early Holocene. Our δ2Hn-C31 record documents past changes in the isotopic composition of summer precipitation and roughly shows the isotope pattern known from Greenland. Both records show lower values during the Younger Dryas, but at Bichlersee the signal is less pronounced, corroborating earlier suggestions that the Younger Dryas was mainly a winter phenomenon and less extreme during summer. δ18Ofucose records the isotopic composition of the lake water during summer and is sensitive to evaporative enrichment. Coupling δ2Hn-C31 and δ18Ofucose allows calculating lake water deuterium-excess and thus disentangling changes in the isotopic composition of precipitation and evaporative enrichment. Our deuterium-excess record reveals that the warm Bølling-Allerød and Early Holocene were characterized by more evaporative enrichment compared to the colder Younger Dryas. Site-specific hydrological conditions, seasonality, and coupling δ2H and δ18O are thus important when interpreting isotope records

A 1100-year multi-proxy palaeoenvironmental record from Lake Höglwörth, Bavaria, Germany

Anthropogenic activities have exerted strong influence on ecosystems worldwide, particularly since 1950 CE. The local impact of past human activities often started much earlier and deserves detailed study. Here, we present an environmental record from a 278 cm long sedimentary core from Lake Höglwörth (Bavaria, Germany). Sedimentological and geochemical parameters indicate that the organic-rich bottom sediments of the record consist of peat that formed prior to 870+140-160 CE, when lake sediments started to accumulate. After 870+140-160 CE, distinct shifts in lithology, elemental composition, and the biological record are visible and are interpreted to result from the construction of a monastery on the lake peninsula in 1125 CE and/or the damming of the lake. From 1120±120 to 1240+110-120 CE, the lake environment was relatively stable. This period was followed by enhanced deforestation that led to a more open landscape and soil erosion, visible in increased allochthonous input from 1240+110-120 to 1380+90-110 CE. This was accompanied by high aquatic productivity and bottom or interstitial water anoxia from 1310+100-120 to 1470+90-100 CE, possibly triggered by increased nutrient availability. Enhanced allochthonous input and a substantial shift in the aquatic community can be assigned to the construction of a flour mill and related rerouting of a small creek in 1701 CE. High aquatic productivity and bottom or interstitial water anoxia after 1960±10 CE correspond to recent eutrophication resulting from accelerated local anthropogenic activities. The sedimentary record from Lake Höglwörth exemplarily demonstrates that anthropogenic activities have had substantial environmental impacts on aquatic environments during the past millennium

Environmental controls on the distribution of GDGT molecules in Lake Höglwörth, Southern Germany

Tetraether lipids, such as glycerol dialkyl glycerol tetraethers (GDGTs), are an increasingly used proxy for reconstructing paleoclimatic and paleoenvironmental dynamics. On a global scale, environmental drivers controlling the distribution of GDGTs in lake systems have been described extensively. However, the drivers that control down-core sedimentary GDGT composition within single lake systems are still poorly constrained. Here, we analysed GDGTs in a sediment core collected from Lake Höglwörth (Bavaria, Germany) covering the last ∼1100 years. The increase in ratio ΣIIIa/ΣIIa values (a ratio which captures the variation of 3 structural isomers of penta- and hexamethylated brGDGTs respectively) reflects a higher contribution of branched (br) GDGTs from aquatic sources after 1800 CE. This is synchronous with a high nutrient input as a result of increased local anthropogenic activities. The climate proxy methylation of branched tetraethers (MBT'5ME) reveals a pattern that deviates from the anticipated temperature changes during the last millennium. Instead, high MBT'5ME values from ∼880 to 1120 CE coincide with a period of increased soil input, resulting from lake damming and/or construction of the Höglwörth monastery. Decreased values after 1800 CE until present date correspond to a higher contribution of aquatic brGDGTs, with changes in the dependency between Ia and IIa suggesting a direct influence of bacterial community changes on the MBT'5ME. The proxy cyclisation of branched tetraethers (CBT') shows a linear increase with time, and a stepwise increase at 1700 CE, when a creek stream inflow channel was rerouted. Over time, MBT’5ME decreases gradually, while CBT’ and ΣIIIa/ΣIIa increase. This is hypothesized to be potentially caused by decreasing water depth over time and/or post- or syn-sedimentary production of GDGTs. The degree of cyclization (DC') shows variations on shorter timescales, possibly driven by the lake mixing regime and water column redox conditions. Our results indicate that caution must be taken when interpreting GDGTs for paleoclimate and paleoenvironmental reconstruction considering the possible influence of shifts in the provenance of brGDGTs. Further studies focusing on both sedimentary and intact polar lipids are highly recommended to constrain the source (water column, or sedimentary production) of GDGTs in lake sediments.ISSN:0146-638

Total organic carbon, calcium carbonate and compound-specific δ2H on n-alkanes and δ18O on hemicellulose sugars from Late Glacial sediments from Bichlersee, Bavarian Alps

Variations in the δ18O signals from lake sediments in the European Alps have been interpreted to reflect past temperature during the Late Glacial–Early Holocene transition due to the strong similarity with δ18O records from Greenland. However, past changes in evaporative enrichment could have played an important role, but were rarely considered yet. Therefore, we analyze δ2H on n-alkanes and δ18O on hemicellulose sugars from Late Glacial sediments (~15 ka cal. BP) from Bichlersee, Bavarian Alps (47.676007 N, 12.122035 E). With this, deuterium excess as a proxy for lake water evaporative enrichment is modelled based on coupling δ2H and δ18O. The chronology for this dataset is based on 14C-dating of terrestrial macrofossils and charcoal. The dataset contains geochemical data including total organic carbon and calcium carbonate content and the compound-specific stable hydrogen and oxygen composition of n-alkanes and hemicellulose sugars, respectively. Based on this, deuterium excess as a proxy for evaporative enrichment of lake water is calculated after Hepp et al. (2015, doi:10.1016/j.jhydrol.2014.10.012). For additional paleoclimatic information see Prochnow et al. (in submission)