Jus Soli and Jus Sanguinis: Politics, Race, Culture, and Citizenship in the Dominican Republic and Haiti

The promulgation of laws such as the Dominican Republic’s Constitutional Court’s Judgment TC-168-13 serves as a basis upon which to argue the major impediments presented by the Dominican government to deny Haitians and Dominicans of Haitians descent citizenship. The right to citizenship is based on legal principles of jus soli and jus sanguinis and is recognized in a series of international legal documents. Following a Marxist framework, this research demonstrates the uncounted possible relationships between modern social forces and politics that have been working closely following European productions of knowledge for decades against Haitians and Dominicans of Haitian descent in the Dominican Republic. Haitians and Dominicans of Haitian descent are not afforded the same constitutional rights and privileges as Dominicans because of their Blackness rooted in their African lineage. Judgment TC-168-13 is inherently a racist law that excludes Haitians and Dominicans of Haitian descent from procuring citizenship in the Dominican Republic

Heating Strategies in Cellulose Pyrolysis as an Alternative For Targeting Energy Efficient Product Distribution

Energy generation and platform chemicals production from biomass are a potential route towards an oil-free economy. Pyrolysis is one of the key technologies for transforming biomass into both fuels and chemicals. However, pyrolysis is a complex and energy-intensive process, and optimizing the operation for reducing its energy requirements is critical for the design of competitive biorefineries. This work presents a model to describe cellulose pyrolysis based on mass, energy and momentum conservation of solid and gaseous species. Lumped and detailed kinetic models are used to investigate how heating conditions impact pyrolysis product distribution. The resulting complex system was solved using gPROMS. Results suggest that pyrolysis mainly occurs in the boundary of the modelled particles. The developed model presents flexibility to use lumped and detailed kinetic models and provided both a general perspective of the pyrolysis process and detailed information on product distribution. Using this model, the results show that an initial high heating rate, followed by a lower heating rate, could reduce energy requirements by 10 % without changing the product distribution. There is also a trade-off between the yield of high added-value products, such as levoglucosan, and the overall energy requirement

Thermal storage of nitrate salts as Phase Change Materials (PCMs)

This study presents the energy storage potential of nitrate salts for specific applications in energy systems that use renewable resources. For this, the thermal, chemical, and morphological characterization of 11 samples of nitrate salts as phase change materials (PCM) was conducted. Specifically, sodium nitrate (NaNO3), sodium nitrite (NaNO2), and potassium nitrate (KNO3) were considered as base materials; and various binary and ternary mixtures were evaluated. For the evaluation of the materials, differential Fourier transform infrared spectroscopy (FTIR), scanning calorimetry (DSC), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) to identify the temperature and enthalpy of phase change, thermal stability, microstructure, and the identification of functional groups were applied. Among the relevant results, sodium nitrite presented the highest phase change enthalpy of 220.7 J/g, and the mixture of 50% NaNO3 and 50% NaNO2 presented an enthalpy of 185.6 J/g with a phase change start and end temperature of 228.4 and 238.6 °C, respectively. This result indicates that sodium nitrite mixtures allow the thermal storage capacity of PCMs to increase. In conclusion, these materials are suitable for medium and high-temperature thermal energy storage systems due to their thermal and chemical stability, and high thermal storage capacity

Eruption type probability and eruption source parameters at Cotopaxi and Guagua Pichincha volcanoes (Ecuador) with uncertainty quantification

Future occurrence of explosive eruptive activity at Cotopaxi and Guagua Pichincha volcanoes, Ecuador, is assessed probabilistically, utilizing expert elicitation. Eight eruption types were considered for each volcano. Type event probabilities were evaluated for the next eruption at each volcano and for at least one of each type within the next 100 years. For each type, we elicited relevant eruption source parameters (duration, average plume height, and total tephra mass). We investigated the robustness of these elicited evaluations by deriving probability uncertainties using three expert scoring methods. For Cotopaxi, we considered both rhyolitic and andesitic magmas. Elicitation findings indicate that the most probable next eruption type is an andesitic hydrovolcanic/ash-emission (~ 26–44% median probability), which has also the highest median probability of recurring over the next 100 years. However, for the next eruption at Cotopaxi, the average joint probabilities for sub-Plinian or Plinian type eruption is of order 30–40%—a significant chance of a violent explosive event. It is inferred that any Cotopaxi rhyolitic eruption could involve a longer duration and greater erupted mass than an andesitic event, likely producing a prolonged emergency. For Guagua Pichincha, future eruption types are expected to be andesitic/dacitic, and a vulcanian event is judged most probable for the next eruption (median probability ~40–55%); this type is expected to be most frequent over the next 100 years, too. However, there is a substantial probability (possibly >40% in average) that the next eruption could be sub-Plinian or Plinian, with all that implies for hazard levels

Platelets Regulate Pulmonary Inflammation and Tissue Destruction in Tuberculosis.

RATIONALE: Platelets may interact with the immune system in tuberculosis (TB) to regulate human inflammatory responses that lead to morbidity and spread of infection. OBJECTIVES: To identify a functional role of platelets in the innate inflammatory and matrix-degrading response in TB. METHODS: Markers of platelet activation were examined in plasma from 50 patients with TB before treatment and 50 control subjects. Twenty-five patients were followed longitudinally. Platelet-monocyte interactions were studied in a coculture model infected with live, virulent Mycobacterium tuberculosis (M.tb) and dissected using qRT-PCR, Luminex multiplex arrays, matrix degradation assays, and colony counts. Immunohistochemistry detected CD41 (cluster of differentiation 41) expression in a pulmonary TB murine model, and secreted platelet factors were measured in BAL fluid from 15 patients with TB and matched control subjects. MEASUREMENTS AND MAIN RESULTS: Five of six platelet-associated mediators were upregulated in plasma of patients with TB compared with control subjects, with concentrations returning to baseline by Day 60 of treatment. Gene expression of the monocyte collagenase MMP-1 (matrix metalloproteinase-1) was upregulated by platelets in M.tb infection. Platelets also enhanced M.tb-induced MMP-1 and -10 secretion, which drove type I collagen degradation. Platelets increased monocyte IL-1 and IL-10 and decreased IL-12 and MDC (monocyte-derived chemokine; also known as CCL-22) secretion, as consistent with an M2 monocyte phenotype. Monocyte killing of intracellular M.tb was decreased. In the lung, platelets were detected in a TB mouse model, and secreted platelet mediators were upregulated in human BAL fluid and correlated with MMP and IL-1β concentrations. CONCLUSIONS: Platelets drive a proinflammatory, tissue-degrading phenotype in TB

D\u27Amico Risk Stratification Correlates with Degree of Suspicion of Prostate Cancer on Multiparametric Magnetic Resonance Imaging.

PURPOSE: We determined whether there is a correlation between D\u27Amico risk stratification and the degree of suspicion of prostate cancer on multiparametric magnetic resonance imaging based on targeted biopsies done with our electromagnetically tracked magnetic resonance imaging/ultrasound fusion platform. MATERIALS AND METHODS: A total of 101 patients underwent 3 Tesla multiparametric magnetic resonance imaging of the prostate, consisting of T2, dynamic contrast enhanced, diffusion weighted and spectroscopy images in cases suspicious for or with a diagnosis of prostate cancer. All prostate magnetic resonance imaging lesions were then identified and graded by the number of positive modalities, including low-2 or fewer, moderate-3 and high-4 showing suspicion on multiparametric magnetic resonance imaging. The biopsy protocol included standard 12-core biopsy, followed by real-time magnetic resonance imaging/ultrasound fusion targeted biopsies of the suspicious magnetic resonance lesions. Cases and lesions were stratified by the D\u27Amico risk stratification. RESULTS: In this screening population 90.1% of men had a negative digital rectal examination. Mean±SD age was 62.7±8.3 years and median prostate specific antigen was 5.8 ng/ml. Of the cases 54.5% were positive for cancer on protocol biopsy. Chi-square analysis revealed a statistically significant correlation between magnetic resonance suspicion and D\u27Amico risk stratification (p CONCLUSIONS: Our data support the notion that using multiparametric magnetic resonance prostate imaging one may assess the degree of risk associated with magnetic resonance visible lesions in the prostate

Delivering 21st century Antarctic and Southern Ocean science

The Antarctic Roadmap Challenges (ARC) project identified critical requirements to deliver high priority Antarctic research in the 21st century. The ARC project addressed the challenges of enabling technologies, facilitating access, providing logistics and infrastructure, and capitalizing on international co-operation. Technological requirements include: i) innovative automated in situ observing systems, sensors and interoperable platforms (including power demands), ii) realistic and holistic numerical models, iii) enhanced remote sensing and sensors, iv) expanded sample collection and retrieval technologies, and v) greater cyber-infrastructure to process ‘big data’ collection, transmission and analyses while promoting data accessibility. These technologies must be widely available, performance and reliability must be improved and technologies used elsewhere must be applied to the Antarctic. Considerable Antarctic research is field-based, making access to vital geographical targets essential. Future research will require continent- and ocean-wide environmentally responsible access to coastal and interior Antarctica and the Southern Ocean. Year-round access is indispensable. The cost of future Antarctic science is great but there are opportunities for all to participate commensurate with national resources, expertise and interests. The scope of future Antarctic research will necessitate enhanced and inventive interdisciplinary and international collaborations. The full promise of Antarctic science will only be realized if nations act together

EFFECTIVENESS ASSESSMENT OF FNA IN IMPROVING SOLUBILIZATION AND CONTROLLING PROBLEMATIC MICROORGANISMS IN PRE-TREATMENT OF FOOD WASTE

Anaerobic digestion (AD) is a sustainable waste-to-energy method for converting organic waste to methane. Various pre-treatment of food waste (FW) with free nitrous acid (FNA; pKa=3.25) were used to stabilize FW and mitigate obstacles (odor in FW storage and pathogenic bacteria) in AD. FNA concentrations ranging from 0-5 mg-N/L were tested in this study at pH ranging from 3-5.5, and volatile solids (VS) content of 16.8-135 g/L. Solubilization of organic material, inhibition of N-related biological processes, and control of problematic microorganisms, including sulfate-reducing bacteria (SRB) and pathogenic bacteria, were compared with the groups without FNA addition. At the tested pH (3, 4, and 5) and concentrations of FNA (0.3-5.0 mg-N/L), FNA addition showed inhibition to N-related biological processes contributing to a consistent FNA concentration over the 72 hours pre-treatment. However, it did not enhance the solubilization of organic materials compared with control group without FNA addition. The FNA concentration affected the bacterial inhibition of SRB. As the concentration of FNA increased from 0.3-5.0 mg-N/L, so did SRB inhibition. Similarly, increasing FNA concentration resulted in a faster reduction (2.5 logs within 4 hours) in pathogenic bacteria compared with the group without FNA addition. Overall, a shorter pre-treatment time ( 80.57 g /L), as the effective FNA concentration cannot be maintained for longer due to NO2- and bioavailable organic carbon consumption by N-related or other microorganisms that remain active or recoverable under the added FNA concentration

COUNTERCYCLICAL CAPITAL BUFFERS, BANK CONCENTRATION AND MACROFINANCIAL STABILITY IN AN AGENT-BASED MACRO-FINANCIAL FRAMEWORK

This paper examines the impact of countercyclical capital buffers (CCyBs) on financial stability and contributes to the discussion of CCyBs in an agent-based framework. The main focus of this work lies upon the question whether the implementation of CCyBs according to the Basel III framework improves financial stability unconditionally, or at the expense of unintended side effects. For this purpose, we extend the agent-based model of [Riccetti, L., Russo, A. and Gallegati, M., Firm-bank credit network, business cycle and macroprudential policy, J. Econ. Interact. Coord. (2021)] to investigate the effect of credit-to-GDP gap-based CCyBs in general as well as the effects of varying the smoothing parameter lambda A of the Hodrick-Prescott (HP) filter within the method of calculating CCyBs. To the best of our knowledge, this study is the first one that investigates systematically how the method of calculating credit-to-GDP gap-based CCyBs may affect macrofinancial dynamics and stability in such an agent-based framework