Study of a laminar falling film flowing over a wavy wall column: Part II. Experimental validation of hydrodynamic model

The interface position of a film flowing over a wavy wall column is experimentally studied by an optical method composed of a charge coupled device (CCD) video camera. The results are compared with theoretical calculations and show a good agreement between results for both the film thickness and the vortex position. However, there exist some discrepancies because the interface is travelled by waves not accounted for in the mathematical model as it is supposed to be flat. Some characteristics of the waves are experimentally noted. Furthermore, the in¯uence of the viscosity on the film thickness is established as well

Modelling of the coupling hydrodynamic transfer for a gas-liquid countercurrent flow on a wavy surface

This paper concerns laminar countercurrent gas–liquid flow over a wavy wall column, in the case of a falling liquid film. The modelling concerns the coupling of hydrodynamic and heat and mass transfer for an absorption as an example of application. The falling liquid film interacts, through the free interface, with the gas phase. The wavy surface generates particular hydrodynamic conditions with the presence of a vortex in both phases. The consequence of these vortices is an increase of transfers compared to the smooth wall

Enhancement of absorption efficiency for a laminar film flow by hydrodynamic conditions generated by a new type of column wall

Anumerical model is developed to quantify the effects of hydrodynamics on heat and mass transfer during an absorption, for a laminar film flowing over awavywall column. First of all, the modelling is written for a singlewave of thewall shape. Then, an experimental set up, composed of aCCDvideo camera, validates this model. Finally, the model is extended to an entire column. The results include a comparison with the simulation of a smooth column having the same geometrical and operating conditions. Thewavy column dissipates more heat through the wall (43%) due to the presence of a vortex in the furrows. This leads to an increase of the absorptionrate at the interface (10%). Moreover, the wavy column reaches equilibrium more rapidly in spite of a lower mean film temperature

Study of a laminar falling film flowing over a wavy wall column: Part I. Numerical investigation of the flow pattern and the coupled heat and mass transfer

Flow pattern and heat and mass transfer characteristics for a film flowing over a vertical wavy column are numerically investigated in a laminar flow regime. In our approach, the heat and mass transfer coefficients are avoided in order to include hydrodynamics directly in the heat and mass transfer rates. As a consequence the numerical model is decomposed into two steps. Firstly, the flow pattern for a film with a free interface is developed. Secondly, heat and mass transfer are investigated with the incorporation of velocity fields. The heat and mass transfer coefficients increase in laminar flow

Hydrodynamic and mass transfer efficiency of ceramic foam packing applied to distillation.

In addition to a high void volume and specific area, solid foams possess other properties (low density, good thermal, mechanical, electrical, and acoustical behaviour) that make them attractive for applications such as heat exchangers and reformers. Applications using foams as catalysts or structured catalyst supports have demonstrated higher performance than classical catalysts. Several studies have explored the hydrodynamic behaviour of foams in monophasic and counter current systems and have reported very low pressure drops. This paper describes the application of ceramic foam to distillation. The β-SiC foam contains 5 pores per inch (PPI) with a 91% void volume and a surface area of 640 m2/m3. Performance parameters including pressure drop for the dry and wet packing, flooding behaviour, and dynamic liquid hold-up were measured in a column of 150 mm internal diameter. The mass transfer efficiency in terms of the height equivalent to theoretical plate (HETP) was determined by total reflux experiments using a mixture of n-heptane and cyclohexane at atmospheric pressure. The experimental results were used to develop a set of correlations describing pressure drop and liquid hold-up in terms of a dimensionless number. The hydrodynamic performance and mass transfer efficiency were compared with classical packing materials used in distillation

Mass transfer and hydrodynamic characteristics of new carbon carbon packing: Application to CO2 post-combustion capture

A novel structured packing, the 4D packing, has been characterized in terms of hydrodynamics, effective area and gas side mass transfer coefficient. The increase of the 4D opening fraction allows to reduce pressure drop and to get a better capacity than Mellapak 500Y and 750Y, for which the geometric areas are similar. The 50% open 4D packing, 4D-50%, leads to effective areas which are higher than Mellapak 500Y ones, and doubled compared with Mellapak Plus 252Y ones. Effective areas for the 4D do not decrease when the opening fraction increases from 30 to 50%, this indicates that a non-negligible amount of droplets is generated at 50%. Gas side mass transfer coefficient had been measured with an original experimental method: water evaporation. Corresponding results seem to be in agreement with the literature, and with the fact that a large amount of droplets is generated. Correlations are proposed for both effective area and gas side mass transfer coefficient for the 4D-50%.The 4D-50% packing could be very interesting for post-combustion CO2 capture since it generates low pressure drop and a very high interfacial area. This will be further confirmed by an economic study for which the absorber plant will be designed with a rate based model

Performance characteristics of a new structured packing

A new structured packing using carbon fibres, called Sepcarb® 4D, is presented. This packing has several attractive properties, such as high voidage (ε=94%) and high effective area (a=420 m2 m−3). These properties are advantageous for packing used as a gas–liquid contactor for separation units. To determine the internal characteristics of this packing, we performed several experiments using a 150-mm-internal-diameter column. Firstly, hydrodynamics experiments were conducted using an air–water counter current flow to determine the pressure drop (for both dry and wet packing) and flooding point. Secondly, the mass transfer efficiency was determined in terms of HETP (height equivalent to theoretical plate) by total reflux experiments with an n-heptane/cyclohexane mixture at atmospheric pressure. Hydrodynamic performance and mass transfer efficiency were compared with those of packings generally used in distillation and absorption

Evidence for SrHo2O4 and SrDy2O4 as model J1-J2 zig-zag chain materials

Neutron diffraction and inelastic spectroscopy is used to characterize the magnetic Hamiltonian of SrHo2O4 and SrDy2O4. Through a detailed computation of the crystal-field levels we find site- dependent anisotropic single-ion magnetism in both materials and diffraction measurements show the presence of strong one-dimensional spin correlations. Our measurements indicate that competing interactions of the zig-zag chain, combined with frustrated interchain interactions, play a crucial role in stabilizing spin-liquid type correlations in this series.Comment: 5 pages, 5 figure

Panton–Valentine Leukocidin Colocalizes with Retinal Ganglion and Amacrine Cells and Activates Glial Reactions and Microglial Apoptosis

International audienceExperimental models have established Panton-Valentine leukocidin (PVL) as a potential critical virulence factor during Staphylococcus aureus endophthalmitis. In the present study, we aimed to identify retinal cell targets for PVL and to analyze early retinal changes during infection. After the intravitreous injection of PVL, adult rabbits were euthanized at different time points (30 min, 1, 2, 4 and 8 h). PVL location in the retina, expression of its binding receptor C5a receptor (C5aR), and changes in Müller and microglial cells were analyzed using immunohistochemistry, Western blotting and RT-qPCR. In this model of PVL eye intoxication, only retinal ganglion cells (RGCs) expressed C5aR, and PVL was identified on the surface of two kinds of retinal neural cells. PVL-linked fluorescence increased in RGCs over time, reaching 98% of all RGCs 2 h after PVL injection. However, displaced amacrine cells (DACs) transiently colocalized with PVL. Müller and microglial cells were increasingly activated after injection over time. IL-6 expression in retina increased and some microglial cells underwent apoptosis 4 h and 8 h after PVL infection, probably because of abnormal nitrotyrosine production in the retina

Coopération modélisation : discrimination pour la reconnaissance d'écriture manuscrite

-Reconnaître l'écriture manuscrite est un problème d'une telle complexité qu'il est devenu courant de faire coopérer plusieurs algorithmes de classification. Dans cet article, nous présentons un classifieur hybride original. Un premier expert de modélisation détermine les deux classes les plus pertinentes en comparant le symbole inconnu à un ensemble exhaustif de symboles. Le second, discriminant, permet de lever les ambiguïtés. Cette architecture hybride exploite le fait que la "bonne" classe appartient le plus souvent aux deux classes les plus pertinentes trouvées par le premier classifieur. Les expérimentations, conduites sur une base de test de 20000 formes (62 classes), montrent que l'apport relatif de la coopération s'élève à 30%