15 research outputs found

    Eberbach CORPORATION

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    Stereoselective Synthesis of Enamides by a Peterson Reaction Manifold

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    Vinylsilanes are converted into enamides by a sequence comprising epoxidation, nucleophilic ring opening of the resulting epoxysilanes with NaN<sub>3</sub>, and reduction of the azide, followed by a “one-pot” N-acylation/Peterson elimination process. This method is distinguished by its wide applicability and stereoselective course
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