1 research outputs found
On the Perturbation of the H-Bonding Interaction in Ethylene Glycol Clusters upon Hydration
Ab initio and density functional methods have been employed
to
study the structure, stability, and spectral properties of various
ethylene glycol (EG<i><sub>m</sub></i>) and ethylene glycol–water
(EG<sub><i>m</i></sub>W<sub><i>n</i></sub>) (<i>m</i> = 1–3, <i>n</i> = 1–4) clusters.
The effective fragment potential (EFP) approach was used to explore
various possible EG<sub><i>m</i></sub>W<sub><i>n</i></sub> clusters. Calculated interaction energies of EG<sub><i>m</i></sub>W<sub><i>n</i></sub> clusters confirm that
the hydrogen-bonding interaction between EG molecules is perturbed
by the presence of water molecules and vice versa. Further, energy
decomposition analysis shows that both electrostatic and polarization
interactions predominantly contribute to the stability of these clusters.
It was found from the same analysis that ethylene glycol–water
interaction is predominant over the ethylene glycol–ethylene
glycol and water–water interactions. Overall, the results clearly
illustrate that the presence of water disrupts the ethylene glycol–ethylene
glycol hydrogen bonds