1,1′-(Ethane-1,2-di­yl)bis­(3-phenyl­thio­urea)

The complete molecule of the title compound, C16H18N4S2, is generated by crystallographic inversion symmetry. The dihedral angle between the phenyl ring and the thio­urea group is 52.9 (4)°. The crystal structure displays inter­molecular N—H⋯S hydrogen bonding, which generates sheets in the ab plane

4,6,10,12,16,18,22,24-Octa-O-methyl-2,8,14,20-tetra­pentylresorcin[4]arene

The complete molecule of the title compound, C56H80O8, is generated by a crystallographic inversion centre. The dihedral angle between the aromatic ring and the unique half of the molecule is 81.52 (16)°. There are no π–π inter­actions in the crystal structure

4,10,16,22-Tetra­kis(2-chloro­acet­oxy)-6,12,18,24-tetra­meth­oxy-2,8,14,20-tetra­pentyl­resorcin[4]arene

The title compound, C60H76Cl4O12, has a macrocyclic structure and both the upper and lower rim have disordered atoms. There are no hydrogen bonds or π–π stacking inter­actions in the crystal

4,5,6,10,11,12,16,17,18,22,23,24-Dodeca­kis­[(meth­oxy­carbon­yl)meth­oxy]-2,8,14,20-tetra­pentyl­resorcin[4]arene

The title compound, C84H112O36, has a macrocyclic structure. It has 12 (meth­oxy­carbon­yl)meth­oxy ‘head groups’ in the upper rim and exhibits a flattened boat geometry. Intra­molecular C—H⋯O hydrogen bonds occur. In the crystal, inter­molecular C—H⋯O contacts occur. The ‘head groups’ and the pentyl ‘feet’ contain disordered (0.5:0.5 occupancy ratio) atoms

6,12,18,24-Tetra­meth­oxy-4,10,16,22-tetra­kis­[(meth­oxy­carbon­yl)meth­oxy]-2,8,14,20-tetra­kis­(2-phenyl­eth­yl)resorcin[4]arene

The title compound, C76H80O16, is a macrocyclic structure. This novel resorcin[4]arene derivative has (meth­oxy­carbon­yl)meth­oxy ‘head’ groups on the upper rim. The compound has a C 2v ‘boat’ geometry and there are a range of C—H⋯O contacts in the crystal structure

1-(2-Amino­eth­yl)-3-phenyl­thio­urea

In the crystal structure of the title compound, C9H13N3S, mol­ecules are linked through N—H⋯S and N—H⋯N hydrogen bonds, forming hydrogen-bonded tapes along the b axis. The dihedral angle between the phenyl ring and the thiourea group is 44.9 (2)°

1,1′-(Propane-1,3-di­yl)bis­(3-phenyl­urea)

The title compound, C17H20N4O2, has crystallographic inversion symmetry. In the crystal structure, inter­molecular hydrogen bonding between adjacent urea groups gives rise to infinite polymeric chains diagonally across the bc plane. With a centroid–centroid distance of 3.295 (2) Å, π–π stacking is present in the crystal along the same plane

3,3′-Diphenyl-1,1′-(butane-1,4-diyl)dithiourea

The asymmetric unit of the title compound, C18H22N4S2, contains one half-molecule, the complete molecule being generated by crystallographic inversion symmetry. The crystal structure features two intermolecular N—H...S hydrogen-bonding interactions, the first generating an infinite chain along the b axis and the second an infinite chain along the a axis, together forming an interlocking structure