16 research outputs found
Large Magnetoresistance and Jahn Teller effect in SrFeCoO
Neutron diffraction measurement on the spin glass double perovskite
SrFeCoO reveals site disorder as well as Co intermediate spin
state. In addition, multiple valence states of Fe and Co are confirmed through
M\"{o}ssbauer and X-ray photoelectron spectroscopy. The structural disorder and
multiple valence lead to competing ferromagnetic and antiferromagnetic
interactions and subsequently to a spin glass state, which is reflected in the
form of an additional -linear contribution at low temperatures in specific
heat. A clear evidence of Jahn-Teller distortion at the Co-O complex
is observed and incorporating the physics of Jahn-Teller effect, the presence
of localized magnetic moment is shown. A large, negative and anomalous
magnetoresistance of 63% at 14K in 12T applied field is observed for
SrFeCoO. The observed magnetoresistance could be explained by applying
a semi-empirical fit consisting of a negative and a positive contribution and
show that the negative magnetoresistance is due to spin scattering of carriers
by localized magnetic moments in the spin glass phase
Hyperfine interaction and electronic spin fluctuation study on SrLaFeCoO (x = 0, 1, 2) by high-resolution back-scattering neutron spectroscopy
The study of hyperfine interaction by high-resolution inelastic neutron
scattering is not very well known compared to the other competing techniques
viz. NMR, M\"ossbauer, PACS etc. Also the study is limited mostly to
magnetically ordered systems. Here we report such study on
SrLaFeCoO (x = 0, 1, 2) of which first (SrFeCoO with x
= 0) has a canonical spin spin glass, the second (SrLaFeCoO with x = 1) has
a so-called magnetic glass and the third (LaFeCoO with x = 2) has a
magnetically ordered ground state. Our present study revealed clear inelastic
signal for SrLaFeCoO, possibly also inelastic signal for SrFeCoO
below the spin freezing temperatures but no inelastic signal at all
for for the magnetically ordered LaFeCoO in the neutron scattering
spectra. The broadened inelastic signals observed suggest hyperfine field
distribution in the two disordered magnetic glassy systems and no signal for
the third compound suggests no or very small hyperfine field at the Co nucleus
due to Co electronic moment. For the two magnetic glassy system apart from the
hyperfine signal due only to Co, we also observed electronic spin fluctuations
probably from both Fe and Co electronic moments. \end{abstract
Observation of spin glass state in weakly ferromagnetic SrFeCoO double perovskite
We report the observation of spin glass state in the double perovskite oxide
SrFeCoO prepared through sol-gel technique. Initial structural
studies using x rays reveal that the compound crystallizes in tetragonal structure with lattice parameters, = 5.4609(2) \AA and = 7.7113(7)
\AA. The temperature dependent powder x ray studies reveal no structural phase
transition in the temperature range 10 -- 300 K. However, the unit cell volume
shows an anomaly coinciding with the magnetic transition temperature thereby
suggesting a close connection between lattice and magnetism. Neutron
diffraction studies and subsequent bond valence sums analysis show that in
SrFeCoO, the site is randomly occupied by Fe and Co in the
mixed valence states of Fe/Fe and Co/Co. The random
occupancy and mixed valence sets the stage for inhomogeneous magnetic exchange
interactions and in turn, for the spin glass like state in this double
perovskite which is observed as an irreversibility in temperature dependent dc
magnetization at 75 K. Thermal hysteresis observed in the
magnetization profile of SrFeCoO is indicative of the mixed
magnetic phases present. The dynamic magnetic susceptibility displays
characteristic frequency dependence and confirms the spin glass nature of this
material. Dynamical scaling analysis of yields a critical
temperature = 75.14(8) K and an exponent = 6.2(2) typical for
spin glasses. The signature of presence of mixed magnetic interactions is
obtained from the thermal hysteresis in magnetization of SrFeCoO.
Combining the neutron and magnetization results of SrFeCoO, we deduce
the spin states of Fe to be in low spin while that of Co to be in low spin and
intermediate spin.Comment: 23 pages, 6 figures, accepted in J. Appl. Phy
The order of magnetic phase transitions in disordered double perovskite oxides Sm2FeCoO6 and Dy2FeCoO6
We present the results on the order of phase transition around the spin re-orientation region using isothermal magnetization data performed on the sol-gel synthesized disordered double perovskite oxides Sm2FeCoO6 and Dy2FeCoO6 by Arrott plot method. The temperature variation of the DC magnetization data of both the samples show that there are two magnetic phase transitions; one at high temperature regime, the conventional paramagnetic (PM) to ferro or ferrimagnetic (FM or FIM) and the other at low temperatures, ferro or ferrimagnetic (FM or FIM) to antiferromagnetic (AFM). From the Arrott plot method, it is inferred that spin re-orientation transitions of both the compounds has a first order nature corresponding to the FM (FIM) to AFM transition