3,611 research outputs found
Optical properties, electron-phonon coupling, and Raman scattering of vanadium ladder compounds
The electronic structure of two V-based ladder compounds, the quarter-filled
NaVO in the symmetric phase and the iso-structural half-filled
CaVO is investigated by ab initio calculations. Based on the
bandstructure we determine the dielectric tensor of these
systems in a wide energy range. The frequencies and eigenvectors of the fully
symmetric A phonon modes and the corresponding electron-phonon and
spin-phonon coupling parameters are also calculated from first-principles. We
determine the Raman scattering intensities of the A phonon modes as a
function of polarization and frequency of the exciting light.
All results, i.e. shape and magnitude of the dielectric function, phonon
frequencies and Raman intensities show very good agreement with available
experimental data.Comment: 11 pages, 10 figure
The effect of alloying on the ordering processes in near-alpha titanium alloys
The substructure of near-alpha Ti-Al-Sn-Zr-Mo-Si alloys containing up to 12.5. at% aluminum was studied by transmission electron microscopy (TEM). It was shown that long-range order sections are formed at aging temperatures up to 500. °C in alloys, high in aluminum, and the ordered phase is formed by the nucleation and growth mechanism at 700. °C aging temperatures. Causes of changing the phase transformation mechanism have been discussed, and the relationship between the structure and properties of alloys, depending on modes of heat treatment has been analyzed. Also the influence of aluminides and silicides precipitation on the mechanical alloy properties after aging was examined. It was shown that the aluminide formation led to a slight hardening and a significant viscosity decrease. The silicide particles formation reduced the heat resistance properties, due to the depletion of the solid solution by silicon. © 2012 Elsevier B.V
Optical spectra, crystal-field parameters, and magnetic susceptibility of the new multiferroic NdFe3(BO3)4
We report high-resolution optical absorption spectra for NdFe3(BO3)4 trigonal
single crystal which is known to exhibit a giant magnetoelectric effect below
the temperature of magnetic ordering TN = 33 K. The analysis of the
temperature-dependent polarized spectra reveals the energies and, in some
cases, symmetries and exchange splittings of Nd3+ 84 Kramers doublets. We
perform crystal-field calculations starting from the exchange-charge model,
obtain a set of six real crystal-field parameters, and calculate wave functions
and magnetic g-factors. In particular, the values g(perpendicular) = 2.385,
g(parallel) = 1.376 were found for the Nd3+ ground-state doublet. We obtain
Bloc=7.88 T and |JFN|= 0.48 K for the values of the local effective magnetic
field at liquid helium temperatures at the Nd3+ site and the Nd - Fe exchange
integral, respectively, using the experimentally measured Nd3+ ground-state
splitting of 8.8 cm-1. To check reliability of our set of crystal field
parameters we model the magnetic susceptibility data from literature. A dimer
containing two nearest-neighbor iron ions in the spiral chain is considered to
partly account for quasi-one-dimensional properties of iron borates, and then
the mean-field approximation is used. The results of calculations with the
exchange parameters for Fe3+ ions Jnn = -6.25 K (intra-chain interactions) and
Jnnn = -1.92 K (inter-chain interactions) obtained from fitting agree well with
the experimental data.Comment: 13 pages, 8 figures, 2 table
Inversionless light amplification and optical switching controlled by state-dependent alignment of molecules
We propose a method to achieve amplification without population inversion by
anisotropic molecules whose orientation by an external electric field is
state-dependent. It is based on decoupling of the lower-state molecules from
the resonant light while the excited ones remain emitting. The suitable class
of molecules is discussed, the equation for the gain factor is derived, and the
magnitude of the inversionless amplification is estimated for the typical
experimental conditions. Such switching of the sample from absorbing to
amplifying via transparent state is shown to be possible both with the aid of
dc and ac control electric fields.Comment: AMS-LaTeX v1.2, 4 pages with 4 figure
- …