Optical characterisation of hybrid antireflective coatings using spectrophotometric and ellipsometric measurements

A hybrid antireflective coating combining homogeneous layers and linear gradient refractive index layers has been deposited using different techniques. The samples were analysed by optical characterisation based on spectrophotometric and spectroscopic ellipsometric measurements under different angles of incidence in order to precisely characterise the coatings. The Lorentz-Lorenz model has been used for calculation of refractive index of material mixtures in gradient index layers as well as some homogenous parts of the coating. The obtained refractive index profiles have been compared with the targeted ones to detect errors in processes of deposition

Infrared-Reflective Coating on Fused Silica for a Solar High-Temperature Receiver

In concentrating solar power, high-temperature solar receivers can provide heat to highly efficient cycles for electricity or chemical production. Excessive heating of the fused-silica window and the resulting recrystallization are major problems of high-temperature receivers using windows. Excessive window temperatures can be avoided by applying an infrared-reflective solar-transparent coating on the fused-silica window inside. Both glass temperatures and receiver losses can be reduced. An ideal coating reflects part of the thermal spectrum (λ>2.5 µm) of the hot absorber (1100°C) back onto it without reducing solar transmittance. The examined transparent conductive oxides (TCO) involve a high solar absorptance, inhibiting their use in high-concentration solar systems. Although conventional dielectric interference filters have a low solar absorption, the reflection of solar radiation which comes from various directions is too high. It was found that only rugate filters fulfill the requirements for operation under high-flux solar radiation with different incident angles. A thermodynamic qualification simulation of the rugate coating on a window of a flat-plate receiver showed a reduction of almost 175 K in mean window temperature and 11% in receiver losses compared to an uncoated window. Finally, a first 25-µm thick rugate filter was manufactured and optically characterized. The issue of this paper is to share the work done on the choice of filter type, filter design, thermodynamic evaluation, and deposition experiments

Infrared-Reflective Coating on Fused Silica for a Solar High-Temperature Receiver

In concentrating solar power, high-temperature solar receivers can provide heat to highly efficient cycles for electricity or chemical production. Excessive heating of the fused-silica window and the resulting recrystallization are major problems of high-temperature receivers using windows. Excessive window temperatures can be avoided by applying an infrared-reflective solar-transparent coating on the fused-silica window inside. Both glass temperatures and receiver losses can be reduced. An ideal coating reflects part of the thermal spectrum (lambda>2.5 µm) of the hot absorber (1100°C) back onto it without reducing solar transmittance. Extensive radiation simulations were done to screen different filter types. The examined transparent conductive oxides (TCO) involve a high solar absorptance, inhibiting their use in high-concentration solar systems. Although conventional dielectric interference filters have a low solar absorption, the reflection of solar radiation which comes from various directions is too high. It was found that only rugate filters fulfill the requirements for operation under high-flux solar radiation with different incident angles. A thermodynamic qualification simulation of the rugate coating on a window of a flat-plate receiver showed a reduction of almost 175 K in mean window temperature and 11% in receiver losses compared to an uncoated window. For the configuration of a pressurized receiver (REFOS type), the temperature could be reduced by 65 K with slightly reduced receiver losses. Finally, a first 25-µm thick rugate filter was manufactured and optically characterized. The measured spectra fitted approximately the design spectra, except for two absorption peaks which can be avoided in future depositions by changing the deposition geometry and using in-situ monitoring. The issue of this paper is to share the work done on the choice of filter type, filter design, thermodynamic evaluation, and deposition experiments

Infrared-Reflective Coating on Fused Silica for a Solar High-Temperature Receiver

In concentrating solar power, high-temperature solar receivers can provide heat to highly efficient cycles for electricity or chemical production. Excessive heating of the fused-silica window and the resulting recrystallization are major problems of high-temperature receivers using windows. Excessive window temperatures can be avoided by applying an infrared-reflective solar-transparent coating on the fused-silica window inside. Both glass temperatures and receiver losses can be reduced. An ideal coating reflects part of the thermal spectrum (lambda>2.5 µm) of the hot absorber (1100°C) back onto it without reducing solar transmittance. Extensive radiation simulations were done to screen different filter types. The examined transparent conductive oxides (TCO) involve a high solar absorptance, inhibiting their use in high-concentration solar systems. Although conventional dielectric interference filters have a low solar absorption, the reflection of solar radiation which comes from various directions is too high. It was found that only rugate filters fulfill the requirements for operation under high-flux solar radiation with different incident angles. A thermodynamic qualification simulation of the rugate coating on a window of a flat-plate receiver showed a reduction of almost 175 K in mean window temperature and 11% in receiver losses compared to an uncoated window. For the configuration of a pressurized receiver (REFOS type), the temperature could be reduced by 65 K with slightly reduced receiver losses. Finally, a first 25-µm thick rugate filter was manufactured and optically characterized. The measured spectra fitted approximately the design spectra, except for two absorption peaks which can be avoided in future depositions by changing the deposition geometry and using in-situ monitoring. The issue of this paper is to share the work done on the choice of filter type, filter design, thermodynamic evaluation, and deposition experiments