Синтез, микроструктура и магнитные свойства магнитомягких пленок СоР

Soft magnetic thin CoP films were obtained by means of chemical metallization from aqueous cobalt salt solution in the presence of sodium hydroxide, citric acid and sodium hypophosphite as the reducing agent. The optimal values of the magnetic film parameters (saturation magnetization and width of ferromagnetic resonance line) were obtained by variation of composition of work solutions. It allows to reduce losses in their application in microwave devices. Microphotographs of magnetic film indicate a grain structure with a grain size of about 50 nm and presence of inclusions with the size of 3-5 nm. To determine the magnetic parameters of the investigated films the method of ferromagnetic resonance (FMR) absorption curves processing is used. The values of FMR line width and an effective magnetization of film material saturation were obtained.Приведены результаты исследования свойств магнитомягких тонких пленок СоР, полученных методом химической металлизации из водного раствора на основе цитратных комплексов с применением в качестве щелочного реагента NaOH. С помощью вариации составов рабочих растворов получены оптимальные значения магнитных параметров пленок: намагниченности насыщения и ширины линии ферромагнитного резонанса

Effect of alkali reagents on the crystal structure of chemically deposited CoP films

Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.Abstract—The effect alkali reagents have on the crystal structure of CoP films prepared via chemical depo sition is investigated. It is shown that the use of sodium hydrogen carbonate and ammonium hydroxide in low concentrations leads to growth of the hexagonal phase in the films. As the concentration of alkali reagents is increased, the formation of a cubic or amorphous phase is observed

Influence of solution acidity on growth kinetics, structure and magnetic properties of Co-P films, obtained by chemical deposition

The results of studies of the effect of solution acidity on the growth kinetics, structure and magnetic properties of Co-P films obtained by chemical deposition are presented. It was shown that the growth of Co-P films in the low pH region occurs mainly due to the growth of crystallite sizes, and in the high pH region, due to an increase in the nucleation rate. From the analysis of the chemical equilibrium of redox reactions, taking into account the balance of citrate and hydroxyl complexes of Co, a qualitative explanation of the features of the change in the rate and nature of the deposition of Co atoms from pH is proposed

On Nature of the Induced Anisotropy in the Chemically Deposited Со‒Р Films

The induced magnetic anisotropy in the Со‒Рfilms prepared by chemical deposition from liquid solutions in a magnetic field has been investigated. The pronounced difference between the anisotropy values and relaxation times points out the existence of different physical mechanisms responsible for the occurrence of anisotropy of the Со‒Р films at low and high pH values. Possible mechanisms of the induced anisotropy in the Со‒Р films prepared at different pH values are discussed

Synthesis, Microstructure and Magnetic Properties of Soft Magnetic CoP Films

Soft magnetic thin CoP films were obtained by means of chemical metallization from aqueous cobalt salt solution in the presence of sodium hydroxide, citric acid and sodium hypophosphite as the reducing agent. The optimal values of the magnetic film parameters (saturation magnetization and width of ferromagnetic resonance line) were obtained by variation of composition of work solutions. It allows to reduce losses in their application in microwave devices. Microphotographs of magnetic film indicate a grain structure with a grain size of about 50 nm and presence of inclusions with the size of 3-5 nm. To determine the magnetic parameters of the investigated films the method of ferromagnetic resonance (FMR) absorption curves processing is used. The values of FMR line width and an effective magnetization of film material saturation were obtained

On Nature of the Induced Anisotropy in the Chemically Deposited Со‒Р Films

Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.The induced magnetic anisotropy in the Со‒Р films prepared by chemical deposition from liquid solutions in a magnetic field has been investigated. The pronounced difference between the anisotropy values and relaxation times points out the existence of different physical mechanisms responsible for the occurrence of anisotropy of the Со‒Р films at low and high pH values. Possible mechanisms of the induced anisotropy in the Со‒Р films prepared at different pH values are discussed

Effect of alkali reagents on the crystal structure of chemically deposited CoP films

Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.Abstract—The effect alkali reagents have on the crystal structure of CoP films prepared via chemical depo sition is investigated. It is shown that the use of sodium hydrogen carbonate and ammonium hydroxide in low concentrations leads to growth of the hexagonal phase in the films. As the concentration of alkali reagents is increased, the formation of a cubic or amorphous phase is observed