Proceedings of the Fourth Caldwell Conference, St. Catherines Island, Georgia, March 27-29, 2009.

391 p. : ill. (chiefly col.), maps (chiefly col.) ; 26 cm. "Issued March 23, 2011."This edited volume addresses the geoarchaeology of St. Catherines Island (Georgia). The field of geoarchaeology has typically been defined as either geology pursued within an archaeological framework or (sometimes the reverse) as archaeology framed with the help of geological methodology. Either way, the formalized objectives of geoarchaeology define a broad range of pursuits, from placing archaeological sites into relative and absolute temporal context through the application of stratigraphic principles and absolute dating techniques, to understanding the natural processes of site formation, to reconstructing the landscapes that existed around a site or group of sites at the time of occupation. The editors of this volume have generally followed the lead of G.R. Rapp and C.L. Hill (2006, Geoarchaeology : the earth-science approach to archaeological interpretation) by stressing the importance of multiple viewpoints and methodologies in applying geoscience techniques to evaluate the archaeological record. In the broadest sense, then, Geoarchaeology of St. Catherines Island applies multiple earth science concepts, techniques, or knowledge bases to the known archaeological record and the processes that created that record. This volume consists of 16 papers presenting the newest research on the stratigraphic and geomorphological evolution of the St. Catherines Island landscape. Of particular interest are presentations addressing the relative timing and nature of sedimentation, paleobiology, sea level change, stream capture, hydrology, and erosional patterning evident on St. Catherines Island (and to some degree the rest of the Georgia Bight). These papers were initially presented at the Fourth Caldwell Conference, cosponsored by the American Museum of Natural History and the St. Catherines Island Foundation, held on St. Catherines Island (Georgia), March 27-29, 2009. Table of contents: Why this archaeologist cares about geoarchaeology : some pasts and futures of St. Catherines Island / David Hurst Thomas -- Evolution of late Pleistocene-Holocene climates and environments of St. Catherines Island and the Georgia Bight / Fredrick J. Rich, Anthony Vega, and Frank J. Vento -- Geoarchaeological research at St. Catherines Island : defining the geological foundation / Gale A. Bishop, Brian K. Meyer, R. Kelly Vance, and Fredrick J. Rich -- Development of a late Pleistocene-Holocene genetic stratigraphic framework for St. Catherines Island : archaeological implications / Frank J. Vento and Patty A. Stahlman -- Ichnological diagnosis of ancient storm-washover fans, Yellow Banks Bluff, St. Catherines Island / Anthony J. Martin and Andrew K. Rindsberg -- Quaternary vegetation and depositional history of St. Catherines Island / Fredrick J. Rich and Robert K. Booth -- Recent shoreline erosion and vertical accretion patterns, St. Catherines Island / Donald B. Potter Jr. -- Role of storm events in beach ridge formation, St. Catherines Island / Harold B. Rollins, Kathi Beratan, and James E. Pottinger -- Drainage changes at Ossabaw, St. Catherines, and Sapelo sounds and their influence on island morphology and spit building on St. Catherines Island / Timothy M. Chowns -- Vibracores and vibracore transects : constraining the geological and cultural history of St. Catherines Island / Gale A. Bishop, David Hurst Thomas, Matthew C. Sanger, Brian K. Meyer, R. Kelly Vance, Robert K. Booth, Fredrick J. Rich, Donald B. Potter, and Timothy Keith-Lucas -- Application of ground penetrating radar to investigations of the stratigraphy, structure, and hydrology of St. Catherines Island / R. Kelly Vance, Gale A. Bishop, Fredrick J. Rich, Brian K. Meyer, and Eleanor J. Camann -- Postsettlement dispersal and dynamic repopulation of estuarine habitats by adult Mercenaria mercenaria, St. Catherines Island / Robert S. Prezant, Harold B. Rollins, and Ronald B. Toll -- The foundation for sea turtle geoarchaeology and zooarchaeology : morphology of recent and ancient sea turtle nests, St. Catherines Island, Georgia, and Cretaceous Fox Hills Sandstone, Elbert County, Colorado / Gale A. Bishop, Fredric L. Pirkle, Brian K. Meyer, and William A. Pirkle -- Sea turtle habitat deterioration on St. Catherines Island : defining the modern transgression / Gale A. Bishop and Brian K. Meyer -- Modeling indigenous hunting and harvesting of sea turtles and their eggs on the Georgia Coast / Gale A. Bishop, David Hurst Thomas, and Brian K. Meyer -- Geomorphology, sea level, and marine resources : St. Catherines Island / Harold B. Rollins and David Hurst Thomas -- Appendix 1. Noncultural radiocarbon record from St. Catherines Island : a compendium -- Appendix 2. Vibracore record from St. Catherines Island : a compendium.Conference sponsored by the American Museum of Natural History and the St. Catherines Island Foundation

Heavy-Mineral Mining in the Atlantic Coastal Plain and What Deposit Locations Tell Us about Ancient Shorelines

Economic mining of heavy-mineral sands has a long history in the Atlantic Coastal Plain. From the early part of the 20th century to date, a total of 11 heavy-mineral ore bodies either have been or currently are being mined in Florida and Georgia. Additional deposits have been lost to mining, primarily due to cultural events, or are waiting future exploitation. These deposits have different origins, as has been seen during recent evaluations of the deposits, some in contrast to conventional depositional models. It has long been believed that deposits formed along shorelines at the height of major marine transgressions, but it is now postulated that some heavy-mineral-bearing sands accumulated on regressional beach ridge plains during periods of temporary stillstands or during slight transgressions that accompanied general marine regressions. Although many deposits might indeed have formed as conventional beach placers, others might have accumulated as deposits associated with fluvial–deltaic regimes or with vegetational baffles. These different origins are reflected in the chemical and physical characteristics of the deposits as well as grain size of the sediment. The relationship of the heavy-mineral mineral deposits (location) to the landforms in the Atlantic Coastal Plain provides insight into the ancient shorelines of the Atlantic Coastal Plain

Depositional Environment of the Heavy-Mineral Deposits of Bailey, North Carolina, U.S.A

The Bailey, North Carolina, heavy-mineral deposits cover 12.9 square kilometers and contain 5.72 million metric tons of heavy minerals. The sediments comprising this deposit average 6.2 meters thick and contain an average of 4.72 weight percent heavy minerals. Valuable heavy minerals comprise 65 to 70 percent of the heavy-mineral suite and are comprised of ilmenite, leucoxene, rutile, and zircon. Most of the Bailey heavy-mineral concentrations lie south, southeast, east, and northeast of the town of Bailey, North Carolina. In this area, unconsolidated Cenozoic sediments of the inner Coastal Plain unconformably overlie the roughly circular Upper Paleozoic Sims pluton which intrudes the older slate belt rocks of the region. The Kenly and Hawley heavy-mineral deposits, south of the Bailey deposits, are probably a continuation of the Bailey deposits. The separation of the two areas of heavy-mineral concentrations most likely is the result of post-depositional stream erosion. It is hypothesized that tides and fluvial processes served as the main agents for concentrating the heavy minerals. It is also hypothesized that the presence of delta and salt water marsh environments resulted in the accumulation of the majority of the kaolin clay that is present. Heavy minerals of the Bailey deposits were probably carried by the Neuse River and deposited in a delta at the edge of a salt marsh. A combination of the crossbedding and Ophiomorpha strongly suggest that the ancient sediments were deposited in subtidal high-energy shoals associated with a tidally-dominated channel of moderate size, such as an inlet or sound associated with barrier islands. Thus, the clay and heavy-mineral concentrations seem to have been partially the result of tidal and fluvial processes operating in a shallow marine to brackish (salt marsh) depositional environment. The Sims pluton appears to have played a role in influencing the path of the Neuse River and, hence, the formation of the Bailey deposits. Based on the pollen present, the Bailey heavy-mineral deposits are probably of Late Pliocene or Early Pleistocene age

Assessing chiral self-recognition using chiral stationary phases

[[abstract]]Chiral stationary phases were synthesized and their ability to separate racemic precursors from which they were derived was assessed. Taken in conjunction with homochiral recognition previously observed in the solid state, the results of this study reveal that a geometrically controlling pi-pi interaction has a profound influence on molecular recognition

Confirmation of Statin and Fibrate Use from Small-Volume Archived Plasma Samples by High-Throughput LC-MS/MS Method

Designing studies for lipid-metabolism-related biomarker discovery is challenging because of the high prevalence of various statin and fibrate usage for lipid-lowering therapies. When the statin and fibrate use is determined based on self-reports, patient adherence to the prescribed statin dose regimen remains unknown. A potentially more accurate way to verify a patient’s medication adherence is by direct analytical measurements. Current analytical methods are prohibitive because of the limited panel of drugs per test and large sample volume requirement that is not available from archived samples. A 4-min-long method was developed for the detection of seven statins and three fibrates using 10 µL of plasma analyzed via reverse-phase liquid chromatography and tandem mass spectrometry. The method was applied to the analysis of 941 archived plasma samples collected from patients before cardiac catheterization. When statin use was self-reported, statins were detected in 78.6% of the samples. In the case of self-reported atorvastatin use, the agreement with detection was 90.2%. However, when no statin use was reported, 42.4% of the samples had detectable levels of statins, with a similar range of concentrations as the samples from the self-reported statin users. The method is highly applicable in population studies designed for biomarker discovery or diet and lifestyle intervention studies, where the accuracy of statin or fibrate use may strongly affect the statistical evaluation of the biomarker data