800 research outputs found
Information Length and Localization in One Dimension
The scaling properties of the wave functions in finite samples of the one
dimensional Anderson model are analyzed. The states have been characterized
using a new form of the information or entropic length, and compared with
analytical results obtained by assuming an exponential envelope function. A
perfect agreement is obtained already for systems of -- sites over
a very wide range of disorder parameter . Implications for
higher dimensions are also presented.Comment: 11 pages (+3 Figures upon request), Plain TE
Multifractality beyond the Parabolic Approximation: Deviations from the Log-normal Distribution at Criticality in Quantum Hall Systems
Based on differences of generalized R\'enyi entropies nontrivial constraints
on the shape of the distribution function of broadly distributed observables
are derived introducing a new parameter in order to quantify the deviation from
lognormality. As a test example the properties of the two--measure random
Cantor set are calculated exactly and finally using the results of numerical
simulations the distribution of the eigenvector components calculated in the
critical region of the lowest Landau--band is analyzed.Comment: LaTeX 4 pages, 3 EPS included, to appear in Europhysics Letter
One-parameter superscaling in three dimensions
Numerical and analytical details are presented on the newly discovered
superscaling property of the energy spacing distribution in the three
dimensional Anderson model.Comment: 4 pages, 3 figure
The generalized localization lengths in one dimensional systems with correlated disorder
The scale invariant properties of wave functions in finite samples of one
dimensional random systems with correlated disorder are analyzed. The random
dimer model and its generalizations are considered and the wave functions are
compared. Generalized entropic localization lengths are introduced in order to
characterize the states and compared with their behavior for exponential
localization. An acceptable agreement is obtained, however, the exponential
form seems to be an oversimplification in the presence of correlated disorder.
According to our analysis in the case of the random dimer model and the two new
models the presence of power-law localization cannot be ruled out.Comment: 7 pages, LaTeX (IOP style), 2 figure
On Renyi entropies characterizing the shape and the extension of the phase space representation of quantum wave functions in disordered systems
We discuss some properties of the generalized entropies, called Renyi
entropies and their application to the case of continuous distributions. In
particular it is shown that these measures of complexity can be divergent,
however, their differences are free from these divergences thus enabling them
to be good candidates for the description of the extension and the shape of
continuous distributions. We apply this formalism to the projection of wave
functions onto the coherent state basis, i.e. to the Husimi representation. We
also show how the localization properties of the Husimi distribution on average
can be reconstructed from its marginal distributions that are calculated in
position and momentum space in the case when the phase space has no structure,
i.e. no classical limit can be defined. Numerical simulations on a one
dimensional disordered system corroborate our expectations.Comment: 8 pages with 2 embedded eps figures, RevTex4, AmsMath included,
submitted to PR
QUANTUM CHEMICAL INTERPRETATION OF THE REACTION BETWEEN L-ASCORBIC ACID AND FORMALDEHYDE AND ITS BIOLOGICAL SIGNIFICANCE
We have recognized a new nucleophilic addition reaction between L-ascorbic acid and
formaldehyde in biological circumstances (pH 7.4, T = 300 K). UV spectroscopic investi-
gation showed that the C2=C3 double bond of ascorbic acid rapidly disappears during
the reaction, verifying that the addition breaks the double bond. On the other hand, 13C
NMR studies have proved that on atom C2 an additional C-C single bond is formed. Ex-
act interpretation of the reaction mechanism is possible only by using quantum chemical
argumentations. Ab initio calculations show that in ionized (anionic) form of L-ascorbic
acid in water solution the Mulliken excess atomic charge is strongly negative on atom C2
while C1 and C3 exhibit significant positive net charges. Coulombic attraction arranges
formaldehyde's C=O double bond over the C2=C3 double bond of ascorbic acid and the
interaction of the two loose π-electron systems causes forming of a new σ C-C bond. The
described reaction plays a protective role in biological systems, since in this way the toxic
carcinogenic formaldehyde can be eliminated
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