Mechanical Lock Joint for Effective In-Plane Application of Concentrated Loads to Thin Polymer Matrix Laminates

Means of in-plane loading of thin laminates with concentrated loads are of high practical importance. The purpose of this work was to investigate experimentally and numerically the mechanism of load transfer, load capacity, damage and associated failure modes of a specific, mechanical lock joint intended for in-plane loading of thin laminate plates with concentrated loads. The experimental investigations were carried out with the digital image corelation (DIC) and computed tomography (CT), and numerical ones with the help of a non-linear FE modelling, accounting for progressive damage. For this purpose, a special algorithm was developed accounting for a continuous degradation of the stiffness moduli of the laminate with strains according to the custom defined degradation law. Due to the specific design, the joint loaded a laminate plate with its front and rear parts, unlike a typical bolt joint transferring a load only by contact pressure developed at the front side of a bolt. Due to this feature, the load capacity of the joint was almost two times higher than that of a typical bolt joint of the same relevant dimensions

Resistance of Polymeric Laminates Reinforced with Fabrics against the Growth of Delaminations

Dependence of the initiation values of the Strain Energy Release Rate, GCi, on the orientation of the reinforcement direction α relative to the delamination front was investigated for two laminates of different interfacial ply arrangements. In the case of the first laminate, the delamination was located at the interface of the layers reinforced with symmetric fabric and unidirectional fabric. In the case of the second laminate, the delamination was located at the interface of layers reinforced with symmetric fabric. In both laminates, the orientation of fibers in the layers separated by the delamination differed by 45° regarding the warp directions. The investigations were carried out for Mode I, Mode II, and Mixed-Mode I/II (GII/GI = 1 and GII/GI = 1.7) loadings using hybrid beam specimens. The major problem appearing in the intended tests was the inevitable lack of symmetry in the xz and xy planes of the specimens and the resulting deformation and stress–strain couplings, causing undesired loading modes. To decrease these couplings, especially designed hybrid beam specimens were used. An auxiliary finite element analysis was performed to assess the remaining effects of the reduced couplings. To ascertain whether statistically significant differences between Gci values for different α occurred, the one-way analysis of variance supplemented by Levene’s test was carried out. The dependence of Gci on α was found out for both laminates. However, it was not equally strong, and it turned out that the loading mode and the interfacial ply were arrangement sensitive

Delamination Resistance of Laminates with Various Stacking Sequences against Low Velocity Impacts

score: 5collation: 143-14

Growth stability analysis of embedded delaminations with the use of FE node relocation procedure and effective resistance curve concept

Embedded delamination growth stability was analysed with the help of the FEM combined with a specially developed procedure for node relocation to obtain a smooth variation of the SERR components along the delamination contour. The procedure consisted in the replacement of the actual material with the very compliant fictitious one and the displacement of the delamination front nodes by the previously determined distance in a local coordinate system. Due to this loading, the new delamination front was created. Subsequently, the original material was restored. Evolution under inplane compression of three initially circular delaminations of diameters d = 30, 40 and 50 mm embedded in thin laminates of two different stacking sequences, i.e., 0 ◦ 4 //0 ◦ 24 and 0 ◦ 4 //90◦ 20/0 ◦ 4 were considered. It was found that the growth history and the magnitude of the load that triggers unstable delamination growth depended mainly on the combined effects of the initial delamination size, delamination contour, out of plane post-buckling geometry of the disbonded layers, reinforcement arrangement, and magnitude and variation of the SERR components along the delamination contour. To present the combined effect of these features, an original concept of the effective resistance curve, GReff , was introduced

Delamination Resistance Of Laminate Made With VBO MTM46/HTS Prepreg

A laminate made with the Vacuum Bag Only (VBO) prepregs can be cured out of autoclave. Because of low curing pressure such a process can result in deterioration of laminate mechanical properties. They can be significantly lower than those displayed by the autoclave cured ones. The resistance against delamination can be among the most affected. Since this property is a week point of all the laminates it was of particular interest. Delamination resistance of unidirectional laminate made from VBO MTM46/HTS(12K) prepreg was in the scope of the presented research and the critical values of the Strain Energy Release Rates and the Paris-type equations corresponding to Mode I, Mode II and Mixed-Mode I/II static and cyclic loadings, respectively, were determined

Field repair of a severely damaged FG/epoxy fuselage

The paper presents development of a repair procedure for a severely damaged primary laminate structure of a light aircraft, certified in accordance with CS22. The procedure was developed with the assumption that it would be a field repair carried out by people of average manual skills, who have not been trained in repairs of composite structures. To develop the procedure, a typical FG/epoxy laminate glider fuselage was used. The primary objective of the repair was to restore the original fuselage stiffness, while maintaining possibly low stress concentrations resulting from the repairs. To facilitate development of the repair, an FE model was developed. It was parametrized to be useful for design of similar repairs of similar structures. The experimental work done with the use of a real structure allowed the authors to verify numerical simulations, which were found to be correct

Mechanical Lock Joint for Effective In-Plane Application of Concentrated Loads to Thin Polymer Matrix Laminates

Means of in-plane loading of thin laminates with concentrated loads are of high practical importance. The purpose of this work was to investigate experimentally and numerically the mechanism of load transfer, load capacity, damage and associated failure modes of a specific, mechanical lock joint intended for in-plane loading of thin laminate plates with concentrated loads. The experimental investigations were carried out with the digital image corelation (DIC) and computed tomography (CT), and numerical ones with the help of a non-linear FE modelling, accounting for progressive damage. For this purpose, a special algorithm was developed accounting for a continuous degradation of the stiffness moduli of the laminate with strains according to the custom defined degradation law. Due to the specific design, the joint loaded a laminate plate with its front and rear parts, unlike a typical bolt joint transferring a load only by contact pressure developed at the front side of a bolt. Due to this feature, the load capacity of the joint was almost two times higher than that of a typical bolt joint of the same relevant dimensions

The enantioselective synthesis of (S)-(+)-mianserin and (S)-(+)-epinastine

A simple enantioselective synthetic procedure for the preparation of mianserin and epinastine in optically pure form is described. The key step in the synthetic pathway is the asymmetric reduction of the cyclic imine using asymmetric transfer hydrogenation conditions

Some mechanistic aspects regarding the Suzuki–Miyaura reaction between selected ortho-substituted phenylboronic acids and 3,4,5-tribromo-2,6-dimethylpyridine

Background: Atropisomers are very interesting stereoisomers having axial chirality resulting from restricted rotation around single bonds and are found in various classes of compounds. ortho-Substituted arylpyridines are an important group of them. A regio- and atropselective Suzuki–Miyaura cross-coupling reaction on 3,4,5-tribromo-2,6-dimethylpyridine was studied.Results: Reactions with various amounts of ortho-substituted phenylboronic acids with 3,4,5-tribromo-2,6-dimethylpyridine gave a series of mono- di- and triarylpyridine derivatives which allowed to draw conclusions about the order of substitution. Also, the observed selectivity in the case of ortho-methoxyphenylboronic acid suggested an additional metal O-chelation effect in the transition state, apparently not present in the ortho-chloro analogues. The rotational barrier in selected atropisomers was determined on the basis of HT NMR and thermal epimerisation experiments. The structure of most presented atropisomeric derivatives of 2,6-dimethylpyridine was confirmed by single-crystal X-ray analysis. Racemic chiral, differently substituted atropisomers were also examined by 1H NMR spectroscopy in the presence of a chiral solvating agent.Conclusion: This regio- and atropselectivity may be generally applicable to other arylpyridine systems. A regio- and atropselective Suzuki–Miyaura cross-coupling process has been observed, giving an efficient access to a class of atropisomeric compounds. An opposite selectivity using a differently ortho-substituted phenylbornic acid was observed

The Length of N-Glycans of Recombinant H5N1 Hemagglutinin Influences the Oligomerization and Immunogenicity of Vaccine Antigen

Hemagglutinin glycoprotein (HA) is a principle influenza vaccine antigen. Recombinant HA-based vaccines become a potential alternative for traditional approach. Complexity and variation of HA N-glycosylation are considered as the important factors for the vaccine design. The number and location of glycan moieties in the HA molecule are also crucial. Therefore, we decided to study the effect of N-glycosylation pattern on the H5 antigen structure and its ability to induce immunological response. We also decided to change neither the number nor the position of the HA glycosylation sites but only the glycan length. Two variants of the H5 antigen with high mannose glycosylation (H5hm) and with low-mannose glycosylation (H5Man5) were prepared utilizing different Pichia strains. Our structural studies demonstrated that only the highly glycosylated H5 antigen formed high molecular weight oligomers similar to viral particles. Further, the H5hm was much more immunogenic for mice than H5Man5. In summary, our results suggest that high mannose glycosylation of vaccine antigen is superior to the low glycosylation pattern. Our findings have strong implications for the recombinant HA-based influenza vaccine design