The molecular emission-line spectrum of IRC +10216 between 330 and 358 GHz

We have conducted a spectral line survey of IRC + 10216 using the Caltech Submillimeter Observatory to an average sensitivity of ≾95 mK. A deconvolution algorithm has been used to derive the continuous single-sideband spectrum from 330.2 to 358.1 GHz. A total of 56 spectral lines were detected of which 54 have been identified with 8 molecules and a total of 18 isotopomers. The observed lines are used to derive column densities and relative abundances for the detected species. Within this frequency range the spectral lines detected contribute the majority of the total flux emitted by IRC + 10216. We use the derived column densities and excitation temperatures to simulate the molecular line emission (assuming LTE) at frequencies up to 1000 GHz. The observed and simulated flux from line emission is compared to broadband total flux measurements and to dust emission assuming a power-law variation of the dust emissivity. We conclude that significant corrections for the line flux must be made to broadband flux measurements of IRC + 10216 at wavelengths longer than ~750 µm

Herschel observations in the ultracompact HII region Mon R2: Water in dense photon-dominated regions (PDRs)

Context. Monoceros R2, at a distance of 830 pc, is the only ultracompact Hii region (UC H_(II)) where the photon-dominated region (PDR) between the ionized gas and the molecular cloud can be resolved with Herschel. Therefore, it is an excellent laboratory to study the chemistry in extreme PDRs (G_0 > 10^5 in units of Habing field, n > 10^6 cm^9−3)). Aims. Our ultimate goal is to probe the physical and chemical conditions in the PDR around the UC H_(II) Mon R2. Methods. HIFI observations of the abundant compounds ^(13)CO, C^(18)O, o-H_2^(18)O, HCO^+, CS, CH, and NH have been used to derive the physical and chemical conditions in the PDR, in particular the water abundance. The modeling of the lines has been done with the Meudon PDR code and the non-local radiative transfer model described by Cernicharo et al. Results. The ^(13)CO, C^(18)O, o-H^(18)_2O, HCO^+ and CS observations are well described assuming that the emission is coming from a dense (n = 5 × 10^6 cm^(−3), N(H_2) > 10^(22) cm^(−2)) layer of molecular gas around the H_(II) region. Based on our o-H^(18)_2O observations, we estimate an o-H_2O abundance of ≈2 × 10^(−8). This is the average ortho-water abundance in the PDR. Additional H^(18)_2O and/or water lines are required to derive the water abundance profile. A lower density envelope (n ~ 10^5 cm^(−3), N(H_2) = 2−5 × 10^(22) cm^(−2)) is responsible for the absorption in the NH 1_1 → 0_2 line. The emission of the CH ground state triplet is coming from both regions with a complex and self-absorbed profile in the main component. The radiative transfer modeling shows that the ^(13)CO and HCO^+ line profiles are consistent with an expansion of the molecular gas with a velocity law, v_e = 0.5 × (r/R_(out))^(−1) km s^(−1), although the expansion velocity is poorly constrained by the observations presented here. Conclusions. We determine an ortho-water abundance of ≈2 × 10^(−8) in Mon R2. Because shocks are unimportant in this region and our estimate is based on H^(18)_2O observations that avoids opacity problems, this is probably the most accurate estimate of the water abundance in PDRs thus far

A Line Survey of Orion KL from 325 to 360 GHz

We present a high-sensitivity spectral line survey of the high-mass star-forming region Orion KL in the 325-360 GHz frequency band. The survey was conducted at the Caltech Submillimeter Observatory on Mauna Kea, Hawaii. The sensitivity achieved is typically 0.1-0.5 K and is limited mostly by the sideband separation method utilized. We find 717 resolvable features consisting of 1004 lines, among which 60 are unidentified. The identified lines are due to 34 species and various isotopomers. Most of the unidentified lines are weak, and many of them most likely due to isotopomers or vibrationally or torsionally excited states of known species with unknown line frequencies, but a few reach the 2-5 K level. No new species have been identified, but we were able to strengthen evidence for the identification of ethanol in Orion and found the first nitrogen sulfide line in this source. The molecule dominating the integrated line emission is SO_2, which emits twice the intensity of CO, followed by SO, which is only slightly stronger than CO. In contrast, the largest number of lines is emitted from heavy organic rotors like HCOOCH_3, CH_3CH_2CN, and CH_3OCH_3, but their contribution to the total flux is unimportant. CH_3OH is also very prominent, both in the number of lines and in integrated flux. An interesting detail of this survey is the first detection of vibrationally excited HCN in the v_2 = 2 state, 2000 K above ground. Clearly this is a glimpse into the very inner part of the Orion hot core

Thermal expansion of the spin-1/2 Heisenberg-chain compound Cu(C4_4H4_4N2_2)(NO3_3)2_2

Compounds containing magnetic subsystems representing simple model spin systems with weak magnetic coupling constants are ideal candidates to test theoretical predictions for the generic behavior close to quantum phase transitions. We present measurements of the thermal expansion and magnetostriction of the spin-1/2-chain compound copper pyrazine dinitrate Cu(C$_4$H$_4$N$_2$)(NO$_3$)$_2$. Of particular interest is the low-temperature thermal expansion close to the saturation field $H_c \simeq 13.9 \mathrm{T}$, which defines a quantum phase transition from the gapless Luttinger liquid state to the fully saturated state with a finite excitation gap. We observe a sign change of the thermal expansion for the different ground states, and at the quantum critical point $H_c$ the low-temperature expansion approaches a $1/\sqrt{T}$ divergence. Thus, our data agree very well with the expected quantum critical behaviour.Comment: 4 pages, 3 figures; to appear in the proceedings of the ICM 09 held in Karlsruhe, German

Gas morphology and energetics at the surface of PDRs: New insights with Herschel observations of NGC 7023

Context. We investigate the physics and chemistry of the gas and dust in dense photon-dominated regions (PDRs), along with their dependence on the illuminating UV field. Aims. Using Herschel/HIFI observations, we study the gas energetics in NGC 7023 in relation to the morphology of this nebula. NGC 7023 is the prototype of a PDR illuminated by a B2V star and is one of the key targets of Herschel. Methods. Our approach consists in determining the energetics of the region by combining the information carried by the mid-IR spectrum (extinction by classical grains, emission from very small dust particles) with that of the main gas coolant lines. In this letter, we discuss more specifically the intensity and line profile of the 158 μm (1901 GHz) [C ii] line measured by HIFI and provide information on the emitting gas. Results. We show that both the [C ii] emission and the mid-IR emission from polycyclic aromatic hydrocarbons (PAHs) arise from the regions located in the transition zone between atomic and molecular gas. Using the Meudon PDR code and a simple transfer model, we find good agreement between the calculated and observed [C ii] intensities. Conclusions. HIFI observations of NGC 7023 provide the opportunity to constrain the energetics at the surface of PDRs. Future work will include analysis of the main coolant line [O i] and use of a new PDR model that includes PAH-related species

Discovery of Water Vapor in the High-redshift Quasar APM 08279+5255 at z = 3.91

We report a detection of the excited 2_(20)-2_(11) rotational transition of para-H_2O in APM 08279+5255 using the IRAM Plateau de Bure Interferometer. At z = 3.91, this is the highest-redshift detection of interstellar water to date. From large velocity gradient modeling, we conclude that this transition is predominantly radiatively pumped and on its own does not provide a good estimate of the water abundance. However, additional water transitions are predicted to be detectable in this source, which would lead to an improved excitation model. We also present a sensitive upper limit for the hydrogen fluoride (HF) J = 1-0 absorption toward APM 08279+5255. While the face-on geometry of this source is not favorable for absorption studies, the lack of HF absorption is still puzzling and may be indicative of a lower fluorine abundance at z = 3.91 compared with the Galactic interstellar medium

Enrichment Procedures for Soft Clusters: A Statistical Test and its Applications

Clusters, typically mined by modeling locality of attribute spaces, are often evaluated for their ability to demonstrate ‘enrichment’ of categorical features. A cluster enrichment procedure evaluates the membership of a cluster for significant representation in pre-defined categories of interest. While classical enrichment procedures assume a hard clustering definition, in this paper we introduce a new statistical test that computes enrichments for soft clusters. We demonstrate an application of this test in refining and evaluating soft clusters for classification of remotely sensed images