Watershed assessment modelling to identify critical sources of pollution and evaluate effectiveness of conservation management practices

Critical watershed assessments allow land managers to create strategic plans and prioritize funding and technical assistance when resources are limited. The Natural Resources Conservation Service (NRCS) National Water Quality Initiative (NWQI) provides a framework for watershed assessment to support long-term, strategic watershed planning and prioritize resources. The Tenmile Watershed in the Nooksack Basin in Whatcom County was selected as a pilot watershed for the NWQI assessment for Washington State in 2017. The primary objective of this assessment was to identify critical source areas (CSAs) within the watershed that were most susceptible to nutrient, sediment and bacteria export based on physical (terrain) features and land use. Secondary objectives were to model the effectiveness of conservation practices within CSAs and create an outreach plan for maximum engagement of landowners in the watershed improvement process. NOAA’s open-source Nonpoint Source Pollution and Erosion Comparison Tool (OpenNSPECT) was used to identify CSAs. Spatial data representing terrain features (soils, elevation and hydrology), precipitation, and land use cover within the watershed were collected, aggregated and input into OpenNSPECT. The model identified CSAs for nitrogen, phosphorus, pathogens, and sediment, as well as a combined ranking of all contaminants for the watershed. OpenNSPECT was then used to model the effects of implementation of different conservation practices on pollutant reduction. In one example, the model showed that implementation of winter cover crops on agricultural fields reduced the export area of nitrogen and phosphorus into the watershed by 92% and 79%, respectively, thus improving water quality in the Tenmile Watershed and Nooksack Basin. This assessment process can be used in any watershed to help understand where CSAs are located and how land conservation practices reduce pollutants, thus helping NRCS and local partners prioritize location and land use type (crop, farm, residential, etc.) for conservation practice implementation, including cost-share and technical assistance

Revealing core-valence interactions in solution with femtosecond X-ray pump X-ray probe spectroscopy

Abstract Femtosecond pump-probe spectroscopy using ultrafast optical and infrared pulses has become an essential tool to discover and understand complex electronic and structural dynamics in solvated molecular, biological, and material systems. Here we report the experimental realization of an ultrafast two-color X-ray pump X-ray probe transient absorption experiment performed in solution. A 10 fs X-ray pump pulse creates a localized excitation by removing a 1s electron from an Fe atom in solvated ferro- and ferricyanide complexes. Following the ensuing Auger–Meitner cascade, the second X-ray pulse probes the Fe 1s → 3p transitions in resultant novel core-excited electronic states. Careful comparison of the experimental spectra with theory, extracts +2 eV shifts in transition energies per valence hole, providing insight into correlated interactions of valence 3d with 3p and deeper-lying electrons. Such information is essential for accurate modeling and predictive synthesis of transition metal complexes relevant for applications ranging from catalysis to information storage technology. This study demonstrates the experimental realization of the scientific opportunities possible with the continued development of multicolor multi-pulse X-ray spectroscopy to study electronic correlations in complex condensed phase systems

Bycatch in gillnet fisheries threatens Critically Endangered small cetaceans and other aquatic megafauna

The conservation status of small cetaceans has significantly worsened since the 1980s, when the baiji was the only species of small cetacean listed as Endangered by IUCN. Now the baiji is almost certainly extinct and 13 other species, subspecies, or populations (hereafter units-to-conserve or units) of small cetaceans are listed as Critically Endangered (CR) on the IUCN Red List. Bycatch is the main threat to 11 of the CR units. Entanglement in gillnets contributed to the extinction of the baiji and is responsible for the imminent extinction of the vaquita. Unfortunately, there is no simple technical solution to the problem of bycatch of small cetaceans. If the 8 CR units with 100 or fewer remaining individuals are to be saved, conservation zones must be established where gillnets are eliminated and bans on their use are strictly enforced. Recent experience with the vaquita in Mexico demonstrates that enforcement of such conservation zones can be very difficult. Ineffective enforcement is also a problem for at least 4 of the other CR units. Time is very short and, unless major efforts are made now to address the bycatch problem, the prospects for CR small cetaceans and other at-risk aquatic megafauna are grim. The ultimate long-term solution to the bycatch problem is the development of efficient, inexpensive, alternative fishing gear that can replace gillnets without jeopardizing the livelihoods of fishermen. Good fishery governance and the direct involvement of fishing communities are also essential to the successful conservation of most threatened populations of small cetaceans.</p

SLC2A9 is a newly identified urate transporter influencing serum urate concentration, urate excretion and gout

Uric acid is the end product of purine metabolism in humans and great apes, which have lost hepatic uricase activity, leading to uniquely high serum uric acid concentrations (200?500 lM) compared with other mammals (3?120 lM)1. About 70% of daily urate disposal occurs via the kidneys, and in 5?25% of the human population, impaired renal excretion leads to hyperuricemia2. About 10% of people with hyperuricemia develop gout, an inflammatory arthritis that results from deposition of monosodium urate crystals in the joint. We have identified genetic variants within a transporter gene, SLC2A9, that explain 1.7?5.3% of the variance in serum uric acid concentrations, following a genome-wide association scan in a Croatian population sample. SLC2A9 variants were also associated with low fractional excretion of uric acid and/or gout in UK, Croatian and German population samples. SLC2A9 is a known fructose transporter3, and we now show that it has strong uric acid transport activity in Xenopus laevis oocytes