27 research outputs found

    An efficient synthesis of novel N-acetyl-3-alkanoyl and 3-dienoyl tetramic acids

    No full text

    Rh(II)-binaphthol phosphate catalysts in the enantioselective intramolecular oxonium ylide formation-[3,2] sigmatropic rearrangement of alpha-diazo-beta-ketoesters

    No full text
    The enantioselective intramolecular oxonium ylide formation-[3,2] sigmatropic rearrangement of α-diazo-β-ketoesters 9 using catalytic (1 mol%) dirhodium tetrakisbinaphthol phosphate catalysts 1 and 2 to give benzofuranones 11 in up to 62% e.e. is described. © 2001 Elsevier Science Ltd

    Synthesis and NMR spectroscopic studies of novel N-Acetyl-3-hydrazonoalkyl tetramic acids

    No full text
    3-(Hydrazonoethyl) and 3-(hydrazonobutyl) tetramic acids 6 - 11 are prepared by condensation reaction of N,3-diacetyl and N-acetyl-3-butanoyl tetramic acids, 4 and 5, with a variety of 1,2-(bis)-nucleophiles. The structure elucidation and the tautomeric equilibrium of the novel compounds 6-11 have been studied using 1H and 13C NMR spectroscopy
    corecore