Investigating the Synthesis and Characterization of a Novel “Green” H₂O₂-Assisted, Water-Soluble Chitosan/Polyvinyl Alcohol Nanofiber for Environmental End Uses

The present work highlights the formation of a novel green nanofiber based on H2O2-assisted water-soluble chitosan/polyvinyl alcohol (WSCHT/PVA) by using water as an ecofriendly solvent and genipin used as a nontoxic cross-linker. The 20/80 blend ratio was found to have the most optimum uniform fiber morphology. WSCHT retained the same structure as WISCHT. The prepared nanofibers were characterized by Scanning electron microscopy (SEM), Fourier transform spectroscopy (FTIR), Thermo gravimetric analysis (TGA), Differential scanning calorimeter (DSC), X-ray diffraction (XRD), Water Contact Angle (WCA) and Ultraviolet-visible spectroscopy (UV-vis). During electrospinning, the crystalline microstructure of the WSCHT/PVA underwent better solidification and after cross-linking there was an increase in the melting temperature of the fiber. Swelling ratio studies revealed noticeable increase in hydrophilicity with increase of WSCHT, which was further demonstrated by the decrease of contact angle from 64.74° to 14.68°. WSCHT/PVA nanofiber mats exhibit excellent UV blocking protection with less than 5% transmittance value and also showed improved in vitro drug release properties with stable release for longer duration (cross-linked fibers) and burst release for shorter duration (uncross linked) fibers. Finally our experimental data demonstrates excellent adsorption ability of Colour Index (C.I.) reactive black 5 (RB5) due to protonated amino groups

Investigation on the Thermo-Regulating Fabric by Using Phase Change Material for Modern Textile Practical Application

Phase change materials (PCM) which can store energy and increased thermal properties of fabric applied on over a narrow temperature range. It is antiphonal to temperature change by absorbing or releasing heat which is potential for human skin. PCM for Thermal Energy Storage (TES) are materials supplying thermal regulation and change particular phase in temperatures by absorbing and emitting medium condition heat. Polyethylene glycol (PEG-1000) is used as PCM in this experiment and we took a 2.5% concentration that was encapsulated by using an in-situ polymerization technique. PEG microcapsules are verified by measuring FTIR analysis and DSC studies. The heat storage capacity of 2.5% PEG coated fabric was determined to be 2842.5120 J/g and for binder coated fabric 1557.8 J/g by DSC analysis and FT-IR analysis of PEG microcapsules exhibited the highest peak at 3400-2400cm−1 this is the characteristic absorption peaks of –OH stretching vibrations and we got average stiffness values for binder coated is 0.49 (warp wise) and 0.57(weft wise) and for 2.5% PEG coated is 0.71(warp wise) and 0.98(weft wise).  After that the treated fabrics were characterized with respect to their morphology and the laundering durability testing of 5 and 10 cycles was evaluated for practical use. In this paper we investigated about cooling effect of Fabric by using 2.5%. PCMs via the storage of latent heat by producing microcapsules showed higher thermal energy amount, than the binder coated fabric

Organic Silicone Based Poly-Acrylate Binder Synthesis for Textile Pigment Printing

This present study deals about an organic silicone based poly-acrylate binder by using Emulsion Polymerization technique because it produces high molecular weight polymers, and there is no or negligible content of volatile organic compounds (VOC) for textile pigment printing. The binder was prepared by polymerizing hard monomers, soft monomers, functional monomers, and compound emulsifying agent, organic silicone, an initiator, pH adjustor and deionized water. Then the properties like sublimation test, durability test, fastness test, yellowness and softness testing were performed. The role of acrylic acid and Methyl methacrylate on the characterization of the polymers was detected and recorded. A material has been selected based on pervious study of different research and effect of silicone amount on film was observed

Ford Highway Driving RTK Dataset: 30,000 km of North American Highways

There is a growing need for vehicle positioning information to support Advanced Driver Assistance Systems (ADAS), Connectivity (V2X), and Autonomous Driving (AD) features. These range from a need for road determination ($<$5 meters), lane determination ($<$1.5 meters), and determining where the vehicle is within the lane ($<$0.3 meters). This paper presents the Ford Highway Driving RTK (Ford-HDR) dataset. This dataset includes nearly 30,000 km of data collected primarily on North American highways during a driving campaign designed to validate driver assistance features in 2018. This includes data from a representative automotive production GNSS used primarily for turn-by-turn navigation as well as an Inertial Navigation System (INS) which couples two survey-grade GNSS receivers with a tactical grade Inertial Measurement Unit (IMU) to act as ground truth. The latter utilized networked Real-Time Kinematic (RTK) GNSS corrections delivered over a cellular modem in real-time. This dataset is being released into the public domain to spark further research in the community.Comment: 8 pages, 4 figures, ION GNSS+ 202

Electrolyte influence on sorption behaviours of Direct Blue 71 dye on ramie fibre

Ramie loose fibre was dyed using Direct Blue 71 dye at 70, 80, 90 and 100°C without and with NaCl electrolyte in order to investigate the distinction of dye sorption behaviours. The results show that the dye exhaustion increases with addition of NaCl and shortens the equilibrium dyeing time. The dye adsorption process of dyeing without and with NaCl followed pseudo second-order kinetics, but the rate constant of sorption is larger for the latter compared to the former

Standalone and RTK GNSS on 30,000 km of North American Highways

There is a growing need for vehicle positioning information to support Advanced Driver Assistance Systems (ADAS), Connectivity (V2X), and Automated Driving (AD) features. These range from a need for road determination (<5 meters), lane determination (<1.5 meters), and determining where the vehicle is within the lane (<0.3 meters). This work examines the performance of Global Navigation Satellite Systems (GNSS) on 30,000 km of North American highways to better understand the automotive positioning needs it meets today and what might be possible in the near future with wide area GNSS correction services and multi-frequency receivers. This includes data from a representative automotive production GNSS used primarily for turn-by-turn navigation as well as an Inertial Navigation System which couples two survey grade GNSS receivers with a tactical grade Inertial Measurement Unit (IMU) to act as ground truth. The latter utilized networked Real-Time Kinematic (RTK) GNSS corrections delivered over a cellular modem in real-time. We assess on-road GNSS accuracy, availability, and continuity. Availability and continuity are broken down in terms of satellite visibility, satellite geometry, position type (RTK fixed, RTK float, or standard positioning), and RTK correction latency over the network. Results show that current automotive solutions are best suited to meet road determination requirements at 98% availability but are less suitable for lane determination at 57%. Multi-frequency receivers with RTK corrections were found more capable with road determination at 99.5%, lane determination at 98%, and highway-level lane departure protection at 91%.Comment: Accepted for the 32nd International Technical Meeting of the Satellite Division of The Institute of Navigation (ION GNSS+ 2019), Miami, Florida, September 201

Effluent-free deep dyeing of cotton fabric with cacao husk extracts using the Taguchi optimization method

Textile dyehouses are under scrutiny because they discharge colored and hazardous effluents to waterways. There is a need to develop an alternative dyeing system that does not produce any hazardous effluent. The waterless dyeing method could be a viable eco-friendly alternative to the traditional aqueous dyeing method. In this work, cacao husk extracts were used as a natural dye in the decamethylcyclopentasiloxane (D5) medium for the dyeing of cotton fabric, and subsequently, the dyed cotton was treated by a fixation treatment with a cationic dye-fixing agent in the D5 medium. The cotton fabric dyed with cacao husk extracts exhaustion in the waterless D5 medium exhibited better exhaustion, fixation rate, color strength (K/S), and colorfastness to washing and rubbing compared to the fabric dyed with the same extracts using the conventional aqueous dyeing and dye-fixing methods. The dye exhaustion percentage and the dye fixation rate were 95.6% and 94.8% in the D5 medium respectively, which is significantly higher in comparison to a 48.2% dye exhaustion percentage and a 35.3% dye fixation rate in the conventional water medium. An orthogonal array design (L9) was adopted to optimize the dyeing conditions with respect to exhaustion percentage. The results indicated that the dyebath temperature was the most important factor for achieving the optimal dye exhaustion, and dyeing time also showed considerable effects. Linear regression was used to predict the exhaustion percentage, and the resulting p value of 0.000 demonstrated that a strong coefficient was proven among all selected factors. This study has demonstrated that dyeing of cotton fabric with cacao husk extracts in the D5 dyeing system can be a viable method for the textile industry with minimal environmental pollution

Broadening Color Shade of Dyed Wool Fibre with Binary and Ternary Natural Plant Dye Combinations

A limited selection of natural dyes’ color impedes the development of textile dyeing with natural plant dyes. Inspiring by the conventional coloration of textiles with a combination of three synthetic dyes generally, the present work is to investigate the broadening color shade of dyed wool fiber with ternary natural dye combinations of madder red (MR), gardenia yellow (GY), and gardenia blue (GB) without mordants in a decamethylcyclopentasiloxane (D5) medium. The wool yarn was wetted in an aqueous solution of pH 3 to own a 300% pickup rate, followed by immersion in a D5 medium containing 2% of alcohol ethoxylate (AEO-3) and solid natural dyes at 90°C for 90 min for coloration. The colorfastness to washing was achieved at a 4–5 for fading and a 5 rating for staining for all colors. The XRD patterns and TGA analysis confirmed that the dyeing procedure did not affect the crystallinity nature and stable thermal tendency. SEM images and cross-sections showed that the dyeing procedure did not damage the morphological structure of the wool fiber surface, and the dyes were evenly distributed. Finally, many color shades of dyed fibers were prepared with various dyes’ ratios

Influence of Sequential Liquid Ammonia and Caustic Mercerization Pre-Treatment on Dyeing Performance of Knit Cotton Fabric

A two-stage sequential pretreatment including caustic mercerization (CM) and liquid ammonia (LA) treatment was applied to investigate the influence on dyeing performance and handle of knit cotton fabric, and the relationship between dye size and dyeing properties. Various techniques were applied to characterize all the treated fabrics. X-ray diffraction (XRD) and Fourier-transform infrared (FTIR) analyses of the treated fabrics confirmed that both sequential treatments decreased the crystallinity of cotton fabric more than only the CM or LA treatment. The pattern of cellulose I was transferred to a mixed configuration of cellulose II and cellulose III after the CM/LA or LA/CM treatment. Thermal performances measured by thermogravimetric analysis (TGA) and differential thermogravimetry (DTG) techniques showed that the thermal stability of the treated cotton only marginally decreased. The wicking height increased after the sequential CM/LA treatment, indicating that the hydrophilicity of the fabric increased. The dye absorption and color uniformity were better for the reactive dye with a smaller molecular weight (Reactive Red 2) compared with the one with a larger molecular weight (Reactive Red 195). The total dye fixation efficiency (T%) increased to 72.93% and 73.24% for Reactive Red 2 dyeings of CM/LA- and LA/CM-cotton fabric from 46.75% of the untreated fabric, respectively; the T% increased to 65.33% and 72.27% for Reactive Red 195 dyeings of CM/LA- and LA/CM-cotton fabric from 35.17% of the untreated fabric, respectively. The colorfastness and dye exhaustion and fixation percentages of the samples were enhanced after the treatments. Furthermore, compared to the single CM or LA treatment, the softness handle properties were further improved after the fabrics were sequentially treated by CM/LA. The developed pre-treatment of CM/LA can be used in the textile industry to promote the dyeability, handle, and mechanical properties of knit cotton fabrics

The optimisation of whiteness of polyester fabric treated with nanoparticles of 2,2′-(vinylenedi-p-phenylene)bis-benzoxazole (OB-1) by the Taguchi method

This study explores a new approach to achieve a whitening effect on polyester fabric by utilizing a ground form of raw OB-1 (OB-1-G) in combination with dispersing agents. The whitening process parameters, such as whitening temperature, OB-1-G mass, and whitening time were optimized using the L16 orthogonal array-based Taguchi methodology. The signal-to-noise ratio was carried out through a larger-is-better approach to augment the parameter responses, specifically the whiteness. The results suggest that the degree of whiteness of polyester fabric is significantly affected by the whitening treatment temperature (P < 0.05), with a contribution percentage of 93.87%. A whiteness index of 94.12 was achieved for the polyester fabric treated at the optimized conditions. The fabric treated with OB-1-G at the optimized conditions was characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and X-ray diffraction (XRD). The investigation also included the correlation between the length of time spent in washing and rubbing, and their efficacy in achieving whitening outcomes. The research demonstrated the effectiveness of OB-1-G nanopowder in combination with dispersing agents as a fluorescent optical brightener for the optical brightening of polyester fiber with potential use in the textile industry on a larger scale