L'organisation biogéologique du lac Temsah (Ismaïlia, Egypte)

Le lac Temsah, situé sur le canal de Suez, à mi-distance entre Port Saïd et Suez, est étudié quant à son organisation hydrologique, hydrochimique, biologique et sédimentologique. Dans sa partie axiale, le bassin est alimenté par de l'eau de mer grâce au canal de Suez. Il est par ailleurs soumis à une influence continentale complexe et originale avec interférence d'un climat aride et d'apports d'eau douce en provenance du Nil. L'organisation hydrologique et hydrochimique du lac dépend de facteurs saisonniers qui gèrent notamment le débit du Nil et la circulation des eaux dans le canal de Suez. Malgré ce dispositif original, l'organisation biologique est semblable à celle des lagunes méditerranéennes; la partie centrale du bassin, modérément confinée, abrite des populations dominées par les mollusques. La région directement influencée par les apports nilotiques présente une forte biomasse phytoplanctoniques et des peuplements benthiques typiquement paraliques. La zone de contact entre les eaux du Nil en crue et celles du bassin est marquée par un fort engraissement organique des sédiments qui se traduit par la diminution des filtreurs au profit des détrivore

Teneurs en 18O et concentration saline d'eaux paraliques et continentales égyptiennes

Plusieurs corps d'eau lagunaires et continentaux égyptiens sont comparés quant à l'abondance en oxygène-18 et la concentration saline (ici appréciée par la teneur en Cl¯) de leurs eaux superficielles.En Egypte, les eaux continentales de surface proviennent toutes du système nilotique dont les eaux, après leur longue traversée du grand Desert Oriental, se trouvent très évaporées et fortement enrichies en oxygène-18 à leur arrivée dans le delta.Dans les bassins alimentés uniquement par la mer (lagunes de Mer Rouge et du Golfe de Suez) soit par l'eau du Nil (Lac du Fayoum), les deux paramètres considérés augmentent conjointement depuis les zones d'alimentation vers les reculées marginales selon le déplacement des eaux.Dans les bassins à alimentation mixte, (Partie terminale du delta, lac Temsah sur le Canal de Suez), les eaux les plus diluées sont aussi les plus riches en isotopes lourds.Ainsi, dans le contexte climatique et géographique très particulierde l'Egypte, il est possible de reconnaître les eaux continentales, marines ou paraliques à partir des deux paramètres étudiés mais non à partir d'un seul, notamment la teneur en oxygène-18.The aim of this paper is to study some aspects of the geochemical behaviour (18O, (Cl-)) of waters of some basins in Egypt. Several types of basin are studied (figure 1).1) Basin with marine seawater input only, either wide open to the Red sea such as Zeit Bay (27°45'N, 33°25'E), relatively open such as Guesmah Lagoon (27°40'N, 33°30'E) or indirectly linked to the sea through a coastal sand bar such as the pools of sebkha Melaha (28°10'N, 33°10'E).2) Basin supplied by continental water without outflow such as Fayoum Lake (= Birket Karoum) (29°25'N, 30°30'E) which receives fresh waters from a Nile diversion.3) Water bodies with a mixed water input (continental and marine waters) such as the Nile delta and Temsah Lake (= Ismaïla Lake), (30°25'N, 31°30'E), the katter being on the Suez Canal and receiving waters from Mediterranean Sea and from the eastern branch of the Nile.Local means climatic parameter are those of Cairo, Alexandria, Queseir and Louxor (table 1).RESULTS AND DISCUSSION1 - Nile delta (figure 2 and 3)Sampling period was performed in August 1984.- At the beginning of the Nile delta the water at Beni-Suez (station 14) presents a low chloride concentration (0.1 to 0.2 g l-1) and a relatively high 18O content (+ 3 ‰) due to evaporation of the Nile water during its downstream course from the Aswan High Dam which collects waters in the upper part of the Nile watershed.- The content of both (Cl-) and 18O stightly increases in the delta region in relation to the anastomosis of branches of the Nile due to an intensive irrigation network.- In the coastal region, due to mixing with sea water or/and brackish water, the isotope content decreases while the chloride concentration increases.2 - Temsah or Ismaïla LakeTwo periods of sampling : March and August 1984. The general trend is a decrease of 18O and an increase of (Cl-) from the Nile waters to the central part of the lake, and an increase of both 18O and (Cl-) at the fringes of the lake, due to evaporation.3 - Coastal basins from the Red SeaZeit Bay and Guesmah Lagoon. Two sampling periods : March and August 1984. The isotope content and chloride concentration act in parallel and depend principally on the movement of water bodies. For the surface waters wind velocity and direction play a major rote in the spatial distribution of the chlorinity and isotope content. A slight enrichment is noted during the summer period.4 - Pools in Sebkha MelahaThe isotope composition and chloride content of the ponds water fed by sea water through the sand salt bar increased during the summer as it is the case in the first stages of evaporation of salt pans (PIERRE and FONTES, 1982).5 - Fayoun Lake : Birket KaroumTwo sampling periods : March and August 1984. Because of a lack of sufficient data (salinity and isotopic composition of the input, water flux of the incoming water, local values of the relative humidity and temperature of the atmosphere, isotopic composition of the water vapour...) a water mass balance coupled with a chloride and isotopic mass balance was not possible. Nevertheless, with our data measured (18O, (Cl-) lake levels), some estimations were made of the temperature, evaporation, wind velocities (from meteorological tables) and the isotopic composition of the input : δA in the lake (SIMPSON et al., 1987), and if we assume that the lake presents a long term dynamic equilibrium, it is possible to estimate with reasonable accuracy that : i) the total isotopic enrichment factor (ɛ) is between 8 ‰ and 24 ‰ (figure 12) : ɛ= ɛe + ɛk , with ɛe = equilibrium isotopic enrichment factor; ɛk = kinetic isotopic enrichment factor. ii) the salt content of the incoming water δA is ≈20 g l-1. The principal consequence is that the important loss of water observed between the sampling periods (1.5 m difference in water level) was not due to evaporation only, but more by seepage from the bottom of the take (≈ 560 106 m3 for a total volume of ≈800 106 m3).CONCLUSIONS1) On a diagram δ18O - CL- (figure 13 and 14) where all the data for the Egyptian basins studied are represented, the similarity in the geochemical behaviour of the basins with a single input, is noted; the relation between isotopic composition and chloride content is approximatively logarithmic. In the case of a mixed input basin (Temsah Lake) two branches on the diagram are distinct; the first branch shows the effect of mixing in the west part of the lake, between evaporated Nile water and water from the Mediterranean Sea. The shape of this branch is very similar to that of the Nile delta: the second branch represents evaporation in the east part of the take (figure 13 and 14).2) In the case of a semi-arid environment, this study shows that with two simple parameters only, such as isotopic composition and the chloride content of waters, it is possible to distinguish the marine, paralic and continental domain (figure 15)

A SAMPLING DESIGN FOR WITHIN-TREE LARVAL POPULATIONS OF THE MARITIME PINE SCALE, <i>MATSUCOCCUS FEYTAUDI</i> DUC. (HOMOPTERA: MARGARODIDAE), AND THE RELATIONSHIP BETWEEN LARVAL POPULATION ESTIMATES AND MALE CATCH IN PHEROMONE TRAPS

AbstractSampling procedures for estimating within-tree populations of second-stage larvae (L2) of Matsucoccus feytaudi Duc., infesting maritime pine (Pinus pinaster Ait.), were investigated. These included random sampling without replacement, and systematic sampling with and without a linear model. The relative precision of the sampling was affected by the number, size, and bark thickness of the sample units. Because of symmetrical vertical distribution of within-tree populations, systematic sampling with a linear model did not increase precision when compared with simple systematic sampling. Sampling can be profitably reduced to below the crown portion of the bole, after removal of the part with either smooth or very thick and pyramidal bark. Counting L2 exuviae in the upper 10 cm of each 20-cm-long log, using one in every three logs, provided a relative precision of about 40%. The numbers of male M. feytaudi caught in sticky traps baited with 5 or 30 μg of synthetic pheromone were compared with the numbers of L2 estimated according to the sampling method previously developed. There was a significant positive correlation between number of scales caught and L2 estimates, at the level of individual trees for the lower dose lures, and at the level of groups of trees for the higher dose lures, used in 20-year-old stands. Large captures in younger, weakly infested stands were related to a possible immigration of flying scale insects.</jats:p

Isolation of a Low-Coordinate Rhodium Phosphine Complex Formed by C-C Bond Activation of Biphenylene

The isolation of a low-coordinate rhodium complex containing the 2,2′-biphenyl ligand, trans-[Rh(2,2′-biphenyl)(P iPr 3) 2][BAr F4], is described. This complex is prepared by C-C bond activation of biphenylene by the [Rh(P iPr 3) 2] + fragment and proceeds via the (isolated) intermediate π complex [Rh(η 6-biphenylene) (P iPr 3) 2][BAr F4]. An intramolecular ring slippage mechanism is suggested for this process, and this is supported by DFT calculations. © 2010 American Chemical Society