Thermal Lensing Spectroscopy With Picosecond Pulse Trains and a New Dual Beam Configuration

In this communication, we wish to report on the use of synchronously mode-locked picosecond lasers in a pump-probe configuration for TL spectroscopy. The peak power for these picosecond lasers is very high and, of course, the fundamental of the dye laser (red beam) can be efficiently (~10%) doubled in frequency (U.V. beam) by second harmonic generation in nonlinear crystals. We use this generated U.V. beam as a probe to monitor the very weak absorption of the red beam. An arrangement [4] of the beams involving different waist positions for the pump and probe is used. This arrangement results in an enhancement of sensitivity (at least a factor of three to seven). Also, a different dependence of the signal on the cell position compared to the single beam method is obtained. Finally, we have obtained the Δν = 5 CH-stretching overtone absorption spectrum of liquid toluene with this method (see Figure 1). Suggestions are made regarding new applications of this picosecond pulse thermal lensing technique

Enhanced reverse saturable absorption and optical limiting in heavy-atom-substituted phthalocyanines

The reverse saturable absorption and the optical-limiting response of metal phthalocyanines can be enhanced by use of the heavy-atom effect. Phthalocyanines containing heavy-metal atoms, such as In, Sn, and Pb, show a nearly factor-of-2 enhancement in the ratio of effective excited-state to ground-state absorption cross sections compared with those containing lighter atoms, such as Al and Si. In an f/8 optical geometry, homogeneous solutions of heavy-metal phthalocyanines, at 30% linear transmission, limit 8-ns 532-nm laser pulses to ≤ 3 µJ the energy for 50% probability of eye damage) for incident energies as high as 800 µJ

The Physics of 2-d Stringy Spacetimes

We examine the two-dimensional spacetimes that emerge from string theory. We find all the solutions with no tachyons, and show that the only non-trivial solution is the black hole spacetime. We examine the role of duality in this picture. We then explore the thermodynamics of these solutions which is complicated by the fact that only in two spacetime dimensions is it impossible to redefine the dilaton field in terms of a canonical scalar field. Finally, we extend our analysis to the heterotic string, and briefly comment on exact, as opposed to perturbative, solutions

Observation of high-energy vibrational overtones of molecules in solids: Local modes and intramolecular relaxations

In the last few years, the spectra of vibrational overtones (1) (at ~15-20,000 cm^-1) in large molecules have received considerable attention. The focus is on three problems dealing with the origin of relaxation at such high energies, the association of spectral band positions with the local modes (LM) in molecules, and the relevance of these spectra to possible selectivity in laser-induced chemistry

Kleinian Geometry and the N=2 Superstring

This paper is devoted to the exploration of some of the geometrical issues raised by the $N=2$ superstring. We begin by reviewing the reasons that $\beta$-functions for the $N=2$ superstring require it to live in a four-dimensional self-dual spacetime of signature $(--++)$, together with some of the arguments as to why the only degree of freedom in the theory is that described by the gravitational field. We then move on to describe at length the geometry of flat space, and how a real version of twistor theory is relevant to it. We then describe some of the more complicated spacetimes that satisfy the $\beta$-function equations. Finally we speculate on the deeper significance of some of these spacetimes.Comment: 30 pages, AMS-Te

A study of the usefulness of Skylab EREP data for earth resources studies in Australia

There are no author-identified significant results in this report