High-precision calculations of In I and Sn II atomic properties

We use all-order relativistic many-body perturbation theory to study 5s^2 nl configurations of In I and Sn II. Energies, E1-amplitudes, and hyperfine constants are calculated using all-order method, which accounts for single and double excitations of the Dirac-Fock wave functions.Comment: 10 pages, accepted to PRA; v2: Introduction changed, references adde

Oscillator strengths with pseudopotentials

The time-dependent local-density approximation (TDLDA) is shown to remain accurate in describing the atomic response of IB elements under the additional approximation of using pseudopotentials to treat the effects of core electrons. This extends the work of Zangwill and Soven who showed the utility of the all-electron TDLDA in the atomic response problem.Comment: 13 pages including 3 Postscript figure

Optical response of small silver clusters

The time-dependent local density approximation is applied to the optical response of the silver clusters, Ag_2, Ag_3, Ag_8 and Ag_9^+. The calculation includes all the electrons beyond the closed-shell Ag^{+11} ionic core, thus including for the first time explicitly the filled d-shell in the response. The excitation energy of the strong surface plasmon near 4 eV agrees well with experiment. The theoretical transition strength is quenched by a factor of 4 with respect to the pure s-electron sum rule in Ag_8 due to the d-electrons. A comparable amount of strength lies in complex states below 6 eV excitation. The total below 6 eV, about 50% of the s sum rule, is consistent with published experiments.Comment: 13 pages RevTex and 9 Postscript figure

E1 amplitudes, lifetimes, and polarizabilities of the low-lying levels of atomic ytterbium

The results of ab initio calculation of E1 amplitudes, lifetimes,and polarizabilities for several low-lying levels of ytterbium are reported. The effective Hamiltonian for the valence electrons has been constructed in the frame of CI+MBPT method and solutions of many electron equation are found.Comment: 11 pages, submitted to Phys.Rev.

A spectroscopic study of the plasma generated in a thallium arc. Transition probabilities for several lines of Tl I

The optical emission spectra (2000–15 000) A of a plasma produced an a Tl arc lamp have been recorded and analysed; using the series nd 2D3/2`5/2 → 6p 2P Q3/2 and ns 2SL/2 → 6p 2P Q3/2 we have obtained that the electron density is of the order of 10L4 cm−3 and the excitation temperature is (2880 ± 50) K. Relative transition probabilities for 26 lines from excited levels near the ionization limit of Tl I have been determined from line intensities