3 research outputs found
Self-Assembled Nanocube-Based Plasmene Nanosheets as Soft Surface-Enhanced Raman Scattering Substrates toward Direct Quantitative Drug Identification on Surfaces
We report on self-assembled nanocube-based
plasmene nanosheets
as new surface-enhanced Raman scattering (SERS) substrates toward
direct identification of a trace amount of drugs sitting on topologically
complex real-world surfaces. The uniform nanocube arrays (superlattices)
led to low spatial SERS signal variances (∼2%). Unlike conventional
SERS substrates which are based on rigid nanostructured metals, our
plasmene nanosheets are mechanically soft and optically semitransparent,
enabling conformal attachment to real-world solid surfaces such as
banknotes for direct SERS identification of drugs. Our plasmene nanosheets
were able to detect benzocaine overdose down to a parts-per-billion
(ppb) level with an excellent linear relationship (<i>R</i><sup>2</sup> > 0.99) between characteristic peak intensity and
concentration.
On banknote surfaces, a detection limit of ∼0.9 × 10<sup>–6</sup> g/cm<sup>2</sup> benzocaine could be achieved. Furthermore,
a few other drugs could also be identified, even in their binary mixtures
with our plasmene nanosheets. Our experimental results clearly show
that our plasmene sheets represent a new class of unique SERS substrates,
potentially serving as a versatile platform for real-world forensic
drug identification
Large-Scale Self-Assembly and Stretch-Induced Plasmonic Properties of Core–Shell Metal Nanoparticle Superlattice Sheets
We report on a facile interfacial
self-assembly approach to fabricate large-scale metal nanoparticle
superlattice sheets from nonspherical core–shell nanoparticles,
which exhibited reversible plasmonic responses to repeated mechanical
stretching. Monodisperse Au@Ag nanocubes (NCs) and Au@Ag nanocuboids
(NBs) could be induced to self-assembly at the hexane/water interface,
forming uniform superlattices up to at least ∼13 cm<sup>2</sup> and giving rise to mirror-like reflection. Such large-area mirror-like
superlattice sheets exhibited reversible plasmonic responses to external
mechanical strains. Under stretching, the dominant plasmonic resonance
peak for both NB and NC superlattice sheets shifted to blue, following
a power-law function of the applied strain. Interestingly, the power-law
exponent (or the decay rate) showed a strong shape dependence, where
a faster rate was observed for NB superlattice sheets than that for
NC superlattice sheets
Giant Plasmene Nanosheets, Nanoribbons, and Origami
We introduce <i>Plasmene</i> in analogy to grapheneas free-standing, one-particle-thick, superlattice sheets of nanoparticles (“meta-atoms”) from the “plasmonic periodic table”, which has implications in many important research disciplines. Here, we report on a general bottom-up self-assembly approach to fabricate giant plasmene nanosheets (<i>i.e.</i>, plasmene with nanoscale thickness but with macroscopic lateral dimensions) as thin as ∼40 nm and as wide as ∼3 mm, corresponding to an aspect ratio of ∼75 000. In conjunction with top–down lithography, such robust giant nanosheets could be milled into one-dimensional nanoribbons and folded into three-dimensional origami. Both experimental and theoretical studies reveal that our giant plasmene nanosheets are analogues of graphene from the plasmonic nanoparticle family, simultaneously possessing unique structural features and plasmon propagation functionalities