864 research outputs found
Nucleon Mass Splitting at Finite Isospin Chemical Potential
We investigate nucleon mass splitting at finite isospin chemical potential in
the frame of two flavor Nambu--Jona-Lasinio model. It is analytically proved
that, in the phase with explicit isospin symmetry breaking the proton mass
decreases and the neutron mass increases linearly in the isospin chemical
potential.Comment: 3 pages and no figure
1S0 pairing correlation in symmetric nuclear matter with Debye screening effects
AbstractThe 1S0 pairing of symmetric nuclear matter is discussed in the framework of relativistic nuclear theory with Dyson–Schwinger equations (DSEs). The in-medium nucleon and meson propagators are treated in a more self-consistent way through meson polarizations. The screening effects on mesons due to in-medium nucleon excitation are found to reduce the 1S0 pairing gap and shift remarkably the gap peak to low density region
Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand
A new Cd(II) coordination polymer, {[Cd3(L)2(DMF)2(H2O)2]·H2O}n (H2L = 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid) was synthesized by one-pot synthesis method from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid, NaOH, DMF, and Cd(NO3)2·4H2O. Its structure was determined by elemental analysis and single crystal X-ray diffraction. Structural analysis shows that three Cd(II) ions are all six-coordinated with four oxygen atoms of four 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands and two O atoms from two DMF molecules (Cd1) or two oxygen atoms of two coordinated H2O molecules (Cd2 and Cd3) to form an octahedral coordination geometry. The Cd(II) coordination polymer displays a 1D chained structure by the bridging carboxylate groups from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands. The conversion of benzaldehyde is 90.9%, which is 40~50% higher than those of the other three aldehydes (4-methylbenzaldehyde, p-methoxybenzaldehyde and 3-chlorobenzaldehyde), so the Cd(II) coordination polymer catalyst shows better catalytic activity for the coupling reaction of benzaldehyde, phenylacetylene, and piperidine than the other three aldehydes. Copyright © 2018 BCREC Group. All rights reserved
Received: 25th April 2017; Revised: 11st September 2017; Accepted: 1st November 2017; Available online: 11st June 2018; Published regularly: 1st August 2018
How to Cite: Ji, Z.X., Li, P.F. (2018). Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 220-226 (doi:10.9767/bcrec.13.2.1178.220-226
ReAct Meets ActRe: When Language Agents Enjoy Training Data Autonomy
Language agents have demonstrated autonomous decision-making abilities by
reasoning with foundation models. Recently, efforts have been made to train
language agents for performance improvement, with multi-step reasoning and
action trajectories as the training data. However, collecting such trajectories
still requires considerable human effort, by either artificial annotation or
implementations of diverse prompting frameworks. In this work, we propose
AT, a framework that enables the Autonomous Annotation of Agent
Trajectories in the style of ReAct. The central role is an ActRe prompting
agent, which explains the reason for an arbitrary action. When randomly
sampling an external action, the ReAct-style agent could query the ActRe agent
with the action to obtain its textual rationales. Novel trajectories are then
synthesized by prepending the posterior reasoning from ActRe to the sampled
action. In this way, the ReAct-style agent executes multiple trajectories for
the failed tasks, and selects the successful ones to supplement its failed
trajectory for contrastive self-training. Realized by policy gradient methods
with binarized rewards, the contrastive self-training with accumulated
trajectories facilitates a closed loop for multiple rounds of language agent
self-improvement. We conduct experiments using QLoRA fine-tuning with the
open-sourced Mistral-7B-Instruct-v0.2. In AlfWorld, the agent trained with
AT obtains a 1-shot success rate of 96%, and 100% success with 4 iterative
rounds. In WebShop, the 1-shot performance of the AT agent matches human
average, and 4 rounds of iterative refinement lead to the performance
approaching human experts. AT agents significantly outperform existing
techniques, including prompting with GPT-4, advanced agent frameworks, and
fully fine-tuned LLMs
A coordinated control method of voltage and reactive power for active distribution net-works based on soft open point
The increasing penetration of distributed generators (DGs) exacerbates the risk of voltage violations in active distribu-tion networks (ADNs). The conventional voltage regulation de-vices limited by the physical constraints are difficult to meet the requirement of real-time voltage and VAR control (VVC) with high precision when DGs fluctuate frequently. However, soft open point (SOP), a flexible power electronic device, can be used as the continuous reactive power source to realize the fast voltage regu-lation. Considering the cooperation of SOP and multiple regula-tion devices, this paper proposes a coordinated VVC method based on SOP for ADNs. Firstly, a time-series model of coordi-nated VVC is developed to minimize operation costs and eliminate voltage violations of ADNs. Then, by applying the linearization and conic relaxation, the original nonconvex mixed-integer non-linear optimization model is converted into a mixed-integer sec-ond-order cone programming (MISOCP) model which can be efficiently solved to meet the requirement of voltage regulation rapidity. Case studies are carried out on the IEEE 33-node system and IEEE 123-node system to illustrate the effectiveness of the proposed method
Non-Abelian Medium Effects in Quark-Gluon Plasma
Based on the kinetic theory, the non-Abelian medium property of hot
Quark-Gluon Plasma is investigated. The nonlinearity of the plasma comes from
two aspects: The nonlinear wave-wave interaction and self-interaction of color
field. The non-Abelian color permittivity is obtained by expanding the kinetic
equations to third order. As an application, the nonlinear Landau damping rate
and the nonlinear eigenfrequency shift are calculated in the longwave length
limit.Comment: 12 pages(Revtex), no figure
Can Touchscreen Devices be Used to Facilitate Young Children's Learning? A Meta-Analysis of Touchscreen Learning Effect
Because of the continuous stream of touchscreen apps that are claimed to be educational and the increasing use of touchscreen devices in early childhood, considerable attention is being paid to the effect of touchscreens on young children's learning. However, the existing empirical findings in young child samples are not consistent. In this meta-analysis we tested the overall effect of touchscreen devices on young children's (0- to 5-year-olds) learning performance, as well as moderators of this effect, based on 36 empirical articles (79 effect sizes) involving 4,206 participants. The overall analysis showed a significant touchscreen learning effect (d = 0.46), indicating that young children indeed benefited from touchscreen learning. Interestingly, age, learning material domain, comparison group, and experimental environment significantly moderated the effect of touchscreen devices on young children's learning outcome. These findings shed light on the role of touchscreen-related physical experience in early childhood education
- …