Achieving the Theoretical Depairing Current Limit in Superconducting Nanomesh Films

We show the theoretical depairing current limit can be achieved in a robust fashion in highly ordered superconductor nanomesh films having spatial periodicities smaller than both the superconducting coherence length and the magnetic penetration depth. For a niobium nanomesh film with 34 nm spatial periodicity, the experimental critical current density is enhanced by more than 17 times over the continuous film and is in good agreement with the depairing limit over the entire measured temperature range. The nanomesh superconductors are also less susceptible to thermal fluctuations when compared to nanowire superconductors. T_c values similar to the bulk film are achieved, and the nanomeshes are capable of retaining superconductivity to higher fields relative to the bulk. In addition, periodic oscillations in T_c are observed as a function of field, reflecting the highly ordered nanomesh structure

Scanning Tunneling Microscopy Characterization of the Electrical Properties of Wrinkles in Exfoliated Graphene Monolayers

We report on the scanning tunneling microscopy study of a new class of corrugations in exfoliated monolayer graphene sheets, that is, wrinkles ~10 nm in width and ~3 nm in height. We found such corrugations to be ubiquitous in graphene and have distinctly different properties when compared to other regions of graphene. In particular, a “three-for-six” triangular pattern of atoms is exclusively and consistently observed on wrinkles, suggesting the local curvature of the wrinkle provides a sufficient perturbation to break the 6-fold symmetry of the graphene lattice. Through scanning tunneling spectroscopy, we further demonstrate that the wrinkles have lower electrical conductance and are characterized by the presence of midgap states, which is in agreement with recent theoretical predictions. The observed wrinkles are likely important for understanding the electrical properties of graphene

Advanced ceramics and composites based on rice hulls

As a by-product of the agricultural industry, rice hulls are available at large volume across the world. The disposal of the rice hulls itself is a big problem for the rice millers where the rice paddies are peeled off and rice hulls are produced. There have been many disposal methods developed, but the true value of the rice hulls would be more appreciated when they are employed to produce high value-added advanced ceramics. In this dissertation, advanced ceramics, such as AlN nanowires, SiC whiskers, mullite and SiC/Al2O3 nano-sized composites, were developed and studied based on the rice hulls. The SiC whiskers and AlN fibers were successfully prepared at high yield in a process (patent pending) developed by the author. Since the one-dimensional ceramic materials are valuable raw materials for many industrial applications, the study presented in this dissertation is particularly valuable. During the development of the one-dimensional ceramics, some unique morphology, such as the beaded SiC whiskers were also prepared and investigated. Some potential applications of the prepared ceramics were investigated, such as the application of SiC whiskers as a heat transfer enhancement agent, and the application of beaded SiC whiskers as the reinforcement phase in composites. The heat transfer enhancement by SiC whiskers in a convective flow is promising: an enhancement as high as 27% was achieved by a dispersion of SiC (0.16 wt % in water) at low temperature (300-330 K). The beaded SiC whiskers are confirmed to be an efficient reinforcement phase for plastic-matrix composites, because their special structures would render them a new interlocking mechanism to obtain a much more reliable coupling with the matrix in a composite