7,798 research outputs found

    A shrinking core model for steam hydration of CaO-based sorbents cycled for CO2 capture

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    Calcium looping is a developing CO2 capture technology. It is based on the reversible carbonation of CaO sorbent, which becomes less reactive upon cycling. One method of increasing the reactivity of unreactive sorbent is by hydration in the calcined (CaO) form. Here, sorbent has been subjected to repeated cycles of carbonation and calcination within a small fluidised bed reactor. Cycle numbers of 0 (i.e., one calcination), 2, 6 and 13 have been studied to generate sorbents that have been deactivated to different extents. Subsequently, the sorbent generated was subjected to steam hydration tests within a thermogravimetric analyser, using hydration temperatures of 473, 573 and 673 K. Sorbents that had been cycled less prior to hydration hydrated rapidly. However, the more cycled sorbents exhibited behaviour where the hydration conversion tended towards an asymptotic value, which is likely to be associated with pore blockage. This asymptotic value tended to be lower at higher hydration temperatures; however, the maximum rate of hydration was found to increase with increasing hydration temperature. A shrinking core model has been developed and applied to the data. It fits data from experiments that did not exhibit extensive pore blockage well, but fits data from experiments that exhibited pore blockage less well

    On Writ of Certiorari to the United States Court of Appeals for the Ninth Circuit, Brief of Product Liability Advisory Council, Inc., National Association of Manufacturers, Business Roundtable, and Chemical Manufacturers Association as Amici Curiae in Support of Respondent, William Daubert and Joyce Daubert, Individually and as Guardians Ad Litem for Jason Daubert, and Anita De Young, Individually and as Gaurdian Ad Litem for Eric Schuller v. Merrell Dow Pharmaceuticals, Inc.

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    The Federal Rules of Evidence exclude expert scientific testimony when it has been developed without regard for accepted scientific methods. This case focuses on expert scientific evidence. Such evidence plays a vital and often dispositive role in modern litigation. For scientific evidence to be helpful to the factfinder it must meet some minimal threshold of reliability. To hold otherwise would be to allow a system of adjudication based more on chance than on reason

    Order information and retrieval distinctiveness: Recall of common versus bizarre material.

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    An overview of advances in biomass gasification

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    Biomass gasification is a widely used thermochemical process for obtaining products with more value and potential applications than the raw material itself. Cutting-edge, innovative and economical gasification techniques with high efficiencies are a prerequisite for the development of this technology. This paper delivers an assessment on the fundamentals such as feedstock types, the impact of different operating parameters, tar formation and cracking, and modelling approaches for biomass gasification. Furthermore, the authors comparatively discuss various conventional mechanisms for gasification as well as recent advances in biomass gasification. Unique gasifiers along with multi-generation strategies are discussed as a means to promote this technology into alternative applications, which require higher flexibility and greater efficiency. A strategy to improve the feasibility and sustainability of biomass gasification is via technological advancement and the minimization of socio-environmental effects. This paper sheds light on diverse areas of biomass gasification as a potentially sustainable and environmentally friendly technology
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